Priyankesh Kumar, Devesh Kumar, Ravi Shankar, Prateek Khare
{"title":"利用基于 TiO2-ZnO 纳米催化剂的盒式贝肯设计优化废食用油生物柴油产量和成本分析","authors":"Priyankesh Kumar, Devesh Kumar, Ravi Shankar, Prateek Khare","doi":"10.1007/s11814-024-00262-7","DOIUrl":null,"url":null,"abstract":"<div><p>The present work deals with the optimization of waste cooking oil biodiesel yield (WCOBD) and its preparation cost with the help of Box–Behnken design (BBD) using response surface methodology (RSM) in design expert software. Initially, TiO<sub>2</sub>–ZnO (nanocatalyst) was prepared with the help of the sol–gel method and ratio of TiO<sub>2</sub>–ZnO was optimized by single parameter study. The doping of ZnO over TiO<sub>2</sub> surface was studied by FTIR, XRD, SEM, and EDAX analysis. ANOVA suggests the quadratic model is closely fitted for both biodiesel yield and biodiesel cost. The value of adjusted and predicted <i>R</i><sup>2</sup> was found to be 0.9309 and 0.8465 for biodiesel yield. While the value of adjusted and predicted <i>R</i><sup>2</sup> was found to be 0.9313 and 0.8472 for biodiesel cost. The maximum actual and predicted yield of 88% was obtained at catalyst dose: 2.5 g/l; methanol: 50 ml; waste cooking oil (WCO): 50 ml; time: 120 min, and temperature: 65 °C. The % error between actual and predicted biodiesel varies in the range of −7.90–7.19%. The minimum actual and predicted WCOBD cost was found to be INR 47.29/l and INR 44.68/l with % error in the range of −19.56–13.87% at catalyst dose: 2.5 g/l; methanol: 25 ml; waste cooking oil (WCO): 75 ml; time: 120 min, and temperature: 65 °C, respectively. Overall, the model used to predict the waste cooking oil biodiesel yield, and its cost is closely fitted with the actual result.</p></div>","PeriodicalId":684,"journal":{"name":"Korean Journal of Chemical Engineering","volume":null,"pages":null},"PeriodicalIF":2.9000,"publicationDate":"2024-09-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Optimization of Biodiesel Yield and Cost Analysis from Waste Cooking Oil Using Box–Behnken Design with TiO2–ZnO-Based Nano-catalyst\",\"authors\":\"Priyankesh Kumar, Devesh Kumar, Ravi Shankar, Prateek Khare\",\"doi\":\"10.1007/s11814-024-00262-7\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The present work deals with the optimization of waste cooking oil biodiesel yield (WCOBD) and its preparation cost with the help of Box–Behnken design (BBD) using response surface methodology (RSM) in design expert software. Initially, TiO<sub>2</sub>–ZnO (nanocatalyst) was prepared with the help of the sol–gel method and ratio of TiO<sub>2</sub>–ZnO was optimized by single parameter study. The doping of ZnO over TiO<sub>2</sub> surface was studied by FTIR, XRD, SEM, and EDAX analysis. ANOVA suggests the quadratic model is closely fitted for both biodiesel yield and biodiesel cost. The value of adjusted and predicted <i>R</i><sup>2</sup> was found to be 0.9309 and 0.8465 for biodiesel yield. While the value of adjusted and predicted <i>R</i><sup>2</sup> was found to be 0.9313 and 0.8472 for biodiesel cost. The maximum actual and predicted yield of 88% was obtained at catalyst dose: 2.5 g/l; methanol: 50 ml; waste cooking oil (WCO): 50 ml; time: 120 min, and temperature: 65 °C. The % error between actual and predicted biodiesel varies in the range of −7.90–7.19%. The minimum actual and predicted WCOBD cost was found to be INR 47.29/l and INR 44.68/l with % error in the range of −19.56–13.87% at catalyst dose: 2.5 g/l; methanol: 25 ml; waste cooking oil (WCO): 75 ml; time: 120 min, and temperature: 65 °C, respectively. Overall, the model used to predict the waste cooking oil biodiesel yield, and its cost is closely fitted with the actual result.</p></div>\",\"PeriodicalId\":684,\"journal\":{\"name\":\"Korean Journal of Chemical Engineering\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":2.9000,\"publicationDate\":\"2024-09-10\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Korean Journal of Chemical Engineering\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s11814-024-00262-7\",\"RegionNum\":4,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Korean Journal of Chemical Engineering","FirstCategoryId":"5","ListUrlMain":"https://link.springer.com/article/10.1007/s11814-024-00262-7","RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Optimization of Biodiesel Yield and Cost Analysis from Waste Cooking Oil Using Box–Behnken Design with TiO2–ZnO-Based Nano-catalyst
The present work deals with the optimization of waste cooking oil biodiesel yield (WCOBD) and its preparation cost with the help of Box–Behnken design (BBD) using response surface methodology (RSM) in design expert software. Initially, TiO2–ZnO (nanocatalyst) was prepared with the help of the sol–gel method and ratio of TiO2–ZnO was optimized by single parameter study. The doping of ZnO over TiO2 surface was studied by FTIR, XRD, SEM, and EDAX analysis. ANOVA suggests the quadratic model is closely fitted for both biodiesel yield and biodiesel cost. The value of adjusted and predicted R2 was found to be 0.9309 and 0.8465 for biodiesel yield. While the value of adjusted and predicted R2 was found to be 0.9313 and 0.8472 for biodiesel cost. The maximum actual and predicted yield of 88% was obtained at catalyst dose: 2.5 g/l; methanol: 50 ml; waste cooking oil (WCO): 50 ml; time: 120 min, and temperature: 65 °C. The % error between actual and predicted biodiesel varies in the range of −7.90–7.19%. The minimum actual and predicted WCOBD cost was found to be INR 47.29/l and INR 44.68/l with % error in the range of −19.56–13.87% at catalyst dose: 2.5 g/l; methanol: 25 ml; waste cooking oil (WCO): 75 ml; time: 120 min, and temperature: 65 °C, respectively. Overall, the model used to predict the waste cooking oil biodiesel yield, and its cost is closely fitted with the actual result.
期刊介绍:
The Korean Journal of Chemical Engineering provides a global forum for the dissemination of research in chemical engineering. The Journal publishes significant research results obtained in the Asia-Pacific region, and simultaneously introduces recent technical progress made in other areas of the world to this region. Submitted research papers must be of potential industrial significance and specifically concerned with chemical engineering. The editors will give preference to papers having a clearly stated practical scope and applicability in the areas of chemical engineering, and to those where new theoretical concepts are supported by new experimental details. The Journal also regularly publishes featured reviews on emerging and industrially important subjects of chemical engineering as well as selected papers presented at international conferences on the subjects.