Palash Godani , T. Shanmuga Priya , U. Johnson Alengaram
{"title":"环境固化条件下基于 GGBS-MBS 的预拌土工聚合物的化学物理力学特性评估","authors":"Palash Godani , T. Shanmuga Priya , U. Johnson Alengaram","doi":"10.1016/j.conbuildmat.2024.138202","DOIUrl":null,"url":null,"abstract":"<div><p>This research demonstrates the synthesis of GGBS-based ready-mix (one-part) geopolymer (RMG) utilizing MBS as partial replacement to GGBS (10, 20 and 30 % by-mass) in addition to solid-alkaline reagents (NaOH-flakes and Na<sub>2</sub>SiO<sub>3</sub> powder) using thermal and mechanical treatments, resulting in the formation of “ready-to-use” geopolymer product, “just-add-water” alike cement. The RMG was characterized by analyzing mineral phases, functional-groups identification followed by surface-morphology and elemental analysis at multiple stages, and engineering properties such as setting-time, flowability, compressive strength and ultrasonic-pulse-velocity were evaluated under ambient curing condition. The results show that GGBS-MBS-based RMG has dense morphology, affirming the development of C-S-H and C(N)-A-S-H gels due to its amorphous nature with some crystalline-phases (SiO<sub>2</sub>) which are in-linked to Si-O-Si and Al-O-Si bonds. The dry-mix of GGBS with powdered-Na<sub>2</sub>SiO<sub>3</sub> and 4 m molality NaOH (Na<sub>2</sub>SiO<sub>3</sub>/NaOH=1), pre-heated at 105±5°C for 6 h, followed by 6 h ball-milling with 20 % MBS replacement, achieved the highest 28-day compressive strength of 72.8 MPa, 10 % higher than the referenced mix and had satisfactory UPV results. The RMG not only solves handling problems caused due to concentrated aqueous-alkaline reagents used in two-part geopolymer synthesis but also provides sustainability by utilizing industrial and agricultural waste/by-products, hence reducing Portland cement demand, carbon footprint and waste-disposal issues.</p></div>","PeriodicalId":7,"journal":{"name":"ACS Applied Polymer Materials","volume":"449 ","pages":"Article 138202"},"PeriodicalIF":4.4000,"publicationDate":"2024-09-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Evaluation of chemo-physio-mechanical characteristics of GGBS-MBS-based ready-mix geopolymer under ambient curing condition\",\"authors\":\"Palash Godani , T. Shanmuga Priya , U. Johnson Alengaram\",\"doi\":\"10.1016/j.conbuildmat.2024.138202\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>This research demonstrates the synthesis of GGBS-based ready-mix (one-part) geopolymer (RMG) utilizing MBS as partial replacement to GGBS (10, 20 and 30 % by-mass) in addition to solid-alkaline reagents (NaOH-flakes and Na<sub>2</sub>SiO<sub>3</sub> powder) using thermal and mechanical treatments, resulting in the formation of “ready-to-use” geopolymer product, “just-add-water” alike cement. The RMG was characterized by analyzing mineral phases, functional-groups identification followed by surface-morphology and elemental analysis at multiple stages, and engineering properties such as setting-time, flowability, compressive strength and ultrasonic-pulse-velocity were evaluated under ambient curing condition. The results show that GGBS-MBS-based RMG has dense morphology, affirming the development of C-S-H and C(N)-A-S-H gels due to its amorphous nature with some crystalline-phases (SiO<sub>2</sub>) which are in-linked to Si-O-Si and Al-O-Si bonds. The dry-mix of GGBS with powdered-Na<sub>2</sub>SiO<sub>3</sub> and 4 m molality NaOH (Na<sub>2</sub>SiO<sub>3</sub>/NaOH=1), pre-heated at 105±5°C for 6 h, followed by 6 h ball-milling with 20 % MBS replacement, achieved the highest 28-day compressive strength of 72.8 MPa, 10 % higher than the referenced mix and had satisfactory UPV results. The RMG not only solves handling problems caused due to concentrated aqueous-alkaline reagents used in two-part geopolymer synthesis but also provides sustainability by utilizing industrial and agricultural waste/by-products, hence reducing Portland cement demand, carbon footprint and waste-disposal issues.</p></div>\",\"PeriodicalId\":7,\"journal\":{\"name\":\"ACS Applied Polymer Materials\",\"volume\":\"449 \",\"pages\":\"Article 138202\"},\"PeriodicalIF\":4.4000,\"publicationDate\":\"2024-09-12\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"ACS Applied Polymer Materials\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0950061824033440\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"MATERIALS SCIENCE, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"ACS Applied Polymer Materials","FirstCategoryId":"5","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0950061824033440","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
Evaluation of chemo-physio-mechanical characteristics of GGBS-MBS-based ready-mix geopolymer under ambient curing condition
This research demonstrates the synthesis of GGBS-based ready-mix (one-part) geopolymer (RMG) utilizing MBS as partial replacement to GGBS (10, 20 and 30 % by-mass) in addition to solid-alkaline reagents (NaOH-flakes and Na2SiO3 powder) using thermal and mechanical treatments, resulting in the formation of “ready-to-use” geopolymer product, “just-add-water” alike cement. The RMG was characterized by analyzing mineral phases, functional-groups identification followed by surface-morphology and elemental analysis at multiple stages, and engineering properties such as setting-time, flowability, compressive strength and ultrasonic-pulse-velocity were evaluated under ambient curing condition. The results show that GGBS-MBS-based RMG has dense morphology, affirming the development of C-S-H and C(N)-A-S-H gels due to its amorphous nature with some crystalline-phases (SiO2) which are in-linked to Si-O-Si and Al-O-Si bonds. The dry-mix of GGBS with powdered-Na2SiO3 and 4 m molality NaOH (Na2SiO3/NaOH=1), pre-heated at 105±5°C for 6 h, followed by 6 h ball-milling with 20 % MBS replacement, achieved the highest 28-day compressive strength of 72.8 MPa, 10 % higher than the referenced mix and had satisfactory UPV results. The RMG not only solves handling problems caused due to concentrated aqueous-alkaline reagents used in two-part geopolymer synthesis but also provides sustainability by utilizing industrial and agricultural waste/by-products, hence reducing Portland cement demand, carbon footprint and waste-disposal issues.
期刊介绍:
ACS Applied Polymer Materials is an interdisciplinary journal publishing original research covering all aspects of engineering, chemistry, physics, and biology relevant to applications of polymers.
The journal is devoted to reports of new and original experimental and theoretical research of an applied nature that integrates fundamental knowledge in the areas of materials, engineering, physics, bioscience, polymer science and chemistry into important polymer applications. The journal is specifically interested in work that addresses relationships among structure, processing, morphology, chemistry, properties, and function as well as work that provide insights into mechanisms critical to the performance of the polymer for applications.