{"title":"金涂层氧化铁磁性纳米粒子在水中催化的醇类氧化反应","authors":"Neda Motaghed, Rakhshan Hakimelahi, Majid Moghadam, Sahar Baniyaghoob","doi":"10.1007/s13738-024-03068-w","DOIUrl":null,"url":null,"abstract":"<div><p>Gold-coated magnetic iron oxide nanoparticles (ION) (Fe<sub>3</sub>O<sub>4</sub>@Au) were synthesized and utilized as catalyst for alcohol oxidation with <i>tert</i>-butyl hydroperoxide (TBHP). First, iron oxide magnetic nanoparticles (Fe<sub>3</sub>O<sub>4</sub>) were prepared and finally coated with a thin layer of gold. Structure and composition of Fe<sub>3</sub>O<sub>4</sub>@Au nanocatalyst were characterized by XRD, TGA, and FT-IR analysis. Size and morphology and size of particles were determined through TEM. Surface properties and topographies of coated nanoparticles were investigated by the AFM technique. The magnetic properties of Fe<sub>3</sub>O<sub>4</sub> and Fe<sub>3</sub>O<sub>4</sub>@Au nanoparticles were measured by VSM technique. After confirming the structure of gold-coated magnetic ION, its performance for the oxidation of various aliphatic and aromatic alcohols with TBHP was studied in water. Finally, the reusability of Fe<sub>3</sub>O<sub>4</sub>@Au nanocatalyst was evaluated after five consecutive cycles in the 4-methoxybenzyl alcohol oxidation. The measured results revealed that the gold-coated iron oxide magnetic nanoparticles can be reused well in the oxidation processes of alcohols with high efficiency.</p></div>","PeriodicalId":676,"journal":{"name":"Journal of the Iranian Chemical Society","volume":"21 9","pages":"2315 - 2324"},"PeriodicalIF":2.2000,"publicationDate":"2024-08-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Catalytic oxidation of alcohols catalyzed by gold-coated iron oxide magnetic nanoparticles in water\",\"authors\":\"Neda Motaghed, Rakhshan Hakimelahi, Majid Moghadam, Sahar Baniyaghoob\",\"doi\":\"10.1007/s13738-024-03068-w\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Gold-coated magnetic iron oxide nanoparticles (ION) (Fe<sub>3</sub>O<sub>4</sub>@Au) were synthesized and utilized as catalyst for alcohol oxidation with <i>tert</i>-butyl hydroperoxide (TBHP). First, iron oxide magnetic nanoparticles (Fe<sub>3</sub>O<sub>4</sub>) were prepared and finally coated with a thin layer of gold. Structure and composition of Fe<sub>3</sub>O<sub>4</sub>@Au nanocatalyst were characterized by XRD, TGA, and FT-IR analysis. Size and morphology and size of particles were determined through TEM. Surface properties and topographies of coated nanoparticles were investigated by the AFM technique. The magnetic properties of Fe<sub>3</sub>O<sub>4</sub> and Fe<sub>3</sub>O<sub>4</sub>@Au nanoparticles were measured by VSM technique. After confirming the structure of gold-coated magnetic ION, its performance for the oxidation of various aliphatic and aromatic alcohols with TBHP was studied in water. Finally, the reusability of Fe<sub>3</sub>O<sub>4</sub>@Au nanocatalyst was evaluated after five consecutive cycles in the 4-methoxybenzyl alcohol oxidation. The measured results revealed that the gold-coated iron oxide magnetic nanoparticles can be reused well in the oxidation processes of alcohols with high efficiency.</p></div>\",\"PeriodicalId\":676,\"journal\":{\"name\":\"Journal of the Iranian Chemical Society\",\"volume\":\"21 9\",\"pages\":\"2315 - 2324\"},\"PeriodicalIF\":2.2000,\"publicationDate\":\"2024-08-14\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of the Iranian Chemical Society\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s13738-024-03068-w\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of the Iranian Chemical Society","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1007/s13738-024-03068-w","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Catalytic oxidation of alcohols catalyzed by gold-coated iron oxide magnetic nanoparticles in water
Gold-coated magnetic iron oxide nanoparticles (ION) (Fe3O4@Au) were synthesized and utilized as catalyst for alcohol oxidation with tert-butyl hydroperoxide (TBHP). First, iron oxide magnetic nanoparticles (Fe3O4) were prepared and finally coated with a thin layer of gold. Structure and composition of Fe3O4@Au nanocatalyst were characterized by XRD, TGA, and FT-IR analysis. Size and morphology and size of particles were determined through TEM. Surface properties and topographies of coated nanoparticles were investigated by the AFM technique. The magnetic properties of Fe3O4 and Fe3O4@Au nanoparticles were measured by VSM technique. After confirming the structure of gold-coated magnetic ION, its performance for the oxidation of various aliphatic and aromatic alcohols with TBHP was studied in water. Finally, the reusability of Fe3O4@Au nanocatalyst was evaluated after five consecutive cycles in the 4-methoxybenzyl alcohol oxidation. The measured results revealed that the gold-coated iron oxide magnetic nanoparticles can be reused well in the oxidation processes of alcohols with high efficiency.
期刊介绍:
JICS is an international journal covering general fields of chemistry. JICS welcomes high quality original papers in English dealing with experimental, theoretical and applied research related to all branches of chemistry. These include the fields of analytical, inorganic, organic and physical chemistry as well as the chemical biology area. Review articles discussing specific areas of chemistry of current chemical or biological importance are also published. JICS ensures visibility of your research results to a worldwide audience in science. You are kindly invited to submit your manuscript to the Editor-in-Chief or Regional Editor. All contributions in the form of original papers or short communications will be peer reviewed and published free of charge after acceptance.