利用基于 TiO2-ZnO 纳米催化剂的盒式贝肯设计优化废食用油生物柴油产量和成本分析

IF 2.9 4区 工程技术 Q2 CHEMISTRY, MULTIDISCIPLINARY Korean Journal of Chemical Engineering Pub Date : 2024-09-10 DOI:10.1007/s11814-024-00262-7
Priyankesh Kumar, Devesh Kumar, Ravi Shankar, Prateek Khare
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引用次数: 0

摘要

本研究利用设计专家软件中的响应面方法学(RSM),在方框-贝肯设计(BBD)的帮助下,对废弃食用油生物柴油产量(WCOBD)及其制备成本进行了优化。最初,利用溶胶-凝胶法制备了 TiO2-ZnO(纳米催化剂),并通过单参数研究对 TiO2-ZnO 的比例进行了优化。通过傅立叶变换红外光谱、X 射线衍射、扫描电镜和 EDAX 分析研究了 ZnO 在 TiO2 表面的掺杂情况。方差分析表明,二次模型与生物柴油产量和生物柴油成本密切相关。生物柴油产量的调整 R2 值和预测 R2 值分别为 0.9309 和 0.8465。而生物柴油成本的调整和预测 R2 值分别为 0.9313 和 0.8472。在催化剂剂量:2.5 克/升;甲醇:50 毫升;废食用油(WCO):50 毫升;时间:120 分钟;反应时间:20 分钟的条件下,实际和预测的最高产率均为 88%:时间:120 分钟,温度:65 °C。实际生物柴油与预测生物柴油之间的误差在 -7.90-7.19% 之间。在催化剂剂量:2.5 克/升;甲醇:25 毫升;废食用油(WCO):75 毫升;时间:120 分钟;温度:65 °C的条件下,WCOBD 的实际成本和预测成本分别为 47.29 印度卢比/升和 44.68 印度卢比/升,误差范围为-19.56%-13.87%:时间:120 分钟,温度:65 °C。总体而言,用于预测废食用油生物柴油产量及其成本的模型与实际结果非常吻合。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

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Optimization of Biodiesel Yield and Cost Analysis from Waste Cooking Oil Using Box–Behnken Design with TiO2–ZnO-Based Nano-catalyst

The present work deals with the optimization of waste cooking oil biodiesel yield (WCOBD) and its preparation cost with the help of Box–Behnken design (BBD) using response surface methodology (RSM) in design expert software. Initially, TiO2–ZnO (nanocatalyst) was prepared with the help of the sol–gel method and ratio of TiO2–ZnO was optimized by single parameter study. The doping of ZnO over TiO2 surface was studied by FTIR, XRD, SEM, and EDAX analysis. ANOVA suggests the quadratic model is closely fitted for both biodiesel yield and biodiesel cost. The value of adjusted and predicted R2 was found to be 0.9309 and 0.8465 for biodiesel yield. While the value of adjusted and predicted R2 was found to be 0.9313 and 0.8472 for biodiesel cost. The maximum actual and predicted yield of 88% was obtained at catalyst dose: 2.5 g/l; methanol: 50 ml; waste cooking oil (WCO): 50 ml; time: 120 min, and temperature: 65 °C. The % error between actual and predicted biodiesel varies in the range of −7.90–7.19%. The minimum actual and predicted WCOBD cost was found to be INR 47.29/l and INR 44.68/l with % error in the range of −19.56–13.87% at catalyst dose: 2.5 g/l; methanol: 25 ml; waste cooking oil (WCO): 75 ml; time: 120 min, and temperature: 65 °C, respectively. Overall, the model used to predict the waste cooking oil biodiesel yield, and its cost is closely fitted with the actual result.

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来源期刊
Korean Journal of Chemical Engineering
Korean Journal of Chemical Engineering 工程技术-工程:化工
CiteScore
4.60
自引率
11.10%
发文量
310
审稿时长
4.7 months
期刊介绍: The Korean Journal of Chemical Engineering provides a global forum for the dissemination of research in chemical engineering. The Journal publishes significant research results obtained in the Asia-Pacific region, and simultaneously introduces recent technical progress made in other areas of the world to this region. Submitted research papers must be of potential industrial significance and specifically concerned with chemical engineering. The editors will give preference to papers having a clearly stated practical scope and applicability in the areas of chemical engineering, and to those where new theoretical concepts are supported by new experimental details. The Journal also regularly publishes featured reviews on emerging and industrially important subjects of chemical engineering as well as selected papers presented at international conferences on the subjects.
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