Anbang Lu, Fei Wang, Zhendong Liu, Yuchen Wang, Yue Gu, Shuang Wang, Chong Ye, Quanbing Liu, Chengzhi Zhang, Jun Tan
{"title":"用于可充电金属离子电池的金属氯石墨插层化合物","authors":"Anbang Lu, Fei Wang, Zhendong Liu, Yuchen Wang, Yue Gu, Shuang Wang, Chong Ye, Quanbing Liu, Chengzhi Zhang, Jun Tan","doi":"10.1002/cey2.600","DOIUrl":null,"url":null,"abstract":"The typical metal chloride-graphite intercalation compounds (MC-GICs) inherit intercalation capacity, high charge conductivity, and high tap density from graphite, and these are considered as one of the promising alternatives of graphite anode in rechargeable metal-ion batteries (MIBs). Notably, the special interlayer decoupling effects and the introduction of extra conversion capacity by metal chloride could greatly break the capacity limitation of graphite anodes and achieve higher energy density in MIBs. The optimization of both graphite host and metal chloride species with specific structures endows MC-GICs with design feasibility for different application requirements of different MIBs, such as several times the actual capacity compared to graphite anodes, rapid migration of large carriers, and other properties. Herein, a brief review has been provided with the latest understanding of conductivity characteristics and energy storage mechanisms of MC-GICs and their interesting performance features of full potential application in rechargeable MIBs. Based on the existing research of MC-GICs, necessary improvements and prospects in the near future have been put forward.","PeriodicalId":33706,"journal":{"name":"Carbon Energy","volume":null,"pages":null},"PeriodicalIF":19.5000,"publicationDate":"2024-09-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Metal chloride-graphite intercalation compounds for rechargeable metal-ion batteries\",\"authors\":\"Anbang Lu, Fei Wang, Zhendong Liu, Yuchen Wang, Yue Gu, Shuang Wang, Chong Ye, Quanbing Liu, Chengzhi Zhang, Jun Tan\",\"doi\":\"10.1002/cey2.600\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The typical metal chloride-graphite intercalation compounds (MC-GICs) inherit intercalation capacity, high charge conductivity, and high tap density from graphite, and these are considered as one of the promising alternatives of graphite anode in rechargeable metal-ion batteries (MIBs). Notably, the special interlayer decoupling effects and the introduction of extra conversion capacity by metal chloride could greatly break the capacity limitation of graphite anodes and achieve higher energy density in MIBs. The optimization of both graphite host and metal chloride species with specific structures endows MC-GICs with design feasibility for different application requirements of different MIBs, such as several times the actual capacity compared to graphite anodes, rapid migration of large carriers, and other properties. Herein, a brief review has been provided with the latest understanding of conductivity characteristics and energy storage mechanisms of MC-GICs and their interesting performance features of full potential application in rechargeable MIBs. Based on the existing research of MC-GICs, necessary improvements and prospects in the near future have been put forward.\",\"PeriodicalId\":33706,\"journal\":{\"name\":\"Carbon Energy\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":19.5000,\"publicationDate\":\"2024-09-06\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Carbon Energy\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://doi.org/10.1002/cey2.600\",\"RegionNum\":1,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Carbon Energy","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.1002/cey2.600","RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
Metal chloride-graphite intercalation compounds for rechargeable metal-ion batteries
The typical metal chloride-graphite intercalation compounds (MC-GICs) inherit intercalation capacity, high charge conductivity, and high tap density from graphite, and these are considered as one of the promising alternatives of graphite anode in rechargeable metal-ion batteries (MIBs). Notably, the special interlayer decoupling effects and the introduction of extra conversion capacity by metal chloride could greatly break the capacity limitation of graphite anodes and achieve higher energy density in MIBs. The optimization of both graphite host and metal chloride species with specific structures endows MC-GICs with design feasibility for different application requirements of different MIBs, such as several times the actual capacity compared to graphite anodes, rapid migration of large carriers, and other properties. Herein, a brief review has been provided with the latest understanding of conductivity characteristics and energy storage mechanisms of MC-GICs and their interesting performance features of full potential application in rechargeable MIBs. Based on the existing research of MC-GICs, necessary improvements and prospects in the near future have been put forward.
期刊介绍：
Carbon Energy is an international journal that focuses on cutting-edge energy technology involving carbon utilization and carbon emission control. It provides a platform for researchers to communicate their findings and critical opinions and aims to bring together the communities of advanced material and energy. The journal covers a broad range of energy technologies, including energy storage, photocatalysis, electrocatalysis, photoelectrocatalysis, and thermocatalysis. It covers all forms of energy, from conventional electric and thermal energy to those that catalyze chemical and biological transformations. Additionally, Carbon Energy promotes new technologies for controlling carbon emissions and the green production of carbon materials. The journal welcomes innovative interdisciplinary research with wide impact. It is indexed in various databases, including Advanced Technologies & Aerospace Collection/Database, Biological Science Collection/Database, CAS, DOAJ, Environmental Science Collection/Database, Web of Science and Technology Collection.
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