"成分流 "条件及其对提高大陆中高成熟度页岩油产量的影响

IF 7 Q1 ENERGY & FUELS Petroleum Exploration and Development Pub Date : 2024-08-01 DOI:10.1016/S1876-3804(24)60509-4
Wenzhi ZHAO , Congsheng BIAN , Yongxin LI , Wei LIU , Bing QIN , Xiugang PU , Jianlin JIANG , Shiju LIU , Ming GUAN , Jin DONG , Yutan SHEN
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引用次数: 0

摘要

根据中国湖相页岩油区重点试采井的产量曲线、碳氢化合物组成和数量随时间的变化以及生产系统,进行了细馏分切割实验和分子动力学数值模拟,研究了页岩油组成变化对宏观流动性的影响。提出了页岩油 "组分流 "的概念,探讨了组分流的形成机理和条件。研究发现了四个方面的问题。首先,根据相似性和互溶性原理,轻、中、重烃在地下页岩的微孔/纳米孔内形成混溶状态,使流动性差的组分以分子团聚形式悬浮在重烃等轻、中烃溶剂中,从而降低页岩油粘度,提高流动性和流出性。其次,小分子芳香烃作为组分流动的载体,气态和轻烃含量越高,越有利于抑制树脂和沥青等重组分形成较大的聚集体,从而提高其塑性变形能力,带来更好的组分流动效率。第三,较高的地层温度会降低蜡等重烃组分的粘度,从而提高其流动性。第四,保存条件、地层能量和生产系统对控制轻烃组分的含量、流出率和形成稳定的 "组分流 "具有重要作用,是页岩油中多组分烃类达到最佳相容性和最大流速的关键因素。地下页岩油的组分流对于提高页岩油的单井产量和累积最终采收率意义重大。
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“Component flow” conditions and its effects on enhancing production of continental medium-to-high maturity shale oil

Based on the production curves, changes in hydrocarbon composition and quantities over time, and production systems from key trial production wells in lacustrine shale oil areas in China, fine fraction cutting experiments and molecular dynamics numerical simulations were conducted to investigate the effects of changes in shale oil composition on macroscopic fluidity. The concept of “component flow” for shale oil was proposed, and the formation mechanism and conditions of component flow were discussed. The research reveals findings in four aspects. First, a miscible state of light, medium and heavy hydrocarbons form within micropores/nanopores of underground shale according to similarity and intermiscibility principles, which make components with poor fluidity suspended as molecular aggregates in light and medium hydrocarbon solvents, such as heavy hydrocarbons, thereby decreasing shale oil viscosity and enhancing fluidity and outflows. Second, small-molecule aromatic hydrocarbons act as carriers for component flow, and the higher the content of gaseous and light hydrocarbons, the more conducive it is to inhibit the formation of larger aggregates of heavy components such as resin and asphalt, thus increasing their plastic deformation ability and bringing about better component flow efficiency. Third, higher formation temperatures reduce the viscosity of heavy hydrocarbon components, such as wax, thereby improving their fluidity. Fourth, preservation conditions, formation energy, and production system play important roles in controlling the content of light hydrocarbon components, outflow rate, and forming stable “component flow”, which are crucial factors for the optimal compatibility and maximum flow rate of multi-component hydrocarbons in shale oil. The component flow of underground shale oil is significant for improving single-well production and the cumulative ultimate recovery of shale oil.

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CiteScore
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473
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