{"title":"确定单轴拉伸后微观结构方案的聚(2,5-呋喃二甲酸乙烯酯)极值图:取向与结晶之间的联系","authors":"","doi":"10.1016/j.polymer.2024.127613","DOIUrl":null,"url":null,"abstract":"<div><p>The emergent biobased polymer poly (ethylene 2,5-furandicarboxylate), PEF, has been studied through an innovative approach based on pole figures and orientation factor calculation. PEF uniaxial stretching was performed with different mechanical conditions (different equivalent strain rates), up to several levels of strain and while considering different post-stretching cooling conditions (interrupted, unloaded and ruptured samples). Samples were stretched and interrupted before and after the Natural Draw Ratio (NDR), the deformation for which the material starts strain-hardening. When PEF strain-hardens, it reveals both an increase of the crystalline orientation and crystallinity ratio with the deformation imposed. Unloading the material at temperature tends to decrease partially crystalline orientation, especially regarding the aliphatic part of the chains. Moreover, stretching PEF up to high strains, superior to the NDR, leads to crystal fragmentation. After all, all experimental results were compared to a texture model. It appears that a texture can be developed upon stretching that is close to a fibre texture, as the furan cycles tend to be parallel to the specimen plane.</p></div>","PeriodicalId":405,"journal":{"name":"Polymer","volume":null,"pages":null},"PeriodicalIF":4.1000,"publicationDate":"2024-09-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Poly(ethylene 2,5-furandicarboxylate) pole figures to determine the microstructural scheme upon uniaxial stretching: Link between orientation and crystallisation\",\"authors\":\"\",\"doi\":\"10.1016/j.polymer.2024.127613\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The emergent biobased polymer poly (ethylene 2,5-furandicarboxylate), PEF, has been studied through an innovative approach based on pole figures and orientation factor calculation. PEF uniaxial stretching was performed with different mechanical conditions (different equivalent strain rates), up to several levels of strain and while considering different post-stretching cooling conditions (interrupted, unloaded and ruptured samples). Samples were stretched and interrupted before and after the Natural Draw Ratio (NDR), the deformation for which the material starts strain-hardening. When PEF strain-hardens, it reveals both an increase of the crystalline orientation and crystallinity ratio with the deformation imposed. Unloading the material at temperature tends to decrease partially crystalline orientation, especially regarding the aliphatic part of the chains. Moreover, stretching PEF up to high strains, superior to the NDR, leads to crystal fragmentation. After all, all experimental results were compared to a texture model. It appears that a texture can be developed upon stretching that is close to a fibre texture, as the furan cycles tend to be parallel to the specimen plane.</p></div>\",\"PeriodicalId\":405,\"journal\":{\"name\":\"Polymer\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":4.1000,\"publicationDate\":\"2024-09-10\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Polymer\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0032386124009492\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"POLYMER SCIENCE\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Polymer","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0032386124009492","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"POLYMER SCIENCE","Score":null,"Total":0}
Poly(ethylene 2,5-furandicarboxylate) pole figures to determine the microstructural scheme upon uniaxial stretching: Link between orientation and crystallisation
The emergent biobased polymer poly (ethylene 2,5-furandicarboxylate), PEF, has been studied through an innovative approach based on pole figures and orientation factor calculation. PEF uniaxial stretching was performed with different mechanical conditions (different equivalent strain rates), up to several levels of strain and while considering different post-stretching cooling conditions (interrupted, unloaded and ruptured samples). Samples were stretched and interrupted before and after the Natural Draw Ratio (NDR), the deformation for which the material starts strain-hardening. When PEF strain-hardens, it reveals both an increase of the crystalline orientation and crystallinity ratio with the deformation imposed. Unloading the material at temperature tends to decrease partially crystalline orientation, especially regarding the aliphatic part of the chains. Moreover, stretching PEF up to high strains, superior to the NDR, leads to crystal fragmentation. After all, all experimental results were compared to a texture model. It appears that a texture can be developed upon stretching that is close to a fibre texture, as the furan cycles tend to be parallel to the specimen plane.
期刊介绍:
Polymer is an interdisciplinary journal dedicated to publishing innovative and significant advances in Polymer Physics, Chemistry and Technology. We welcome submissions on polymer hybrids, nanocomposites, characterisation and self-assembly. Polymer also publishes work on the technological application of polymers in energy and optoelectronics.
The main scope is covered but not limited to the following core areas:
Polymer Materials
Nanocomposites and hybrid nanomaterials
Polymer blends, films, fibres, networks and porous materials
Physical Characterization
Characterisation, modelling and simulation* of molecular and materials properties in bulk, solution, and thin films
Polymer Engineering
Advanced multiscale processing methods
Polymer Synthesis, Modification and Self-assembly
Including designer polymer architectures, mechanisms and kinetics, and supramolecular polymerization
Technological Applications
Polymers for energy generation and storage
Polymer membranes for separation technology
Polymers for opto- and microelectronics.