{"title":"使用预硫化橡胶胶乳可剥离薄膜保护材料表面的简便策略","authors":"Yaowaret Maiket, Rungsima Yeetsorn, Waritnan Wanchan, Sunanta Chuayprakong, Thitinun Ungtrakul, Mesum Abbas, Edmund Haberstroh","doi":"10.1007/s12034-024-03304-2","DOIUrl":null,"url":null,"abstract":"<div><p>This study introduces a method for producing environmentally friendly peelable film using prevulcanized rubber latex, offering a simple and cost-effective solution capable of covering complex shapes. The synthesis investigation explores the relationship between conventional rubber formulations and the film’s performance, highlighting the significance of selecting appropriate chemicals to improve functionality. Key considerations for selecting the latex compound formulation include the solution's properties, particularly focussing on flow behaviour and coating time, as well as the mechanical properties, fire resistance, peel ability and durability of the resulting film under challenging conditions. The primary investigation into the impact of the zinc diethyldithiocarbamate : sulphur (ZDEC : S) ratio on crosslink density provides insight into rheological and mechanical properties. Furthermore, the addition of phenol, 4-methyl-, reaction products with dicyclopentadiene and isobutene (CPL) as an antioxidant improves heat resistance and oxygen tolerance. The remarkable versatility of peelable film allows for its application through various methods, including sagging (1–10 s<sup>–1</sup>), painting and spraying (10–100 s<sup>–1</sup>), effectively protecting against dust, scratches and temperatures exceeding 200°C. Particularly noteworthy are its low peel force of 0.139 N, 44 mm removal path and 2-month service life. The findings from testing the crucial properties of the manufactured films, which meets industrial standards, indicate a pathway to produce environmentally sustainable products, with a strong potential for further advancement towards commercial production.</p></div>","PeriodicalId":502,"journal":{"name":"Bulletin of Materials Science","volume":"47 4","pages":""},"PeriodicalIF":1.9000,"publicationDate":"2024-09-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Facile strategy to protect material surface using peelable film from prevulcanized rubber latex\",\"authors\":\"Yaowaret Maiket, Rungsima Yeetsorn, Waritnan Wanchan, Sunanta Chuayprakong, Thitinun Ungtrakul, Mesum Abbas, Edmund Haberstroh\",\"doi\":\"10.1007/s12034-024-03304-2\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>This study introduces a method for producing environmentally friendly peelable film using prevulcanized rubber latex, offering a simple and cost-effective solution capable of covering complex shapes. The synthesis investigation explores the relationship between conventional rubber formulations and the film’s performance, highlighting the significance of selecting appropriate chemicals to improve functionality. Key considerations for selecting the latex compound formulation include the solution's properties, particularly focussing on flow behaviour and coating time, as well as the mechanical properties, fire resistance, peel ability and durability of the resulting film under challenging conditions. The primary investigation into the impact of the zinc diethyldithiocarbamate : sulphur (ZDEC : S) ratio on crosslink density provides insight into rheological and mechanical properties. Furthermore, the addition of phenol, 4-methyl-, reaction products with dicyclopentadiene and isobutene (CPL) as an antioxidant improves heat resistance and oxygen tolerance. The remarkable versatility of peelable film allows for its application through various methods, including sagging (1–10 s<sup>–1</sup>), painting and spraying (10–100 s<sup>–1</sup>), effectively protecting against dust, scratches and temperatures exceeding 200°C. Particularly noteworthy are its low peel force of 0.139 N, 44 mm removal path and 2-month service life. The findings from testing the crucial properties of the manufactured films, which meets industrial standards, indicate a pathway to produce environmentally sustainable products, with a strong potential for further advancement towards commercial production.</p></div>\",\"PeriodicalId\":502,\"journal\":{\"name\":\"Bulletin of Materials Science\",\"volume\":\"47 4\",\"pages\":\"\"},\"PeriodicalIF\":1.9000,\"publicationDate\":\"2024-09-13\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Bulletin of Materials Science\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s12034-024-03304-2\",\"RegionNum\":4,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"MATERIALS SCIENCE, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Bulletin of Materials Science","FirstCategoryId":"88","ListUrlMain":"https://link.springer.com/article/10.1007/s12034-024-03304-2","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
Facile strategy to protect material surface using peelable film from prevulcanized rubber latex
This study introduces a method for producing environmentally friendly peelable film using prevulcanized rubber latex, offering a simple and cost-effective solution capable of covering complex shapes. The synthesis investigation explores the relationship between conventional rubber formulations and the film’s performance, highlighting the significance of selecting appropriate chemicals to improve functionality. Key considerations for selecting the latex compound formulation include the solution's properties, particularly focussing on flow behaviour and coating time, as well as the mechanical properties, fire resistance, peel ability and durability of the resulting film under challenging conditions. The primary investigation into the impact of the zinc diethyldithiocarbamate : sulphur (ZDEC : S) ratio on crosslink density provides insight into rheological and mechanical properties. Furthermore, the addition of phenol, 4-methyl-, reaction products with dicyclopentadiene and isobutene (CPL) as an antioxidant improves heat resistance and oxygen tolerance. The remarkable versatility of peelable film allows for its application through various methods, including sagging (1–10 s–1), painting and spraying (10–100 s–1), effectively protecting against dust, scratches and temperatures exceeding 200°C. Particularly noteworthy are its low peel force of 0.139 N, 44 mm removal path and 2-month service life. The findings from testing the crucial properties of the manufactured films, which meets industrial standards, indicate a pathway to produce environmentally sustainable products, with a strong potential for further advancement towards commercial production.
期刊介绍:
The Bulletin of Materials Science is a bi-monthly journal being published by the Indian Academy of Sciences in collaboration with the Materials Research Society of India and the Indian National Science Academy. The journal publishes original research articles, review articles and rapid communications in all areas of materials science. The journal also publishes from time to time important Conference Symposia/ Proceedings which are of interest to materials scientists. It has an International Advisory Editorial Board and an Editorial Committee. The Bulletin accords high importance to the quality of articles published and to keep at a minimum the processing time of papers submitted for publication.