Xiaowu Hu , Fabio Piccinelli , Silvia Ruggieri , Pablo Camarero Linares , Patricia Haro , Marco Bettinelli
{"title":"导致镱富集的 Sr3Yb0.98Er0.02(PO4)3 eulytite 中发生强烈的近红外-红外上转换的能量转移过程","authors":"Xiaowu Hu , Fabio Piccinelli , Silvia Ruggieri , Pablo Camarero Linares , Patricia Haro , Marco Bettinelli","doi":"10.1016/j.omx.2024.100358","DOIUrl":null,"url":null,"abstract":"<div><p>The optical spectroscopy and the decay kinetics of samples with composition Sr<sub>3</sub>Yb(PO<sub>4</sub>)<sub>3</sub>, Sr<sub>3</sub>Y<sub>0.98</sub>Yb<sub>0.02</sub>(PO<sub>4</sub>)<sub>3</sub>, Sr<sub>3</sub>Y<sub>0.98</sub>Er<sub>0.02</sub>(PO<sub>4</sub>)<sub>3</sub> and Sr<sub>3</sub>Yb<sub>0.98</sub>Er<sub>0.02</sub>(PO<sub>4</sub>)<sub>3</sub> have been studied at room temperature. The presence of efficient energy transfer and migration processes has been clearly evidenced in the Sr<sub>3</sub>Yb(PO<sub>4</sub>)<sub>3</sub> and Sr<sub>3</sub>Yb<sub>0.98</sub>Er<sub>0.02</sub>(PO<sub>4</sub>)<sub>3</sub> materials, giving rise to strong visible upconversion upon excitation in the spectral region around 1 μm in the latter material. The strong anti-Stokes emission is connected to fast migration in the <sup>2</sup>F<sub>5/2</sub> level of Yb<sup>3+</sup>, due to the inefficient concentration quenching for this ion. In this class of materials, the upconversion processes could be optimized even in the presence of high concentrations of the Yb<sup>3+</sup> sensitizer.</p></div>","PeriodicalId":52192,"journal":{"name":"Optical Materials: X","volume":"24 ","pages":"Article 100358"},"PeriodicalIF":0.0000,"publicationDate":"2024-09-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2590147824000706/pdfft?md5=0ac6e7c411764cff7996f7b7f673be53&pid=1-s2.0-S2590147824000706-main.pdf","citationCount":"0","resultStr":"{\"title\":\"Energy transfer processes leading to strong NIR-to-red upconversion in the Yb-concentrated Sr3Yb0.98Er0.02(PO4)3 eulytite\",\"authors\":\"Xiaowu Hu , Fabio Piccinelli , Silvia Ruggieri , Pablo Camarero Linares , Patricia Haro , Marco Bettinelli\",\"doi\":\"10.1016/j.omx.2024.100358\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The optical spectroscopy and the decay kinetics of samples with composition Sr<sub>3</sub>Yb(PO<sub>4</sub>)<sub>3</sub>, Sr<sub>3</sub>Y<sub>0.98</sub>Yb<sub>0.02</sub>(PO<sub>4</sub>)<sub>3</sub>, Sr<sub>3</sub>Y<sub>0.98</sub>Er<sub>0.02</sub>(PO<sub>4</sub>)<sub>3</sub> and Sr<sub>3</sub>Yb<sub>0.98</sub>Er<sub>0.02</sub>(PO<sub>4</sub>)<sub>3</sub> have been studied at room temperature. The presence of efficient energy transfer and migration processes has been clearly evidenced in the Sr<sub>3</sub>Yb(PO<sub>4</sub>)<sub>3</sub> and Sr<sub>3</sub>Yb<sub>0.98</sub>Er<sub>0.02</sub>(PO<sub>4</sub>)<sub>3</sub> materials, giving rise to strong visible upconversion upon excitation in the spectral region around 1 μm in the latter material. The strong anti-Stokes emission is connected to fast migration in the <sup>2</sup>F<sub>5/2</sub> level of Yb<sup>3+</sup>, due to the inefficient concentration quenching for this ion. In this class of materials, the upconversion processes could be optimized even in the presence of high concentrations of the Yb<sup>3+</sup> sensitizer.</p></div>\",\"PeriodicalId\":52192,\"journal\":{\"name\":\"Optical Materials: X\",\"volume\":\"24 \",\"pages\":\"Article 100358\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2024-09-11\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://www.sciencedirect.com/science/article/pii/S2590147824000706/pdfft?md5=0ac6e7c411764cff7996f7b7f673be53&pid=1-s2.0-S2590147824000706-main.pdf\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Optical Materials: X\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S2590147824000706\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"Engineering\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Optical Materials: X","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2590147824000706","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"Engineering","Score":null,"Total":0}
Energy transfer processes leading to strong NIR-to-red upconversion in the Yb-concentrated Sr3Yb0.98Er0.02(PO4)3 eulytite
The optical spectroscopy and the decay kinetics of samples with composition Sr3Yb(PO4)3, Sr3Y0.98Yb0.02(PO4)3, Sr3Y0.98Er0.02(PO4)3 and Sr3Yb0.98Er0.02(PO4)3 have been studied at room temperature. The presence of efficient energy transfer and migration processes has been clearly evidenced in the Sr3Yb(PO4)3 and Sr3Yb0.98Er0.02(PO4)3 materials, giving rise to strong visible upconversion upon excitation in the spectral region around 1 μm in the latter material. The strong anti-Stokes emission is connected to fast migration in the 2F5/2 level of Yb3+, due to the inefficient concentration quenching for this ion. In this class of materials, the upconversion processes could be optimized even in the presence of high concentrations of the Yb3+ sensitizer.
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