使用预硫化橡胶胶乳可剥离薄膜保护材料表面的简便策略

IF 1.9 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Bulletin of Materials Science Pub Date : 2024-09-13 DOI:10.1007/s12034-024-03304-2
Yaowaret Maiket, Rungsima Yeetsorn, Waritnan Wanchan, Sunanta Chuayprakong, Thitinun Ungtrakul, Mesum Abbas, Edmund Haberstroh
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引用次数: 0

摘要

本研究介绍了一种使用预硫化橡胶胶乳生产环保型可剥离薄膜的方法,提供了一种能够覆盖复杂形状的简单而经济的解决方案。合成研究探讨了传统橡胶配方与薄膜性能之间的关系,强调了选择合适的化学品来提高功能性的重要性。选择胶乳化合物配方的主要考虑因素包括溶液的性能,特别是流动性和涂覆时间,以及机械性能、耐火性、剥离能力和所制成薄膜在挑战性条件下的耐用性。二乙基二硫代氨基甲酸锌:硫(ZDEC:S)的比例对交联密度的影响这一主要调查提供了对流变和机械性能的深入了解。此外,添加苯酚、4-甲基-、与双环戊二烯和异丁烯的反应产物(CPL)作为抗氧化剂可提高耐热性和耐氧性。可剥离薄膜具有显著的多功能性,可通过各种方法使用,包括下垂(1-10 秒-1)、喷漆和喷涂(10-100 秒-1),有效防止灰尘、划痕和超过 200°C 的温度。尤其值得一提的是,它的剥离力低至 0.139 N,剥离路径为 44 mm,使用寿命长达 2 个月。对符合工业标准的薄膜关键性能的测试结果表明,这是一条生产环境可持续产品的途径,具有进一步推进商业化生产的巨大潜力。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

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Facile strategy to protect material surface using peelable film from prevulcanized rubber latex

This study introduces a method for producing environmentally friendly peelable film using prevulcanized rubber latex, offering a simple and cost-effective solution capable of covering complex shapes. The synthesis investigation explores the relationship between conventional rubber formulations and the film’s performance, highlighting the significance of selecting appropriate chemicals to improve functionality. Key considerations for selecting the latex compound formulation include the solution's properties, particularly focussing on flow behaviour and coating time, as well as the mechanical properties, fire resistance, peel ability and durability of the resulting film under challenging conditions. The primary investigation into the impact of the zinc diethyldithiocarbamate : sulphur (ZDEC : S) ratio on crosslink density provides insight into rheological and mechanical properties. Furthermore, the addition of phenol, 4-methyl-, reaction products with dicyclopentadiene and isobutene (CPL) as an antioxidant improves heat resistance and oxygen tolerance. The remarkable versatility of peelable film allows for its application through various methods, including sagging (1–10 s–1), painting and spraying (10–100 s–1), effectively protecting against dust, scratches and temperatures exceeding 200°C. Particularly noteworthy are its low peel force of 0.139 N, 44 mm removal path and 2-month service life. The findings from testing the crucial properties of the manufactured films, which meets industrial standards, indicate a pathway to produce environmentally sustainable products, with a strong potential for further advancement towards commercial production.

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来源期刊
Bulletin of Materials Science
Bulletin of Materials Science 工程技术-材料科学:综合
CiteScore
3.40
自引率
5.60%
发文量
209
审稿时长
11.5 months
期刊介绍: The Bulletin of Materials Science is a bi-monthly journal being published by the Indian Academy of Sciences in collaboration with the Materials Research Society of India and the Indian National Science Academy. The journal publishes original research articles, review articles and rapid communications in all areas of materials science. The journal also publishes from time to time important Conference Symposia/ Proceedings which are of interest to materials scientists. It has an International Advisory Editorial Board and an Editorial Committee. The Bulletin accords high importance to the quality of articles published and to keep at a minimum the processing time of papers submitted for publication.
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