Oxyfuel combustion based carbon capture onboard ships

Reducing greenhouse gas emissions in the shipping sector is a challenging task. While renewable fuels stand out as the most promising long-term solution, their near- and mid-term viability is hampered by limited availability and high costs. An alternative approach is onboard carbon capture, which can reduce emissions from new ships as well as retrofitted vessels. This paper examines the techno-economic potential of oxyfuel combustion based carbon capture on ships. The oxyfuel concept uses an oxygen-rich atmosphere in the combustion process, resulting in a mixture of carbon dioxide and water. After the condensation of water, the carbon dioxide rich gas can be directly stored on board. Various onboard oxygen supply concepts are investigated, including different technologies for onboard air separation and liquid oxygen bunkering. Influences on the ship energy system are studied by system simulation of a deep-sea container vessel. Benchmarked against a technologically mature post-combustion carbon capture system, the results show that the oxyfuel concepts have limited competitiveness because of reduced engine efficiencies and high energy demands for onboard oxygen supply. Avoiding onboard oxygen supply by using liquefied oxygen as a byproduct from onshore electrolysis increases energy efficiency and the competitiveness of oxyfuel combustion but requires additional storage space. Sensitivity analyses highlight that the engine combustion concept and engine efficiency are the most critical influences on the techno-economic performance.