含改性矿物填料的水分散涂料和清漆成分的性能研究

IF 2.9 3区 材料科学 Q2 MATERIALS SCIENCE, COATINGS & FILMS Coatings Pub Date : 2024-09-08 DOI:10.3390/coatings14091154
Ruslan E. Nurlybayev, Erzhan I. Kuldeyev, Zaure N. Altayeva, Zhanar O. Zhumadilova, Axaya S. Yestemessova, Yelzhan S. Orynbekov
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引用次数: 0

摘要

本文介绍了致力于改善基于聚丙烯酸酯水分散体的油漆和清漆涂料特性的研究成果;建议通过引入矿物原料作为填料和熟石灰,并在涡流层装置中进行后续处理,对其进行改性。引入活性硅藻土不会导致遮盖力和附着力下降,也不会增加涂料的孔隙率。涂料的改性有助于提高其操作性能,这可能与复合材料中自由体积的减少以及具有改性物理和化学特性的聚合物边界层的形成有关。本研究的目的是在聚丙烯酸酯的基础上获得一种含有改性硅藻土的水分散涂料和清漆组合物,并随后研究其主要物理和机械参数。这项工作是通过以下方法进行的:测定对照组合物的孔隙率、附着力、弹性和遮盖力;测定使用改性填料获得的复合材料的孔隙率、附着力、弹性和遮盖力;使用 FLIRB620 热成像仪调查辐射对油漆涂层表面红外光谱的影响。研究结果表明,用硅活性硅藻土改性水分散体有助于消除基于丙烯酸酯粘合剂的材料和涂料的主要缺点--低耐水性和低物理机械特性。在以丙烯酸酯为基料的水乳涂料中引入改性硅藻土不会导致涂料的主要性能特征(孔隙率、附着力、弹性和遮盖力)恶化。
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Study of Properties of Water-Dispersion Paint and Varnish Compositions with the Content of Modified Mineral Filler
This article presents the results of research work devoted to improving the characteristics of paint and varnish coatings based on aqueous dispersions of polyacrylates; it is proposed to modify them by introducing mineral raw materials as fillers and hydrated lime, with subsequent processing in a vortex layer apparatus. The introduction of activated diatomite does not cause the deterioration of covering power, adhesion or an increase in the porosity of the paint material. The modification of coatings contributes to an increase in their operational properties, which can be associated with a reduction in the free volume in the composite and the formation of polymer boundary layers with modified physical and chemical properties. The aim of this study is to obtain a water-dispersion paint and varnish composition containing modified diatomite on a polyacrylate basis and, subsequently, study its main physical and mechanical parameters. The work has been carried out by the following method: determination of porosity, adhesion, elasticity and covering power of the control composition; determination of porosity, adhesion, elasticity and covering power of the obtained composites using modified filler; investigation of the influence of radiation on the infrared spectrum of the paint coating surface using a FLIRB620 thermal imager. As a result of this research work, it was noticed that the modification of water dispersions with silica-activated diatomite helps to eliminate the main disadvantages of materials and coatings based on acrylate binders—low water resistance and low physical and mechanical characteristics. The introduction of modified diatomite into water-emulsion paint on an acrylate base does not lead to the deterioration of the main performance characteristics of paint coatings—porosity, adhesion, elasticity and covering.
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来源期刊
Coatings
Coatings Materials Science-Surfaces, Coatings and Films
CiteScore
5.00
自引率
11.80%
发文量
1657
审稿时长
1.4 months
期刊介绍: Coatings is an international, peer-reviewed open access journal of coatings and surface engineering. It publishes reviews, research articles, communications and technical notes. Our aim is to encourage scientists to publish their experimental and theoretical results in as much detail as possible. There is no restriction on the length of the papers. Full experimental and/or methodical details must be provided. There are, in addition, unique features of this journal: * manuscripts regarding research proposals and research ideas will be particularly welcomed * electronic files or software regarding the full details of the calculation and experimental procedure - if unable to be published in a normal way - can be deposited as supplementary material
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