{"title":"地热水、温度和压力对多组分水泥粘结剂水化的影响","authors":"","doi":"10.1016/j.geothermics.2024.103156","DOIUrl":null,"url":null,"abstract":"<div><p>Cement pastes of different compositions were hydrated in a geothermal solution with the simultaneous action of high temperature (150 °C) and pressure (18 MPa) for 7 days. The influence of solution on phase composition and compressive strength of pastes was investigated based on the comparison with hydration in water and using TGA, XRD, FTIR, <sup>29</sup>Si, and <sup>27</sup>Al NMR. The geothermal solution accelerated hydration and pozzolanic reactions. A higher amount of more thermally stable products was formed. Undesired transformation to crystalline α-C<sub>2</sub>SH in the samples with the highest C/S ratio was restricted. The uptake of carbonates from the solution led to an increased amount of calcite. As a result, increased compressive strength values were determined. Preferential incorporation of Al<sup>3+</sup> into the structure of C-(A-)S-H or hydrogrossular phases depended on the composition of cement pastes.</p></div>","PeriodicalId":55095,"journal":{"name":"Geothermics","volume":null,"pages":null},"PeriodicalIF":3.5000,"publicationDate":"2024-09-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"An influence of geothermal water, temperature and pressure on the hydration of multicomponent cement binders\",\"authors\":\"\",\"doi\":\"10.1016/j.geothermics.2024.103156\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Cement pastes of different compositions were hydrated in a geothermal solution with the simultaneous action of high temperature (150 °C) and pressure (18 MPa) for 7 days. The influence of solution on phase composition and compressive strength of pastes was investigated based on the comparison with hydration in water and using TGA, XRD, FTIR, <sup>29</sup>Si, and <sup>27</sup>Al NMR. The geothermal solution accelerated hydration and pozzolanic reactions. A higher amount of more thermally stable products was formed. Undesired transformation to crystalline α-C<sub>2</sub>SH in the samples with the highest C/S ratio was restricted. The uptake of carbonates from the solution led to an increased amount of calcite. As a result, increased compressive strength values were determined. Preferential incorporation of Al<sup>3+</sup> into the structure of C-(A-)S-H or hydrogrossular phases depended on the composition of cement pastes.</p></div>\",\"PeriodicalId\":55095,\"journal\":{\"name\":\"Geothermics\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":3.5000,\"publicationDate\":\"2024-09-07\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Geothermics\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0375650524002426\",\"RegionNum\":2,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"ENERGY & FUELS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Geothermics","FirstCategoryId":"5","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0375650524002426","RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"ENERGY & FUELS","Score":null,"Total":0}
An influence of geothermal water, temperature and pressure on the hydration of multicomponent cement binders
Cement pastes of different compositions were hydrated in a geothermal solution with the simultaneous action of high temperature (150 °C) and pressure (18 MPa) for 7 days. The influence of solution on phase composition and compressive strength of pastes was investigated based on the comparison with hydration in water and using TGA, XRD, FTIR, 29Si, and 27Al NMR. The geothermal solution accelerated hydration and pozzolanic reactions. A higher amount of more thermally stable products was formed. Undesired transformation to crystalline α-C2SH in the samples with the highest C/S ratio was restricted. The uptake of carbonates from the solution led to an increased amount of calcite. As a result, increased compressive strength values were determined. Preferential incorporation of Al3+ into the structure of C-(A-)S-H or hydrogrossular phases depended on the composition of cement pastes.
期刊介绍:
Geothermics is an international journal devoted to the research and development of geothermal energy. The International Board of Editors of Geothermics, which comprises specialists in the various aspects of geothermal resources, exploration and development, guarantees the balanced, comprehensive view of scientific and technological developments in this promising energy field.
It promulgates the state of the art and science of geothermal energy, its exploration and exploitation through a regular exchange of information from all parts of the world. The journal publishes articles dealing with the theory, exploration techniques and all aspects of the utilization of geothermal resources. Geothermics serves as the scientific house, or exchange medium, through which the growing community of geothermal specialists can provide and receive information.