NiO/MoO2杂化麦壳活性炭上的乙醇电化学氧化。

IF 2.3 4区 物理与天体物理 Q3 PHYSICS, CONDENSED MATTER Journal of Physics: Condensed Matter Pub Date : 2024-08-27 DOI:10.1088/1361-648X/ad7436
Sadegh Azizi, Seyed Mohammad Rozati, Mohammad Bagher Askari, Parisa Salarizadeh
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引用次数: 0

摘要

燃料电池中的乙醇氧化过程在铂催化剂的作用下效率最高。我们的研究团队努力寻找经济高效的催化剂,通过水热法合成了基于镍和钼金属氧化物的催化剂,其形式为 NiO/ MoO2 和 NiO/ MoO2 与从麦壳中提取的活性炭(ACWH)杂化。经过精确的物理表征后,在碱性环境中通过电化学分析测量了这些催化剂在乙醇氧化过程中的能力。催化剂结构中 ACWH 的存在显著提高了活性表面和电催化活性。在峰值电位为 0.55 V 时,NiO/MoO2/ACWH 的电流密度为 16 mA/cm2,在 5000 次交替 CV 循环后,循环稳定性达到 93%。
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Electrochemical oxidation of ethanol on NiO/MoO2 hybridized wheat husk derived activated carbon.

The Ethanol oxidation process in fuel cells is most efficient when conducted by Platinum based catalysts. Our research team endeavored to find affordable and efficient catalysts, synthesizing catalysts based on metal oxides of nickel and molybdenum in the form of NiO/ MoO2 and NiO/ MoO2 hybridized with activated carbon obtained from the wheat husk (ACWH) through a hydrothermal method. After precise physical characterization, the capability of these catalysts in the ethanol oxidation process was measured through electrochemical analyses in an alkaline environment. The presence of ACWH in the catalyst structure significantly improves the active surface and electrocatalytic activity. NiO/MoO2/ACWH with a current density of 16 mA/cm2 at a peak potential of 0.55 V and 93% cyclic stability after 5000 alternate CV cycles, can be an appealing, relatively efficient, and stable option in ethanol oxidation. .

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来源期刊
Journal of Physics: Condensed Matter
Journal of Physics: Condensed Matter 物理-物理:凝聚态物理
CiteScore
5.30
自引率
7.40%
发文量
1288
审稿时长
2.1 months
期刊介绍: Journal of Physics: Condensed Matter covers the whole of condensed matter physics including soft condensed matter and nanostructures. Papers may report experimental, theoretical and simulation studies. Note that papers must contain fundamental condensed matter science: papers reporting methods of materials preparation or properties of materials without novel condensed matter content will not be accepted.
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