{"title":"合成蒽键合膨松松香苷。","authors":"Bharti Yadav , Mangalampalli Ravikanth","doi":"10.1039/d4ob01283f","DOIUrl":null,"url":null,"abstract":"<div><div>The newly synthesized precursor 1,8-di(1<em>H</em>-pyrrol-2-yl)anthracene was condensed with pentafluorobenzaldehyde under acid-catalyzed conditions to afford the first example of a unique anthracenyl-bridged rosarin. The X-ray structure revealed a coil-like arrangement of three dipyrromethene moieties and three anthracenyl units in the rosarin framework, which exhibits a weak fluorescence at 676 nm.</div></div>","PeriodicalId":2,"journal":{"name":"ACS Applied Bio Materials","volume":null,"pages":null},"PeriodicalIF":4.6000,"publicationDate":"2024-09-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Synthesis of anthracene-bridged expanded rosarin†\",\"authors\":\"Bharti Yadav , Mangalampalli Ravikanth\",\"doi\":\"10.1039/d4ob01283f\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>The newly synthesized precursor 1,8-di(1<em>H</em>-pyrrol-2-yl)anthracene was condensed with pentafluorobenzaldehyde under acid-catalyzed conditions to afford the first example of a unique anthracenyl-bridged rosarin. The X-ray structure revealed a coil-like arrangement of three dipyrromethene moieties and three anthracenyl units in the rosarin framework, which exhibits a weak fluorescence at 676 nm.</div></div>\",\"PeriodicalId\":2,\"journal\":{\"name\":\"ACS Applied Bio Materials\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":4.6000,\"publicationDate\":\"2024-09-25\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"ACS Applied Bio Materials\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/org/science/article/pii/S1477052024007742\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"MATERIALS SCIENCE, BIOMATERIALS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"ACS Applied Bio Materials","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/org/science/article/pii/S1477052024007742","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"MATERIALS SCIENCE, BIOMATERIALS","Score":null,"Total":0}
The newly synthesized precursor 1,8-di(1H-pyrrol-2-yl)anthracene was condensed with pentafluorobenzaldehyde under acid-catalyzed conditions to afford the first example of a unique anthracenyl-bridged rosarin. The X-ray structure revealed a coil-like arrangement of three dipyrromethene moieties and three anthracenyl units in the rosarin framework, which exhibits a weak fluorescence at 676 nm.
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