Yihong Li , Zhaozhao Gao , Junxian Li , Zhikang Wang , Xiaoyu Fan , Wei Ji , Liubiao Chen , Junjie Wang
{"title":"氮在丙烷中的扩散溶解度：在 0.1 兆帕斯卡压力下从 96 K 到 227 K 的测量结果","authors":"Yihong Li , Zhaozhao Gao , Junxian Li , Zhikang Wang , Xiaoyu Fan , Wei Ji , Liubiao Chen , Junjie Wang","doi":"10.1016/j.cryogenics.2024.103944","DOIUrl":null,"url":null,"abstract":"<div><p>The burgeoning demand for large-scale energy storage has catalyzed the advancement of Liquid Air Energy Storage (LAES) technology. However, the liquid-phase propane cold storage process in LAES systems encounters a significant challenge: the dissolution of nitrogen protection gas in propane poses a substantial risk to both operational safety and performance. Given the dearth of data on the diffusive solubility of nitrogen in propane under constant atmospheric pressure and low-temperature conditions, this study constructed a testbench and conducted experiments within a temperature range of 96–227 K at a pressure of 0.1 MPa. The molar diffusive solubilities at 227 K, 176 K, 139 K, and 96 K are 0.030 %, 0.177 %, 0.297 %, and 0.962 %, respectively. Besides, this study also fits a calculation equation for the diffusive solubility of nitrogen in propane, which applies to the propane cold storage process in LAES systems.</p></div>","PeriodicalId":10812,"journal":{"name":"Cryogenics","volume":"143 ","pages":"Article 103944"},"PeriodicalIF":1.8000,"publicationDate":"2024-09-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Diffusive solubility of nitrogen in Propane: Measurement from 96 K to 227 K at 0.1 MPa\",\"authors\":\"Yihong Li , Zhaozhao Gao , Junxian Li , Zhikang Wang , Xiaoyu Fan , Wei Ji , Liubiao Chen , Junjie Wang\",\"doi\":\"10.1016/j.cryogenics.2024.103944\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The burgeoning demand for large-scale energy storage has catalyzed the advancement of Liquid Air Energy Storage (LAES) technology. However, the liquid-phase propane cold storage process in LAES systems encounters a significant challenge: the dissolution of nitrogen protection gas in propane poses a substantial risk to both operational safety and performance. Given the dearth of data on the diffusive solubility of nitrogen in propane under constant atmospheric pressure and low-temperature conditions, this study constructed a testbench and conducted experiments within a temperature range of 96–227 K at a pressure of 0.1 MPa. The molar diffusive solubilities at 227 K, 176 K, 139 K, and 96 K are 0.030 %, 0.177 %, 0.297 %, and 0.962 %, respectively. Besides, this study also fits a calculation equation for the diffusive solubility of nitrogen in propane, which applies to the propane cold storage process in LAES systems.</p></div>\",\"PeriodicalId\":10812,\"journal\":{\"name\":\"Cryogenics\",\"volume\":\"143 \",\"pages\":\"Article 103944\"},\"PeriodicalIF\":1.8000,\"publicationDate\":\"2024-09-07\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Cryogenics\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0011227524001644\",\"RegionNum\":3,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"PHYSICS, APPLIED\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Cryogenics","FirstCategoryId":"5","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0011227524001644","RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"PHYSICS, APPLIED","Score":null,"Total":0}
Diffusive solubility of nitrogen in Propane: Measurement from 96 K to 227 K at 0.1 MPa
The burgeoning demand for large-scale energy storage has catalyzed the advancement of Liquid Air Energy Storage (LAES) technology. However, the liquid-phase propane cold storage process in LAES systems encounters a significant challenge: the dissolution of nitrogen protection gas in propane poses a substantial risk to both operational safety and performance. Given the dearth of data on the diffusive solubility of nitrogen in propane under constant atmospheric pressure and low-temperature conditions, this study constructed a testbench and conducted experiments within a temperature range of 96–227 K at a pressure of 0.1 MPa. The molar diffusive solubilities at 227 K, 176 K, 139 K, and 96 K are 0.030 %, 0.177 %, 0.297 %, and 0.962 %, respectively. Besides, this study also fits a calculation equation for the diffusive solubility of nitrogen in propane, which applies to the propane cold storage process in LAES systems.
期刊介绍：
Cryogenics is the world''s leading journal focusing on all aspects of cryoengineering and cryogenics. Papers published in Cryogenics cover a wide variety of subjects in low temperature engineering and research. Among the areas covered are:
- Applications of superconductivity: magnets, electronics, devices
- Superconductors and their properties
- Properties of materials: metals, alloys, composites, polymers, insulations
- New applications of cryogenic technology to processes, devices, machinery
- Refrigeration and liquefaction technology
- Thermodynamics
- Fluid properties and fluid mechanics
- Heat transfer
- Thermometry and measurement science
- Cryogenics in medicine
- Cryoelectronics
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