{"title":"壳聚糖混合天然酚醛食用薄膜特性的比较研究","authors":"Jianfei Zhu, Xiaomei Chen, Tingting Huang, Dongling Tian","doi":"10.1002/app.56252","DOIUrl":null,"url":null,"abstract":"In this study, the reaction of six natural phenolic aldehydes, namely, ethyl vanillin (EV), syringaldehyde (SA), vanillin (VA), isovanillin (ISA), 2‐hydroxy‐4‐methylbenzaldehyde (HDA), and p‐hydroxy benzaldehyde (PHDA), with chitosan produces Schiff bases of chitosan films. All the complex films were characterized through instrumental analysis. The findings suggested that the degrees of substitution of CS‐EV, CS‐SA, CS‐VA, CS‐ISA, CS‐HDA and CS‐PHDA were 73.48%, 42.22%, 58.04%, 51.52%, 40.89% and 45.23%, respectively. The results of X‐ray photoelectron spectroscopy (XPS) and Fourier transform infrared (FT‐IR) analysis confirmed that natural phenolic aldehydes conjugated with chitosan through dynamic imine bonds. The tensile strength and water barrier properties of the films were significantly better than those of the chitosan film. Film thermal stability was altered as a result of the grafting of natural phenolic aldehydes on chitosan. According to the ABTS and DPPH data, the blended films showed better antioxidant packaging performance.","PeriodicalId":183,"journal":{"name":"Journal of Applied Polymer Science","volume":null,"pages":null},"PeriodicalIF":2.7000,"publicationDate":"2024-09-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Comparative study on the characterization of chitosan mixed natural phenolic aldehyde edible films\",\"authors\":\"Jianfei Zhu, Xiaomei Chen, Tingting Huang, Dongling Tian\",\"doi\":\"10.1002/app.56252\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"In this study, the reaction of six natural phenolic aldehydes, namely, ethyl vanillin (EV), syringaldehyde (SA), vanillin (VA), isovanillin (ISA), 2‐hydroxy‐4‐methylbenzaldehyde (HDA), and p‐hydroxy benzaldehyde (PHDA), with chitosan produces Schiff bases of chitosan films. All the complex films were characterized through instrumental analysis. The findings suggested that the degrees of substitution of CS‐EV, CS‐SA, CS‐VA, CS‐ISA, CS‐HDA and CS‐PHDA were 73.48%, 42.22%, 58.04%, 51.52%, 40.89% and 45.23%, respectively. The results of X‐ray photoelectron spectroscopy (XPS) and Fourier transform infrared (FT‐IR) analysis confirmed that natural phenolic aldehydes conjugated with chitosan through dynamic imine bonds. The tensile strength and water barrier properties of the films were significantly better than those of the chitosan film. Film thermal stability was altered as a result of the grafting of natural phenolic aldehydes on chitosan. According to the ABTS and DPPH data, the blended films showed better antioxidant packaging performance.\",\"PeriodicalId\":183,\"journal\":{\"name\":\"Journal of Applied Polymer Science\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":2.7000,\"publicationDate\":\"2024-09-11\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Applied Polymer Science\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1002/app.56252\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"POLYMER SCIENCE\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Applied Polymer Science","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1002/app.56252","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"POLYMER SCIENCE","Score":null,"Total":0}
Comparative study on the characterization of chitosan mixed natural phenolic aldehyde edible films
In this study, the reaction of six natural phenolic aldehydes, namely, ethyl vanillin (EV), syringaldehyde (SA), vanillin (VA), isovanillin (ISA), 2‐hydroxy‐4‐methylbenzaldehyde (HDA), and p‐hydroxy benzaldehyde (PHDA), with chitosan produces Schiff bases of chitosan films. All the complex films were characterized through instrumental analysis. The findings suggested that the degrees of substitution of CS‐EV, CS‐SA, CS‐VA, CS‐ISA, CS‐HDA and CS‐PHDA were 73.48%, 42.22%, 58.04%, 51.52%, 40.89% and 45.23%, respectively. The results of X‐ray photoelectron spectroscopy (XPS) and Fourier transform infrared (FT‐IR) analysis confirmed that natural phenolic aldehydes conjugated with chitosan through dynamic imine bonds. The tensile strength and water barrier properties of the films were significantly better than those of the chitosan film. Film thermal stability was altered as a result of the grafting of natural phenolic aldehydes on chitosan. According to the ABTS and DPPH data, the blended films showed better antioxidant packaging performance.
期刊介绍:
The Journal of Applied Polymer Science is the largest peer-reviewed publication in polymers, #3 by total citations, and features results with real-world impact on membranes, polysaccharides, and much more.