Muhammed Arshad, Linda Williams, Athira Ajayan, Abraham Joseph
{"title":"基于 2-hydroxy-1- Naphthaldehyde 的比色探针，用于同时检测二价铜和镍，具有高灵敏度和高选择性。","authors":"Muhammed Arshad, Linda Williams, Athira Ajayan, Abraham Joseph","doi":"10.1007/s10895-024-03895-3","DOIUrl":null,"url":null,"abstract":"<p><p>A neoteric colorimetric probe based on 2-hydroxy-1-naphthaldehyde (PMB3) was designed and synthesized for the real-time as well as on-site naked-eye detection of Cu<sup>2+</sup>/Ni<sup>2+</sup> ions. Various physicochemical methods were employed to characterize the probe, and its colorimetric response to different metal ions was meticulously investigated. The probe, PMB3, exhibited a sensitive colorimetric response to Cu<sup>2+</sup>/Ni<sup>2+</sup> ions among other competing metal ions, culminating in a prominent colour change from colourless to yellow. The stoichiometry of the ligand metal complexes was ascertained to be in a 1:1 ratio using Job's plot analysis, which was further corroborated by ESI-MS data. With detection limits of 4.56 µM for Cu<sup>2+</sup> and 2.68 µM for Ni<sup>2+</sup>, the method was effectively extended to real sample analysis, ensuring propitious results that closely aligned with the actual values.</p>","PeriodicalId":15800,"journal":{"name":"Journal of Fluorescence","volume":null,"pages":null},"PeriodicalIF":2.6000,"publicationDate":"2024-08-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"2-hydroxy-1- Naphthaldehyde Based Colorimetric Probe for the Simultaneous Detection of Bivalent Copper and Nickel with High Sensitivity and Selectivity.\",\"authors\":\"Muhammed Arshad, Linda Williams, Athira Ajayan, Abraham Joseph\",\"doi\":\"10.1007/s10895-024-03895-3\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p><p>A neoteric colorimetric probe based on 2-hydroxy-1-naphthaldehyde (PMB3) was designed and synthesized for the real-time as well as on-site naked-eye detection of Cu<sup>2+</sup>/Ni<sup>2+</sup> ions. Various physicochemical methods were employed to characterize the probe, and its colorimetric response to different metal ions was meticulously investigated. The probe, PMB3, exhibited a sensitive colorimetric response to Cu<sup>2+</sup>/Ni<sup>2+</sup> ions among other competing metal ions, culminating in a prominent colour change from colourless to yellow. The stoichiometry of the ligand metal complexes was ascertained to be in a 1:1 ratio using Job's plot analysis, which was further corroborated by ESI-MS data. With detection limits of 4.56 µM for Cu<sup>2+</sup> and 2.68 µM for Ni<sup>2+</sup>, the method was effectively extended to real sample analysis, ensuring propitious results that closely aligned with the actual values.</p>\",\"PeriodicalId\":15800,\"journal\":{\"name\":\"Journal of Fluorescence\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":2.6000,\"publicationDate\":\"2024-08-19\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Fluorescence\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1007/s10895-024-03895-3\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"BIOCHEMICAL RESEARCH METHODS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Fluorescence","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1007/s10895-024-03895-3","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"BIOCHEMICAL RESEARCH METHODS","Score":null,"Total":0}
2-hydroxy-1- Naphthaldehyde Based Colorimetric Probe for the Simultaneous Detection of Bivalent Copper and Nickel with High Sensitivity and Selectivity.
A neoteric colorimetric probe based on 2-hydroxy-1-naphthaldehyde (PMB3) was designed and synthesized for the real-time as well as on-site naked-eye detection of Cu2+/Ni2+ ions. Various physicochemical methods were employed to characterize the probe, and its colorimetric response to different metal ions was meticulously investigated. The probe, PMB3, exhibited a sensitive colorimetric response to Cu2+/Ni2+ ions among other competing metal ions, culminating in a prominent colour change from colourless to yellow. The stoichiometry of the ligand metal complexes was ascertained to be in a 1:1 ratio using Job's plot analysis, which was further corroborated by ESI-MS data. With detection limits of 4.56 µM for Cu2+ and 2.68 µM for Ni2+, the method was effectively extended to real sample analysis, ensuring propitious results that closely aligned with the actual values.
期刊介绍：
Journal of Fluorescence is an international forum for the publication of peer-reviewed original articles that advance the practice of this established spectroscopic technique. Topics covered include advances in theory/and or data analysis, studies of the photophysics of aromatic molecules, solvent, and environmental effects, development of stationary or time-resolved measurements, advances in fluorescence microscopy, imaging, photobleaching/recovery measurements, and/or phosphorescence for studies of cell biology, chemical biology and the advanced uses of fluorescence in flow cytometry/analysis, immunology, high throughput screening/drug discovery, DNA sequencing/arrays, genomics and proteomics. Typical applications might include studies of macromolecular dynamics and conformation, intracellular chemistry, and gene expression. The journal also publishes papers that describe the synthesis and characterization of new fluorophores, particularly those displaying unique sensitivities and/or optical properties. In addition to original articles, the Journal also publishes reviews, rapid communications, short communications, letters to the editor, topical news articles, and technical and design notes.
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