碳量子点光催化技术的最新进展

IF 2.8 3区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY Research on Chemical Intermediates Pub Date : 2024-08-28 DOI:10.1007/s11164-024-05389-0
Dan Xu, Cailian Yu, Xianlong Peng, Hong Yan, Yuanbo Zhang
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摘要

碳量子点(CQDs)作为一种新型的碳纳米材料,具有优异的光稳定性、水溶性、生物相容性、荧光性、低成本和绿色无毒等特点,被广泛应用于药物传输、生物传感、荧光探针和光催化等领域。同时,由于 CQDs 的共轭 π 结构和 sp2 杂化产生的表面缺陷,它们具有独特的光电特性,包括可调荧光、良好的上转换光致发光和高效的光电子转移。这些特性是 CQDs 在光催化领域发挥作用的关键。本综述总结了 CQDs 在光催化领域的研究进展和反应机制,包括其光学特性和合成策略。重点介绍了 CQDs 在光催化领域的应用,包括光催化 CO2 转化、有机和重金属污染物降解、制氢和固氮。此外,还讨论了 CQDs 在光催化领域的挑战和前景,为研究 CQDs 光催化材料提供了新思路。图文摘要
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Recent advances in carbon quantum dot photocatalysis

Carbon quantum dots (CQDs), as a novel type of carbon nanomaterial, are widely used in fields such as drug delivery, biosensing, fluorescent probes, and photocatalysis, benefiting from their excellent photostability, water solubility, biocompatibility, fluorescence, low-cost, and green non-toxicity. Meanwhile, due to the conjugated π structure of CQDs and surface defects generated by sp2 hybridization, they possess unique optoelectronic properties, including tunable fluorescence, good upconversion photoluminescence, and efficient photoelectron transfer. These properties are key to the role of CQDs in the field of photocatalysis. This review summarises CQDs’ research progress and reaction mechanisms in photocatalysis, including their optical properties and synthesis strategies. Emphasis was placed on the application of CQDs in the field of photocatalysis, including photocatalytic CO2 conversion, degradation of organic and heavy metal pollutants, hydrogen production, and nitrogen fixation. In addition, the challenges and prospects of CQDs in the field of photocatalysis are discussed, providing new ideas for studying CQDs photocatalytic materials.

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来源期刊
CiteScore
5.70
自引率
18.20%
发文量
229
审稿时长
2.6 months
期刊介绍: Research on Chemical Intermediates publishes current research articles and concise dynamic reviews on the properties, structures and reactivities of intermediate species in all the various domains of chemistry. The journal also contains articles in related disciplines such as spectroscopy, molecular biology and biochemistry, atmospheric and environmental sciences, catalysis, photochemistry and photophysics. In addition, special issues dedicated to specific topics in the field are regularly published.
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