新型低氮氧化物漩涡燃烧器与煤-氨联合燃烧:双通道中的氨比例对燃烧和氮氧化物形成的影响

IF 6.9 2区 环境科学与生态学 Q1 ENGINEERING, CHEMICAL Process Safety and Environmental Protection Pub Date : 2024-08-31 DOI:10.1016/j.psep.2024.08.128
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引用次数: 0

摘要

煤-氨联合燃烧是一种减少燃煤锅炉二氧化碳排放的可行技术。然而,由于氨中的氮含量较高,煤氨联合燃烧可能会产生大量氮氧化物。本研究提出了一种新型低氮氧化物漩涡燃烧器,该燃烧器采用可扩展的双通道氨管道,用于煤氨联合燃烧,并评估了双通道(即内通道和外通道)不同氨比例下的燃烧和氮氧化物形成情况。结果表明,氨被注入内再循环区后面的低氧和高二氧化碳环境中,促进了氨的热解,抑制了氨的氧化反应。成功实现了低氮氧化物和高燃烧效率。此外,还观察到双通道的氨比例对燃烧和氮氧化物形成的影响,在高氨混合比例(20%)时很轻微,而在低氨混合比例(10%)时很明显。特别是在低氨水混合比的情况下,外通道中较低的氨水混合比可以使内通道中的氨水流速较高,从而有助于降低氮氧化物。总体而言,在本研究中,低氨掺入比的情况下,氮氧化物(低于 120 ppm)和粉煤灰含碳量(低于 3.50 %)较低,ROC 较低(0.1、0.2)。
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A novel low-NOx swirl burner with coal-ammonia co-firing: Effect of ammonia ratio in the dual channels on combustion and NOx formation

Coal-ammonia co-firing is a promising technology for reducing CO2 emissions in coal-fired boilers. However, coal-ammonia co-firing may cause significant NOx owing to the high nitrogen in ammonia. This study proposes a novel low-NOx swirl burner with a scalable dual-channel ammonia pipe for coal-ammonia co-firing, and evaluates the combustion and NOx formation under different ammonia ratios of the dual channels (i.e., inner and outer channels). The results show that the ammonia is injected into the low-oxygen and high-CO environment behind the internal recirculation zone, contributing to the ammonia pyrolysis and inhibiting the ammonia oxidation reaction. Low NOx is successfully achieved with high combustion efficiency. In addition, it is observed that the effect of the ammonia ratio of the dual channels on the combustion and NOx formation is slight for the high ammonia blending ratio (20 %), while it is prominent for the low ammonia blending ratio (10 %). Especially, for the low ammonia blending ratio, lower ammonia ratio in the outer channel can obtain high velocity of ammonia stream in the inner channel, contributing to NOx reduction. Overall, the cases with lower ROC (0.1, 0.2) are suggested with low NOx (below 120 ppm) and carbon content in fly ash (below 3.50 %) for the low ammonia blending ratio in this study.

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来源期刊
Process Safety and Environmental Protection
Process Safety and Environmental Protection 环境科学-工程:化工
CiteScore
11.40
自引率
15.40%
发文量
929
审稿时长
8.0 months
期刊介绍: The Process Safety and Environmental Protection (PSEP) journal is a leading international publication that focuses on the publication of high-quality, original research papers in the field of engineering, specifically those related to the safety of industrial processes and environmental protection. The journal encourages submissions that present new developments in safety and environmental aspects, particularly those that show how research findings can be applied in process engineering design and practice. PSEP is particularly interested in research that brings fresh perspectives to established engineering principles, identifies unsolved problems, or suggests directions for future research. The journal also values contributions that push the boundaries of traditional engineering and welcomes multidisciplinary papers. PSEP's articles are abstracted and indexed by a range of databases and services, which helps to ensure that the journal's research is accessible and recognized in the academic and professional communities. These databases include ANTE, Chemical Abstracts, Chemical Hazards in Industry, Current Contents, Elsevier Engineering Information database, Pascal Francis, Web of Science, Scopus, Engineering Information Database EnCompass LIT (Elsevier), and INSPEC. This wide coverage facilitates the dissemination of the journal's content to a global audience interested in process safety and environmental engineering.
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