Fluorinated boron nitride nanosheets for high thermal conductivity and low dielectric constant silicone rubber composites

Increasing miniaturization and integration of microelectronic devices have led to an unprecedented attention on heat dissipation and signal transmission of electronic equipment. However, the mostly used method to enhance the thermal conductivity of polymers by adding thermally conductive fillers usually results in the increase of dielectric constant (Dk). It was still challenging to synergistically achieve low Dk and high thermal conductivity of polymer‐matrix composites. Herein, hydroxylated boron nitride nanosheet (BNNS‐OH) with a high yield of 35.67% was prepared by the liquid ultrasonic exfoliation under the assistance of sodium cholate (SC), and grafted with (1H,1H,2H,2H‐perfluorodecyl) trimethoxy silane to prepare fluorinated boron nitride nanosheets (F‐BNNS), which can uniformly disperse in liquid silicone rubber (LSR) and reduce the Dk of LSR composites. The thermal conductivity of LSR composites with 20 wt% F‐BNNS reached 0.489 W·m−1·K−1, showing an increase of 307.35% in comparison with pure LSR (0.12 W·m−1·K−1). Meantime, the Dk of as‐obtained LSR/F‐BNNS (20 wt%) composites is reduced from 3.4 to 2.6, and the dielectric loss (Df) is less than 0.012. The facile and rational design of fluorinated BNNS offers a new insight for the high‐end electronic packaging materials.Highlights A new method of exfoliation and fluorinated treatment of h‐BN was proposed. The LSR composites achieved an ultralow Dk of 2.63 via fluorinated BNNS. Thermal conductivity of LSR composites increased by 307.35% than pure LSR.