用于检测爆炸物前体的便携式独立时间门控拉曼光谱技术

IF 0.8 4区 化学 Q4 SPECTROSCOPY Journal of Applied Spectroscopy Pub Date : 2024-09-12 DOI:10.1007/s10812-024-01805-w
Wenzhen Ren, Hui Wang, Zhengmao Xie, XiangPing Zhu, Pu Zhang, Bo Wang, Cheng Huang, DanDan Xu, Wei Zhao
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引用次数: 0

摘要

痕量爆炸物和危险化学品的远程检测一直是国防科学、公共安全和反恐领域面临的挑战和关键问题。拉曼光谱是非弹性散射的一种形式,是一种物质识别的 "指纹 "分析方法,可根据化学物质的振动模式对其进行高置信度检测。在此,我们介绍了一种便携式隔离时间门控拉曼光谱,它由无源 Q 开关脉冲激光器、设计门控 ICMOS、光谱仪和望远镜组成,整体尺寸为 476.5 × 321.5 × 219.3 毫米,重量为 23.2 千克,比之前报道的更加紧凑便携。为了证实所设计的便携式时间门控拉曼光谱的有效性,我们在不同的工作距离和不同的物质含量下进行了检测。即使在 10 米距离内检测 0.1 毫克的物质,也能获得较高的拉曼识别率。此外,我们还模拟了可能发生的战区情况,测试了系统识别铝板、木板、纸板、黑布和树叶等不同基质上尿素样品的能力;结果表明识别特征良好。
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Portable Stand-Off Time-Gated Raman Spectroscopy for Detection of Explosive Precursor

Remote detection of trace explosives and hazardous chemicals has been an ongoing challenge and a critical issue in defense science, public safety, and counterterrorism. Raman spectroscopy, a form of inelastic scattering, acts as a "fingerprint" analysis method for substance identification with high confidence in the detection of chemicals based on their vibrational modes. Here, we present a portable stand-off time-gated Raman spectroscopy, which consists of a passive Q-switched pulsed laser, a designed gated ICMOS, a spectrometer, and a telescope, with an overall size of 476.5 × 321.5 × 219.3 mm and a weight of 23.2 kg, which is much more compact and portable than reported previously. To confirm the effectiveness of the designed portable time-gated Raman spectroscopy, detections at different working distances and various amounts of substances are carried out. High levels of Raman identification are acquired even for 0.1 mg at a 10-m distance. Furthermore, we simulate realistic encounters in a possible war-zone scenario by testing the system's ability to recognize urea samples on different substrates such as an aluminum plate, woodblock, cardboard, black cloth, and leaf; good characteristic recognition is shown.

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来源期刊
CiteScore
1.30
自引率
14.30%
发文量
145
审稿时长
2.5 months
期刊介绍: Journal of Applied Spectroscopy reports on many key applications of spectroscopy in chemistry, physics, metallurgy, and biology. An increasing number of papers focus on the theory of lasers, as well as the tremendous potential for the practical applications of lasers in numerous fields and industries.
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