{"title":"推进芳香酮作为芳基亲电子体在多功能交叉偶联反应中的应用","authors":"","doi":"10.1016/j.chempr.2024.08.014","DOIUrl":null,"url":null,"abstract":"<div><p>In this issue of <em>Chem</em>, Yamaguchi and coworkers introduce an exciting strategy for the deacylative cross-coupling of aromatic ketones. Aromatic ketones are first converted into aromatic esters via sequential Claisen and regioselective retro-Claisen condensation. The esters then undergo transition-metal-catalyzed decarbonylative cross-coupling reactions with various nucleophiles affording C–C and C–heteroatom bond formation products.</p></div>","PeriodicalId":268,"journal":{"name":"Chem","volume":null,"pages":null},"PeriodicalIF":19.1000,"publicationDate":"2024-09-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Advancing aromatic ketones as aryl electrophiles in versatile cross-coupling reactions\",\"authors\":\"\",\"doi\":\"10.1016/j.chempr.2024.08.014\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>In this issue of <em>Chem</em>, Yamaguchi and coworkers introduce an exciting strategy for the deacylative cross-coupling of aromatic ketones. Aromatic ketones are first converted into aromatic esters via sequential Claisen and regioselective retro-Claisen condensation. The esters then undergo transition-metal-catalyzed decarbonylative cross-coupling reactions with various nucleophiles affording C–C and C–heteroatom bond formation products.</p></div>\",\"PeriodicalId\":268,\"journal\":{\"name\":\"Chem\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":19.1000,\"publicationDate\":\"2024-09-12\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Chem\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S2451929424004297\",\"RegionNum\":1,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chem","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2451929424004297","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Advancing aromatic ketones as aryl electrophiles in versatile cross-coupling reactions
In this issue of Chem, Yamaguchi and coworkers introduce an exciting strategy for the deacylative cross-coupling of aromatic ketones. Aromatic ketones are first converted into aromatic esters via sequential Claisen and regioselective retro-Claisen condensation. The esters then undergo transition-metal-catalyzed decarbonylative cross-coupling reactions with various nucleophiles affording C–C and C–heteroatom bond formation products.
期刊介绍：
Chem, affiliated with Cell as its sister journal, serves as a platform for groundbreaking research and illustrates how fundamental inquiries in chemistry and its related fields can contribute to addressing future global challenges. It was established in 2016, and is currently edited by Robert Eagling.
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