基于脂环族和含氟二胺的光学透明共聚多亚胺的合成

IF 1.7 4区化学 Q3 CHEMISTRY, MULTIDISCIPLINARY Russian Chemical Bulletin Pub Date : 2024-08-31 DOI:10.1007/s11172-024-4322-7

I. A. Novakov, D. V. Zavyalov, E. N. Savelyev, E. A. Alykova, A. M. Pichugin, M. A. Nakhod, E. M. Sukhareva, A. D. Dubinina, E. I. Farkhutdinova

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引用次数: 0

摘要

研究表明，基于含金刚烷的二胺和 2,3,3′,4′-联苯四羧酸二酐（a-BPDA）和 5,5′-(1,1,1,3,3,3-六氟丙烷-2,2-二基)双(2-苯并呋喃-1、3-二酮）（6FDA）具有良好的热氧化性能（T5% = 465-485 °C）和较高的光学透明度（T400 = 60-80%），而基于相同二酐和 2,2′-双（三氟甲基）联苯-4,4′-二胺（TFBA）的共聚亚胺则含有笨重的三氟甲基片段（T400 = 38-67%）。

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Synthesis of optically transparent copolyimides based on alicyclic and fluorine-containing diamine

It was shown that copolyimides based on adamantane-containing diamine and dianhydrides of 2,3,3′,4′-biphenyltetracarboxylic acid (a-BPDA) and 5,5′-(1,1,1,3,3,3-hexafluoropropane-2,2-diyl)bis(2-benzofuran-1,3-dione) (6FDA) are characterized by good thermal-oxidative properties (T_5% = 465–485 °C) and a high optical transparency (T₄₀₀ = 60–80%) in comparison with copolyimides based on the same dianhydrides and 2,2′-bis(trifluoromethyl)biphenyl-4,4′-diamine (TFBA), containing bulky trifluoromethyl fragments (T₄₀₀ = 38–67%).

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来源期刊

Russian Chemical Bulletin 化学-化学综合

CiteScore

2.70

自引率

47.10%

发文量

257

审稿时长

3-8 weeks

期刊介绍： Publishing nearly 500 original articles a year, by leading Scientists from Russia and throughout the world, Russian Chemical Bulletin is a prominent international journal. The coverage of the journal spans practically all areas of fundamental chemical research and is presented in five sections: General and Inorganic Chemistry; Physical Chemistry; Organic Chemistry; Organometallic Chemistry; Chemistry of Natural Compounds and Bioorganic Chemistry.