{"title":"脉冲电晕放电氧化溴水","authors":"Irina Petrochenko, Sergei Preis","doi":"10.1016/j.elstat.2024.103978","DOIUrl":null,"url":null,"abstract":"<div><p>Bromide in treated natural waters is oxidized to toxic bromate with ozone. For the novelty of pulsed corona discharge (PCD) in water treatment, it's potential in bromide transformation needs clarification. Experimental research into bromide-bromate conversion dependent on control parameters, including pulse repetition frequency, pH, Br<sup>−</sup> concentration, and presence of organics, was undertaken. Bromide transformed to bromate in acidic and circum-neutral media; transformation of bromate to bromide was also observed. Bromide was poorly oxidized in alkaline media. Oxidation of bromide was obstructed with oxalate. Formation of nitrate was noticeably decelerated by bromate.</p></div>","PeriodicalId":54842,"journal":{"name":"Journal of Electrostatics","volume":null,"pages":null},"PeriodicalIF":1.9000,"publicationDate":"2024-09-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Aqueous bromide oxidized with pulsed corona discharge\",\"authors\":\"Irina Petrochenko, Sergei Preis\",\"doi\":\"10.1016/j.elstat.2024.103978\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Bromide in treated natural waters is oxidized to toxic bromate with ozone. For the novelty of pulsed corona discharge (PCD) in water treatment, it's potential in bromide transformation needs clarification. Experimental research into bromide-bromate conversion dependent on control parameters, including pulse repetition frequency, pH, Br<sup>−</sup> concentration, and presence of organics, was undertaken. Bromide transformed to bromate in acidic and circum-neutral media; transformation of bromate to bromide was also observed. Bromide was poorly oxidized in alkaline media. Oxidation of bromide was obstructed with oxalate. Formation of nitrate was noticeably decelerated by bromate.</p></div>\",\"PeriodicalId\":54842,\"journal\":{\"name\":\"Journal of Electrostatics\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":1.9000,\"publicationDate\":\"2024-09-09\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Electrostatics\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0304388624000858\",\"RegionNum\":4,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"ENGINEERING, ELECTRICAL & ELECTRONIC\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Electrostatics","FirstCategoryId":"5","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0304388624000858","RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"ENGINEERING, ELECTRICAL & ELECTRONIC","Score":null,"Total":0}
Aqueous bromide oxidized with pulsed corona discharge
Bromide in treated natural waters is oxidized to toxic bromate with ozone. For the novelty of pulsed corona discharge (PCD) in water treatment, it's potential in bromide transformation needs clarification. Experimental research into bromide-bromate conversion dependent on control parameters, including pulse repetition frequency, pH, Br− concentration, and presence of organics, was undertaken. Bromide transformed to bromate in acidic and circum-neutral media; transformation of bromate to bromide was also observed. Bromide was poorly oxidized in alkaline media. Oxidation of bromide was obstructed with oxalate. Formation of nitrate was noticeably decelerated by bromate.
期刊介绍:
The Journal of Electrostatics is the leading forum for publishing research findings that advance knowledge in the field of electrostatics. We invite submissions in the following areas:
Electrostatic charge separation processes.
Electrostatic manipulation of particles, droplets, and biological cells.
Electrostatically driven or controlled fluid flow.
Electrostatics in the gas phase.