开发用于改进超级电容器电极的 MXene 基混合复合材料的进展和方法

IF 7.1 3区 材料科学 Q1 GREEN & SUSTAINABLE SCIENCE & TECHNOLOGY Materials Today Sustainability Pub Date : 2024-08-22 DOI:10.1016/j.mtsust.2024.100963
Thibeorchews Prasankumar , Kaaviah Manoharan , N.K. Farhana , Shahid Bashir , K. Ramesh , S. Ramesh , Vigna K. Ramachandaramurthy
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引用次数: 0

摘要

人口的快速增长和高耗能技术的广泛使用,导致全球能源消耗大幅增加。最近,超级电容器因其充电和放电时间快、功率密度高和循环寿命长而成为一种更理想的替代品。对于许多研究人员来说,提高超级电容器的效率以实现多功能应用是一个主要的研究领域。许多元素被用作电极材料,以提供最佳的能量和功率密度,同时获得最大的比电容。在这些材料中,二维过渡金属碳化物和氮化物(通常称为 MXenes)是新兴的候选材料,尤其是在电化学储能应用中。MXenes 具有强度高、柔韧性好、结构独特、导电性强、表面积大、活性位点多样、疏水性和亲水性等特点,可用于尖端储能技术,因此是最佳的活性电极材料之一。二氧化二烯具有独特的二维层状结构,为各种电容材料的插层提供了无限可能。此外,MXenes 还具有金属氧化物的高亲水性和金属的高导电性。此外,活性炭(AC)、石墨烯、碳纳米管(CNT)、过渡金属氧化物和导电聚合物(CP)也因其出色的热学、机械、电学和形态学特性而成为极佳的电极材料。根据最近的研究,储能应用的完美方法之一是将二氧化二烯类与其他优异元素结合,生成二氧化二烯类复合电极材料。本综述包括研究用于超级电容器的 MXene 基混合复合材料的最新进展。内容包括复合材料的合成策略、电极结构、电化学性能及其在超级电容器中的效率。
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Advancements and approaches in developing MXene-based hybrid composites for improved supercapacitor electrodes

The rapid increase in population and widespread use of energy-consuming technologies are contributing to a substantial increase in the world's energy consumption. Supercapacitors have recently become a more desirable alternative due to their quick charging and discharging times, high power densities, and extended cycle lives. For many researchers, improving supercapacitor efficiency for multifunctional applications is a major area of study. Many elements have been employed as electrode materials to provide the best energy and power density while achieving the largest specific capacitance. Among these materials, 2D transition metal carbides and nitrides, commonly called MXenes, are emerging candidates, particularly in electrochemical energy storage applications. Because of their strength, flexibility, unique structure, increased electrical conductivity, large surface area, diversity of active sites, hydrophobicity, and hydrophilicity for cutting-edge energy storage technologies, MXenes are among the best active electrode materials. MXene, with its unique 2D layered structure, offers the infinite possibility of the intercalation of various capacitive materials. Also, MXenes have the properties of high hydrophilicity of metal oxides and high electrical conductivity of metals. Alongside, activated carbon (AC), graphene, carbon nanotubes (CNTs), transition metal oxides, and conducting polymers (CPs) act as excellent electrode materials owing to their outstanding thermal, mechanical, electrical, and morphological properties. According to recent studies, one of the perfect methods for energy storage applications is to integrate MXenes with other superior elements for generating MXene-based composite electrode materials. This review includes recent developments in the investigation of MXene-based hybrid composites for supercapacitors. It covers composite's synthesis strategies, electrode architecture, electrochemical performance, and their efficiency in supercapacitors.

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来源期刊
CiteScore
5.80
自引率
6.40%
发文量
174
审稿时长
32 days
期刊介绍: Materials Today Sustainability is a multi-disciplinary journal covering all aspects of sustainability through materials science. With a rapidly increasing population with growing demands, materials science has emerged as a critical discipline toward protecting of the environment and ensuring the long term survival of future generations.
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