污泥碳促进钛酸钡压电特性以激活恩诺沙星的过硫酸盐降解

IF 2.8 4区 生物学 Q3 BIOTECHNOLOGY & APPLIED MICROBIOLOGY Journal of chemical technology and biotechnology Pub Date : 2024-09-07 DOI:10.1002/jctb.7740
Jun Chen, Xue Li, Xiaohong Yang, Yutong Wang, Zongsheng Zhan, Dawei Teng, Mingxia Du, Dong Lv, Kaiqi Yao, Chunnian Da, Mengqiu Xu
{"title":"污泥碳促进钛酸钡压电特性以激活恩诺沙星的过硫酸盐降解","authors":"Jun Chen, Xue Li, Xiaohong Yang, Yutong Wang, Zongsheng Zhan, Dawei Teng, Mingxia Du, Dong Lv, Kaiqi Yao, Chunnian Da, Mengqiu Xu","doi":"10.1002/jctb.7740","DOIUrl":null,"url":null,"abstract":"BACKGROUNDPiezoelectric catalysis using perovskite‐type barium titanate (BaTiO<jats:sub>3</jats:sub>) has been applied to the decomposition of refractory organic pollutants through piezoelectric catalytic persulfate (PS). Nevertheless, challenges such as a limited specific surface area, poor electrical conductivity and a tendency towards agglomeration in BaTiO<jats:sub>3</jats:sub> necessitate the exploration of novel methods to enhance its piezoelectric efficiency.RESULTSSludge carbon (SC) from sewage treatment and BaTiO<jats:sub>3</jats:sub> was utilized to develop a novel piezoelectric catalytic material (BaTiO<jats:sub>3</jats:sub>/SC). The specific surface area of BaTiO<jats:sub>3</jats:sub>/SC reached 67.92 m<jats:sup>2</jats:sup> g<jats:sup>−1</jats:sup>, which is nine times larger than that of BaTiO<jats:sub>3</jats:sub> alone. The inclusion of SC in the composite enhanced the number of active sites and contributed to a higher degree of graphitization, improved electrical conductivity, and provided a more stable structure for BaTiO<jats:sub>3</jats:sub>/SC. This material was capable of harvesting mechanical vibration energy from ultrasound, thereby generating piezoelectric catalytic properties and activating PS to achieve a 93% decomposition ratio of enrofloxacin (ENR) in water within 80 min. The activation of PS by BaTiO<jats:sub>3</jats:sub>/SC piezocatalysis led to the production of reactive oxygen species (ROS), such as <jats:sup>•</jats:sup>OH and SO<jats:sub>4</jats:sub><jats:sup>−•</jats:sup>. These ROS attack the quinolone ring of ENR, which is susceptible to cleavage, resulting in the decomposition of ENR into intermediates of lower toxicity.CONCLUSIONThe incorporation of SC has enhanced the piezoelectric performance of BaTiO<jats:sub>3</jats:sub>, rendering BaTiO<jats:sub>3</jats:sub>/SC a novel perovskite‐type piezoelectric catalytic material that improves piezoelectric efficiency. The BaTiO<jats:sub>3</jats:sub>/SC system, through its piezoelectric catalytic activation of PS, demonstrates potential for decomposition of refractory organic pollutants in water treatment. © 2024 Society of Chemical Industry (SCI).","PeriodicalId":15335,"journal":{"name":"Journal of chemical technology and biotechnology","volume":null,"pages":null},"PeriodicalIF":2.8000,"publicationDate":"2024-09-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Sludge carbon promotes barium titanate piezoelectric property to activate persulfate degradation of enrofloxacin\",\"authors\":\"Jun Chen, Xue Li, Xiaohong Yang, Yutong Wang, Zongsheng Zhan, Dawei Teng, Mingxia Du, Dong Lv, Kaiqi Yao, Chunnian Da, Mengqiu Xu\",\"doi\":\"10.1002/jctb.7740\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"BACKGROUNDPiezoelectric catalysis using perovskite‐type barium titanate (BaTiO<jats:sub>3</jats:sub>) has been applied to the decomposition of refractory organic pollutants through piezoelectric catalytic persulfate (PS). Nevertheless, challenges such as a limited specific surface area, poor electrical conductivity and a tendency towards agglomeration in BaTiO<jats:sub>3</jats:sub> necessitate the exploration of novel methods to enhance its piezoelectric efficiency.RESULTSSludge carbon (SC) from sewage treatment and BaTiO<jats:sub>3</jats:sub> was utilized to develop a novel piezoelectric catalytic material (BaTiO<jats:sub>3</jats:sub>/SC). The specific surface area of BaTiO<jats:sub>3</jats:sub>/SC reached 67.92 m<jats:sup>2</jats:sup> g<jats:sup>−1</jats:sup>, which is nine times larger than that of BaTiO<jats:sub>3</jats:sub> alone. The inclusion of SC in the composite enhanced the number of active sites and contributed to a higher degree of graphitization, improved electrical conductivity, and provided a more stable structure for BaTiO<jats:sub>3</jats:sub>/SC. This material was capable of harvesting mechanical vibration energy from ultrasound, thereby generating piezoelectric catalytic properties and activating PS to achieve a 93% decomposition ratio of enrofloxacin (ENR) in water within 80 min. The activation of PS by BaTiO<jats:sub>3</jats:sub>/SC piezocatalysis led to the production of reactive oxygen species (ROS), such as <jats:sup>•</jats:sup>OH and SO<jats:sub>4</jats:sub><jats:sup>−•</jats:sup>. These ROS attack the quinolone ring of ENR, which is susceptible to cleavage, resulting in the decomposition of ENR into intermediates of lower toxicity.CONCLUSIONThe incorporation of SC has enhanced the piezoelectric performance of BaTiO<jats:sub>3</jats:sub>, rendering BaTiO<jats:sub>3</jats:sub>/SC a novel perovskite‐type piezoelectric catalytic material that improves piezoelectric efficiency. The BaTiO<jats:sub>3</jats:sub>/SC system, through its piezoelectric catalytic activation of PS, demonstrates potential for decomposition of refractory organic pollutants in water treatment. © 2024 Society of Chemical Industry (SCI).\",\"PeriodicalId\":15335,\"journal\":{\"name\":\"Journal of chemical technology and biotechnology\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":2.8000,\"publicationDate\":\"2024-09-07\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of chemical technology and biotechnology\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://doi.org/10.1002/jctb.7740\",\"RegionNum\":4,\"RegionCategory\":\"生物学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"BIOTECHNOLOGY & APPLIED MICROBIOLOGY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of chemical technology and biotechnology","FirstCategoryId":"5","ListUrlMain":"https://doi.org/10.1002/jctb.7740","RegionNum":4,"RegionCategory":"生物学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"BIOTECHNOLOGY & APPLIED MICROBIOLOGY","Score":null,"Total":0}
引用次数: 0

