用于控制水泥窑氮氧化物排放的在线气化炉的多相流模拟和工业应用

IF 5.9 3区 工程技术 Q1 CHEMISTRY, MULTIDISCIPLINARY Journal of Industrial and Engineering Chemistry Pub Date : 2024-08-16 DOI:10.1016/j.jiec.2024.08.019
Xiang Zhang, Jian Tian, Xinye Wang, Yanchao Zhu, Tanghui Hu, Pan Hu
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引用次数: 0

摘要

继电力和钢铁行业之后,水泥行业的氮氧化物(NO)已成为下一阶段大气污染物控制的重要组成部分。因此,采用计算流体动力学(CFD)方法对在线煤气化脱硝系统进行了多相流模拟。其中,固相采用多相颗粒-单元(MP-PIC)方法模拟,气相湍流采用大涡模拟(LES)方法精确捕捉。研究了不同参数(煤、生料、三次风)下气化炉中 NO 的流场特性分布和反应动力学,并得出了指导工业应用的运行条件值。模拟结果表明,在煤2.8 kg/s、生料30 kg/s、三次风2.5 kg/s的条件下,气化炉可以完全脱除回转窑中的NO。应用结果表明,在 1.6 kg/t.cl 氨水与 SNCR 相结合的情况下,NO 排放和氨滑移可分别控制在 50 mg/Nm 和 5 mg/Nm 以下。与类似的脱硝技术相比,该技术显示了在水泥行业实现超低氮氧化物排放水平的潜力。
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Multiphase flow simulation and industrial application of an in-line gasifier for NOx emissions control from cement kiln
Following the power and steel industries, nitrogen oxides (NO) in the cement industry have become an important part of the next stage of air pollutant control. Consequently, the multiphase flow simulation of an in-line coal gasification denitration system was carried out using the computational fluid dynamics (CFD) approach. Among them, the solid phase is simulated by the Multiphase Particle-In-Cell (MP-PIC) method, and the gas phase turbulence is accurately captured by the large eddy simulation (LES) method. The flow field characteristics distribution and the reaction kinetic of NO under different parameters (coal, raw meal, tertiary air) in the gasifier were investigated, and the operating condition values for guiding industrial applications are obtained. The simulation results show that the gasifier can completely remove NO from the rotary kiln at 2.8 kg/s for coal, 30 kg/s for raw meal and 2.5 kg/s for tertiary air. The application results show that under 1.6 kg/t.cl of ammonia water combined with SNCR, NO emission and ammonia slip can be controlled below 50 mg/Nm and 5 mg/Nm, respectively. Compared to similar denitrification technologies, this technology shows the potential to achieve ultra-low NO emission levels in the cement industry.
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来源期刊
CiteScore
10.40
自引率
6.60%
发文量
639
审稿时长
29 days
期刊介绍: Journal of Industrial and Engineering Chemistry is published monthly in English by the Korean Society of Industrial and Engineering Chemistry. JIEC brings together multidisciplinary interests in one journal and is to disseminate information on all aspects of research and development in industrial and engineering chemistry. Contributions in the form of research articles, short communications, notes and reviews are considered for publication. The editors welcome original contributions that have not been and are not to be published elsewhere. Instruction to authors and a manuscript submissions form are printed at the end of each issue. Bulk reprints of individual articles can be ordered. This publication is partially supported by Korea Research Foundation and the Korean Federation of Science and Technology Societies.
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