可持续硬碳作为钠离子电池的阳极材料:从实验室到扩大规模

IF 5.1 4区 材料科学 Q2 ELECTROCHEMISTRY Batteries & Supercaps Pub Date : 2024-08-14 DOI:10.1002/batt.202400428
Zhenyu Guo, Kaitian Zheng, Mengnan Wang, Yichen Huang, Yuanzhu Zhao, Heather Au, Maria-Magdalena Titirici
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引用次数: 0

摘要

钠离子电池(NIBs)是锂离子电池(LIBs)的替代品,尤其是在成本、可用性和可持续性更为重要的应用领域。硬碳正在成为一种很有前途的钠离子电池负极材料,但其规模仍处于发展阶段。在本研究中,我们将重点关注可持续硬碳材料作为 NIBs 阳极材料的开发和潜在升级。硬碳的合成始于 D-葡萄糖,这是一种可扩展且对环境无害的前体。水热碳化和随后的 1500°C 高温分解相结合的简便工艺使硬碳成为一种工业上可行的材料。由此产生的硬质碳展示了极具竞争力的性能指标,包括高初始库仑效率、高可逆容量、长期循环稳定性和速率能力。本研究最后讨论了在电池行业采用这种可持续材料的技术经济分析,强调了在能源存储技术方面取得重大进展的潜力。
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Sustainable Hard Carbon as Anode Materials for Na-Ion Batteries: From Laboratory to Upscaling

Sodium-ion batteries (NIBs) are an alternative to lithium-ion batteries (LIBs), particularly in applications where cost, availability, and sustainability are more critical. Hard carbon is emerging as a promising anode material for NIBs, however, the scale up remains in developmental stages. In this study, we focus on the development and potential upscaling of sustainable hard carbon materials as anodes for NIBs. The synthesis of hard carbon starts from D-glucose, a scalable and environmentally benign precursor. A facile process combining hydrothermal carbonisation and subsequent pyrolysis at 1500 °C allows the hard carbon to become an industrially viable material. The resulting hard carbon demonstrates competitive performance metrics including a high initial Coulombic efficiency, high reversible capacity, long-term cycling stability, and rate capability. This study concludes with a discussion of the techno-economic analysis of adopting such sustainable materials in the battery industry, highlighting the potential for significant advancements in energy storage technologies.

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来源期刊
CiteScore
8.60
自引率
5.30%
发文量
223
期刊介绍: Electrochemical energy storage devices play a transformative role in our societies. They have allowed the emergence of portable electronics devices, have triggered the resurgence of electric transportation and constitute key components in smart power grids. Batteries & Supercaps publishes international high-impact experimental and theoretical research on the fundamentals and applications of electrochemical energy storage. We support the scientific community to advance energy efficiency and sustainability.
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