环境固化条件下基于 GGBS-MBS 的预拌土工聚合物的化学物理力学特性评估

IF 4.4 2区 化学 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY ACS Applied Polymer Materials Pub Date : 2024-09-12 DOI:10.1016/j.conbuildmat.2024.138202
Palash Godani , T. Shanmuga Priya , U. Johnson Alengaram
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引用次数: 0

摘要

本研究展示了基于 GGBS 的预拌(单组分)土工聚合物(RMG)的合成方法,利用 MBS 作为 GGBS 的部分替代物(10%、20% 和 30%(质量百分比)),再加上固碱试剂(NaOH 片和 Na2SiO3 粉),通过热处理和机械处理,形成 "即用型 "土工聚合物产品,即 "加水型 "类似水泥。通过分析矿物相、官能团鉴定以及表面形态和元素分析等多个阶段对 RMG 进行了表征,并在常温固化条件下对凝结时间、流动性、抗压强度和超声波脉冲速度等工程特性进行了评估。结果表明,基于 GGBS-MBS 的 RMG 具有致密的形态,肯定了 C-S-H 和 C(N)-A-S-H 凝胶的发展,这是因为其无定形性质中含有一些晶相(SiO2),这些晶相与 Si-O-Si 和 Al-O-Si 键相连。GGBS 与粉末状 Na2SiO3 和 4 m 摩尔 NaOH(Na2SiO3/NaOH=1)的干混料在 105±5°C 下预热 6 小时,然后进行 6 小时球磨,MBS 替代率为 20%,28 天抗压强度最高,达到 72.8 MPa,比参考混合物高 10%,UPV 结果也令人满意。RMG 不仅解决了双组分土工聚合物合成中使用的高浓度水碱试剂造成的处理问题,还通过利用工业和农业废物/副产品实现了可持续发展,从而减少了对波特兰水泥的需求、碳足迹和废物处置问题。
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Evaluation of chemo-physio-mechanical characteristics of GGBS-MBS-based ready-mix geopolymer under ambient curing condition

This research demonstrates the synthesis of GGBS-based ready-mix (one-part) geopolymer (RMG) utilizing MBS as partial replacement to GGBS (10, 20 and 30 % by-mass) in addition to solid-alkaline reagents (NaOH-flakes and Na2SiO3 powder) using thermal and mechanical treatments, resulting in the formation of “ready-to-use” geopolymer product, “just-add-water” alike cement. The RMG was characterized by analyzing mineral phases, functional-groups identification followed by surface-morphology and elemental analysis at multiple stages, and engineering properties such as setting-time, flowability, compressive strength and ultrasonic-pulse-velocity were evaluated under ambient curing condition. The results show that GGBS-MBS-based RMG has dense morphology, affirming the development of C-S-H and C(N)-A-S-H gels due to its amorphous nature with some crystalline-phases (SiO2) which are in-linked to Si-O-Si and Al-O-Si bonds. The dry-mix of GGBS with powdered-Na2SiO3 and 4 m molality NaOH (Na2SiO3/NaOH=1), pre-heated at 105±5°C for 6 h, followed by 6 h ball-milling with 20 % MBS replacement, achieved the highest 28-day compressive strength of 72.8 MPa, 10 % higher than the referenced mix and had satisfactory UPV results. The RMG not only solves handling problems caused due to concentrated aqueous-alkaline reagents used in two-part geopolymer synthesis but also provides sustainability by utilizing industrial and agricultural waste/by-products, hence reducing Portland cement demand, carbon footprint and waste-disposal issues.

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来源期刊
CiteScore
7.20
自引率
6.00%
发文量
810
期刊介绍: ACS Applied Polymer Materials is an interdisciplinary journal publishing original research covering all aspects of engineering, chemistry, physics, and biology relevant to applications of polymers. The journal is devoted to reports of new and original experimental and theoretical research of an applied nature that integrates fundamental knowledge in the areas of materials, engineering, physics, bioscience, polymer science and chemistry into important polymer applications. The journal is specifically interested in work that addresses relationships among structure, processing, morphology, chemistry, properties, and function as well as work that provide insights into mechanisms critical to the performance of the polymer for applications.
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