Assessment of thermal power plant CO2 emissions quantification performance and uncertainty of measurements by ground-based remote sensing.

Thermal power plants serve as significant CO₂ sources, and accurate monitoring of their emissions is crucial for improving the precision of global carbon emission estimates. In this study, a measurement method based on measuring point source plumes was employed in ground-based remote sensing experiments at the thermal power plant. By simulating CO₂ plumes, we analyzed the impact of surrounding urban structures, the geometric relationship between measurement points and plumes, and the influence on measurement points selection. We also assessed the capability and uncertainties in quantifying CO₂ emissions. For the Hefei power plant, CO₂ emission estimates were on average 7.98 10.01 kg/s higher with surface buildings compared to scenarios without buildings (approximately 4.09% error). By selectively filtering discrete data, the emission estimation errors were significantly reduced by 7.31 7.13 kg/s compared to pre-filtered data. Regarding the relationship between observation paths and plume geometry, simulation studies indicated that the ability to estimate CO₂ emissions varied for near and middle segment observations. The lowest emission rate error was found in the mid-segment near 1.5-2.0 km, reaching 7.13 5.39 kg/s. CO₂ distribution at the mid-segment position becomes more uniform relative to the near segment, making it more suitable for meeting emission estimation requirements. Optimizing measurement schemes by considering environmental factors and precisely selecting measurement points significantly enhances emission estimation accuracy, providing crucial technical support for top-down estimates of anthropogenic CO₂ emissions.