利用改性棕榈叶柄作为高效、可重复使用的吸附剂,对水溶液中的阳离子染料进行可持续修复

IF 1.7 4区 化学 Q4 CHEMISTRY, PHYSICAL Reaction Kinetics, Mechanisms and Catalysis Pub Date : 2024-08-17 DOI:10.1007/s11144-024-02708-9
Amina Aichour, Hakim Djafer Khodja, Dounia Benaidja, Youcef Islam Touahria, Hassina Zaghouane-Boudiaf, Cesar Viseras Iborra
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引用次数: 0

摘要

本研究采用酸处理棕榈叶柄制备吸附剂(APP),该吸附剂对亚甲蓝(150 mg/L)的整体去除率高达 99%(60 min),且在 5 个周期后仍能保持良好性能。利用扫描电镜、傅立叶变换红外光谱、pHPZC 和亚甲基蓝吸附估算 SSA 对吸附剂进行了分析。用磷酸对粗糙的棕榈叶柄进行改性后,APP 能够增强对废水中甲基溴的吸附强度。伪二阶模型具有较高的 R2 和最低的 RMSE,是最适合描述甲基溴在 APP 上吸附的模型。在伪秒阶模型中,存在颗粒内扩散现象。研究发现,甲基溴的吸附过程是自发的,而且会放热。Langmuir 模型给出了非常令人满意的结果,其相关系数为 0.93,均方根误差值最低,饱和单层的吸附量接近实验值。从第一个吸附-解吸周期到第五个吸附-解吸周期,甲基溴在 APP 上的逐渐消除率从 95.03% 到 41.87%。所获得的结果表明,APP 是一种在废水处理领域非常有效的吸附剂。
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Sustainable remediation of a cationic dye in aqueous solutions using modified palm petiole as a highly efficient and reusable adsorbent

This study adopted acid treatment of palm petioles for preparing (APP), which reached notably the whole removal ratio of 99% (60 min) of methylene blue (150 mg/L) and can still maintain good performance after 5 cycles. The adsorbents were analyzed using SEM, FTIR, pHPZC, and SSA estimation by methylene blue adsorption. The modification of the rough palm petiole with phosphoric acid enables the APP to enhance the intensity of MB adsorption from wastewater. With high R2 and the lowest RMSE, the pseudo-second-order model is the most suitable model that describes MB adsorption on APP. There is an intraparticle diffusion, which occurs with the pseudo-second-order. pH has a great effect on MB removal. MB adsorption process was found to be spontaneous and the exothermic. Langmuir model gives very satisfactory results with value of correlation coefficient > 0.93, and the lowest values of RMSE, and saturated monolayers with values of quantities adsorbed close to experimental values. The progressive elimination percentages of the MB on APP were from 95.03% to 41.87% from the first cycle to the fifth cycle of adsorption–desorption. Obtained results have shown that APP is a very promoting adsorbent in the field of wastewater treatment.

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来源期刊
CiteScore
3.30
自引率
5.60%
发文量
201
审稿时长
2.8 months
期刊介绍: Reaction Kinetics, Mechanisms and Catalysis is a medium for original contributions in the following fields: -kinetics of homogeneous reactions in gas, liquid and solid phase; -Homogeneous catalysis; -Heterogeneous catalysis; -Adsorption in heterogeneous catalysis; -Transport processes related to reaction kinetics and catalysis; -Preparation and study of catalysts; -Reactors and apparatus. Reaction Kinetics, Mechanisms and Catalysis was formerly published under the title Reaction Kinetics and Catalysis Letters.
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