粘度对电纺射流弯曲行为的影响:模拟模型和实验

IF 4.1 2区 化学 Q2 POLYMER SCIENCE Polymer Pub Date : 2024-08-21 DOI:10.1016/j.polymer.2024.127529
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摘要

大量实验数据表明,粘度较高的溶液更容易获得较粗的纤维。然而,粘度对射流鞭打行为的影响以及随后对电纺过程中末端纤维形成的影响仍是当前研究的主题。本研究中提出的仿真模型和实验旨在解决这些问题。仿真模型通过改变无量纲参数 Fve 来预测不同粘度对电纺射流弯曲行为的影响,而实验则通过调节溶液浓度来观察不同粘度下的电纺射流弯曲行为。模拟和实验数据的一致性意味着本文结论的准确性。此外,模拟模型和实验还证明,粘度越高,射流轨迹半径越小,射流速度越低,从而形成的纤维越粗。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

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Impacts of viscosity on bending behavior of the electrospun jet: Simulation model and experiment

Numerous experimental data indicate that higher viscosity solutions make it easier to obtain coarser fibers. However, the influences of viscosity on the whipping behavior of the jet and their subsequent impacts on the formation of terminal fiber during electrospinning remain topics of ongoing research. Simulation model and experiment presented in this study aim to solve these problems. The simulation model alters the dimensionless parameter Fve to predict the impacts of different viscosities on the bending behavior of the electrospun jet, while the experiment observes this behavior under different viscosities by regulating the solution concentration. The consistency of the simulation and experimental data implies the accuracy of the conclusions in this paper. Furthermore, the simulation model and experiment have demonstrated that a higher viscosity jet results in a smaller radius of the jet trajectory and lower jet velocity, which in turn leads to the formation of coarser fiber.

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来源期刊
Polymer
Polymer 化学-高分子科学
CiteScore
7.90
自引率
8.70%
发文量
959
审稿时长
32 days
期刊介绍: Polymer is an interdisciplinary journal dedicated to publishing innovative and significant advances in Polymer Physics, Chemistry and Technology. We welcome submissions on polymer hybrids, nanocomposites, characterisation and self-assembly. Polymer also publishes work on the technological application of polymers in energy and optoelectronics. The main scope is covered but not limited to the following core areas: Polymer Materials Nanocomposites and hybrid nanomaterials Polymer blends, films, fibres, networks and porous materials Physical Characterization Characterisation, modelling and simulation* of molecular and materials properties in bulk, solution, and thin films Polymer Engineering Advanced multiscale processing methods Polymer Synthesis, Modification and Self-assembly Including designer polymer architectures, mechanisms and kinetics, and supramolecular polymerization Technological Applications Polymers for energy generation and storage Polymer membranes for separation technology Polymers for opto- and microelectronics.
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