掌握水电池中的质子活动

IF 27.4 1区 材料科学 Q1 CHEMISTRY, MULTIDISCIPLINARY Advanced Materials Pub Date : 2024-09-03 DOI:10.1002/adma.202407852
Leiting Zhang, Chao Zhang, Erik J Berg
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引用次数: 0

摘要

先进的水电池是电网储能的理想解决方案。与有机电解质相比,水基电解质具有传输动力学快、安全性高、成本低和环境可持续性强等优点。然而,电解质中存在的由水自发电离产生的质子可能会与主要的电荷存储机制产生竞争,引发不必要的副反应,并加速电池性能的恶化。因此,了解和掌握水电池中的质子活动至关重要。本视角对以下科学问题进行了评论:为什么质子活动具有相关性?什么是质子活动?我们对水性电池中的质子活动了解多少?如何更好地理解、控制和利用质子活动?
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Mastering Proton Activities in Aqueous Batteries.

Advanced aqueous batteries are promising solutions for grid energy storage. Compared with their organic counterparts, water-based electrolytes enable fast transport kinetics, high safety, low cost, and enhanced environmental sustainability. However, the presence of protons in the electrolyte, generated by the spontaneous ionization of water, may compete with the main charge-storage mechanism, trigger unwanted side reactions, and accelerate the deterioration of the cell performance. Therefore, it is of pivotal importance to understand and master the proton activities in aqueous batteries. This Perspective comments on the following scientific questions: Why are proton activities relevant? What are proton activities? What do we know about proton activities in aqueous batteries? How do we better understand, control, and utilize proton activities?

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来源期刊
Advanced Materials
Advanced Materials 工程技术-材料科学:综合
CiteScore
43.00
自引率
4.10%
发文量
2182
审稿时长
2 months
期刊介绍: Advanced Materials, one of the world's most prestigious journals and the foundation of the Advanced portfolio, is the home of choice for best-in-class materials science for more than 30 years. Following this fast-growing and interdisciplinary field, we are considering and publishing the most important discoveries on any and all materials from materials scientists, chemists, physicists, engineers as well as health and life scientists and bringing you the latest results and trends in modern materials-related research every week.
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