{"title":"用硅烷偶联剂和碳纳米管进行纤维表面处理对碳纤维增强聚酰胺 6 复合材料机械性能的影响","authors":"Haoqiang Du, Guijun Xian, Jingwei Tian, Zirong Ma, Chenggao Li, Meiyin Xin, Yunfeng Zhang","doi":"10.1002/pc.29035","DOIUrl":null,"url":null,"abstract":"<jats:label/>The mechanical properties of carbon fiber (CF) reinforced thermoplastic polymer composites are primarily governed by the interphase between CFs and matrix. However, the inherent inertness of CF surfaces combined with the high viscosity and processing temperatures of thermoplastic resin often result in relatively weak interfacial bonding. This study aims to enhance the interfacial adhesion of carbon fiber reinforced polyamide 6 composites to improve their mechanical properties. CFs were de‐sized and oxidized, followed by re‐sizing with silanized carbon nanotubes. Fracture morphology and composition analysis of the fibers were conducted, and the fibers were subsequently incorporated into composites for mechanical testing. Results revealed a 20.0% increase in tensile strength, a 25.11% increase in flexural strength, and a 24.88% increase in interlaminar shear strength for the resized‐carbon fiber reinforced polyamide 6 composites compared to the pristine‐carbon fiber reinforced polyamide composites. The cross‐sectional morphology of the modified composites exhibited a zig‐zag fracture pattern. Dynamic mechanical analysis indicated that the modified fibers required higher activation energy for the free movement of the polyamide 6 molecular chain. These findings suggest that surface treatment enhances the interfacial adhesive between CF and resin, thereby significantly improving the mechanical properties of carbon fiber reinforced polyamide 6 composites.Highlights<jats:list list-type=\"bullet\"> <jats:list-item>An efficient and reliable carbon fiber surface treatment method is proposed.</jats:list-item> <jats:list-item>Surface modification improves surface chemical activity of carbon fibers.</jats:list-item> <jats:list-item>Composites show substantial improvements in mechanical properties.</jats:list-item> <jats:list-item>Interfacial performance enhancement mechanism of composite was revealed.</jats:list-item> </jats:list>","PeriodicalId":20375,"journal":{"name":"Polymer Composites","volume":null,"pages":null},"PeriodicalIF":4.8000,"publicationDate":"2024-09-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Effect of fiber surface treatment with silane coupling agents and carbon nanotubes on mechanical properties of carbon fiber reinforced polyamide 6 composites\",\"authors\":\"Haoqiang Du, Guijun Xian, Jingwei Tian, Zirong Ma, Chenggao Li, Meiyin Xin, Yunfeng Zhang\",\"doi\":\"10.1002/pc.29035\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<jats:label/>The mechanical properties of carbon fiber (CF) reinforced thermoplastic polymer composites are primarily governed by the interphase between CFs and matrix. However, the inherent inertness of CF surfaces combined with the high viscosity and processing temperatures of thermoplastic resin often result in relatively weak interfacial bonding. This study aims to enhance the interfacial adhesion of carbon fiber reinforced polyamide 6 composites to improve their mechanical properties. CFs were de‐sized and oxidized, followed by re‐sizing with silanized carbon nanotubes. Fracture morphology and composition analysis of the fibers were conducted, and the fibers were subsequently incorporated into composites for mechanical testing. Results revealed a 20.0% increase in tensile strength, a 25.11% increase in flexural strength, and a 24.88% increase in interlaminar shear strength for the resized‐carbon fiber reinforced polyamide 6 composites compared to the pristine‐carbon fiber reinforced polyamide composites. The cross‐sectional morphology of the modified composites exhibited a zig‐zag fracture pattern. Dynamic mechanical analysis indicated that the modified fibers required higher activation energy for the free movement of the polyamide 6 molecular chain. These findings suggest that surface treatment enhances the interfacial adhesive between CF and resin, thereby significantly improving the mechanical properties of carbon fiber reinforced polyamide 6 composites.Highlights<jats:list list-type=\\\"bullet\\\"> <jats:list-item>An efficient and reliable carbon fiber surface treatment method is proposed.</jats:list-item> <jats:list-item>Surface modification improves surface chemical activity of carbon fibers.</jats:list-item> <jats:list-item>Composites show substantial improvements in mechanical properties.</jats:list-item> <jats:list-item>Interfacial performance enhancement mechanism of composite was revealed.</jats:list-item> </jats:list>\",\"PeriodicalId\":20375,\"journal\":{\"name\":\"Polymer Composites\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":4.8000,\"publicationDate\":\"2024-09-12\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Polymer Composites\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://doi.org/10.1002/pc.29035\",\"RegionNum\":2,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"MATERIALS SCIENCE, COMPOSITES\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Polymer Composites","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.1002/pc.29035","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"MATERIALS SCIENCE, COMPOSITES","Score":null,"Total":0}
Effect of fiber surface treatment with silane coupling agents and carbon nanotubes on mechanical properties of carbon fiber reinforced polyamide 6 composites
The mechanical properties of carbon fiber (CF) reinforced thermoplastic polymer composites are primarily governed by the interphase between CFs and matrix. However, the inherent inertness of CF surfaces combined with the high viscosity and processing temperatures of thermoplastic resin often result in relatively weak interfacial bonding. This study aims to enhance the interfacial adhesion of carbon fiber reinforced polyamide 6 composites to improve their mechanical properties. CFs were de‐sized and oxidized, followed by re‐sizing with silanized carbon nanotubes. Fracture morphology and composition analysis of the fibers were conducted, and the fibers were subsequently incorporated into composites for mechanical testing. Results revealed a 20.0% increase in tensile strength, a 25.11% increase in flexural strength, and a 24.88% increase in interlaminar shear strength for the resized‐carbon fiber reinforced polyamide 6 composites compared to the pristine‐carbon fiber reinforced polyamide composites. The cross‐sectional morphology of the modified composites exhibited a zig‐zag fracture pattern. Dynamic mechanical analysis indicated that the modified fibers required higher activation energy for the free movement of the polyamide 6 molecular chain. These findings suggest that surface treatment enhances the interfacial adhesive between CF and resin, thereby significantly improving the mechanical properties of carbon fiber reinforced polyamide 6 composites.HighlightsAn efficient and reliable carbon fiber surface treatment method is proposed.Surface modification improves surface chemical activity of carbon fibers.Composites show substantial improvements in mechanical properties.Interfacial performance enhancement mechanism of composite was revealed.
期刊介绍:
Polymer Composites is the engineering and scientific journal serving the fields of reinforced plastics and polymer composites including research, production, processing, and applications. PC brings you the details of developments in this rapidly expanding area of technology long before they are commercial realities.