摘要

背景使用透辉石型钛酸钡(BaTiO3)的压电催化已被应用于通过压电催化过硫酸盐(PS)分解难熔有机污染物。然而,BaTiO3 面临着比表面积有限、导电性差和容易团聚等挑战,因此有必要探索新方法来提高其压电效率。结果利用污水处理产生的污泥碳(SC)和 BaTiO3 开发了一种新型压电催化材料(BaTiO3/SC)。BaTiO3/SC 的比表面积达到 67.92 m2 g-1,是单独使用 BaTiO3 的 9 倍。在复合材料中加入 SC 增加了活性位点的数量,提高了石墨化程度,改善了导电性,并为 BaTiO3/SC 提供了更稳定的结构。这种材料能够从超声波中获取机械振动能量,从而产生压电催化特性并激活 PS,使恩诺沙星(ENR)在水中的分解率在 80 分钟内达到 93%。BaTiO3/SC 压电催化活化 PS 会产生活性氧(ROS),如 -OH 和 SO4--。这些 ROS 会攻击 ENR 的喹诺酮环,而 ENR 的喹诺酮环很容易被裂解,从而导致 ENR 分解成毒性较低的中间体。结论 SC 的加入增强了 BaTiO3 的压电性能,使 BaTiO3/SC 成为一种新型的包晶型压电催化材料,提高了压电效率。BaTiO3/SC 系统通过其对 PS 的压电催化活化,展示了在水处理中分解难分解有机污染物的潜力。© 2024 化学工业协会 (SCI)。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
Sludge carbon promotes barium titanate piezoelectric property to activate persulfate degradation of enrofloxacin
BACKGROUNDPiezoelectric catalysis using perovskite‐type barium titanate (BaTiO3) has been applied to the decomposition of refractory organic pollutants through piezoelectric catalytic persulfate (PS). Nevertheless, challenges such as a limited specific surface area, poor electrical conductivity and a tendency towards agglomeration in BaTiO3 necessitate the exploration of novel methods to enhance its piezoelectric efficiency.RESULTSSludge carbon (SC) from sewage treatment and BaTiO3 was utilized to develop a novel piezoelectric catalytic material (BaTiO3/SC). The specific surface area of BaTiO3/SC reached 67.92 m2 g−1, which is nine times larger than that of BaTiO3 alone. The inclusion of SC in the composite enhanced the number of active sites and contributed to a higher degree of graphitization, improved electrical conductivity, and provided a more stable structure for BaTiO3/SC. This material was capable of harvesting mechanical vibration energy from ultrasound, thereby generating piezoelectric catalytic properties and activating PS to achieve a 93% decomposition ratio of enrofloxacin (ENR) in water within 80 min. The activation of PS by BaTiO3/SC piezocatalysis led to the production of reactive oxygen species (ROS), such as OH and SO4−•. These ROS attack the quinolone ring of ENR, which is susceptible to cleavage, resulting in the decomposition of ENR into intermediates of lower toxicity.CONCLUSIONThe incorporation of SC has enhanced the piezoelectric performance of BaTiO3, rendering BaTiO3/SC a novel perovskite‐type piezoelectric catalytic material that improves piezoelectric efficiency. The BaTiO3/SC system, through its piezoelectric catalytic activation of PS, demonstrates potential for decomposition of refractory organic pollutants in water treatment. © 2024 Society of Chemical Industry (SCI).
求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
CiteScore
7.00
自引率
5.90%
发文量
268
审稿时长
1.7 months
期刊介绍: Journal of Chemical Technology and Biotechnology(JCTB) is an international, inter-disciplinary peer-reviewed journal concerned with the application of scientific discoveries and advancements in chemical and biological technology that aim towards economically and environmentally sustainable industrial processes.
期刊最新文献
Issue Information Adsorption behavior of graphite‐like walnut shell biochar modified with ammonia for ciprofloxacin in aqueous solution Eco‐friendly approaches for synthesis of indolyl 1H‐pyrroles using rice‐husk‐derived carbonaceous sulfonation as the green catalyst Impact of neutrophil‐activating protein conservation on diagnostic tests and vaccine design Issue Information
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1