{"title":"纳米镍钴针的双金属位点置换作为促进水分离的双功能电催化剂","authors":"Ya Gao, Yuhui Qiao, Xuanrong Li, Chengyu Huang, Jing Zhang, Yirong Wang, Xingli Zou, Zhonghong Xia, Xinxin Yang, Xionggang Lu, Yufeng Zhao","doi":"10.1007/s12274-024-6952-3","DOIUrl":null,"url":null,"abstract":"<p>The bimetallic nickel-cobalt phosphide (NiCoP) has been confirmed as an efficient electrocatalyst in water splitting. But little attention is paid to the selectivity and affinity of metal sites on hydrogen evolution reaction (HER) and oxygen evolution reaction (OER). Herein, we report a trace-Zn-doping (2.18 wt.%) NiCoP (Zn-NiCoP) whereby the nanoparticles self-aggregated to form elongated nanoneedles. We discover that both Co and Ni sites can be replaced by Zn. The Co substitution improves HER, while the Ni substitution dramatically reduces the energy barrier of the rate-determining step (*O → *OOH). The negative shift of d-band centers after Zn doping ameliorates the intermediate desorption. Therefore, Zn-NiCoP demonstrates superior electrocatalytic activity with overpotentials of 48 and 240 mV for HER and OER at 10 and 50 mA·cm<sup>−2</sup>, respectively. The cell voltage with Zn-NiCoP as both anode and cathode in water splitting was as low as 1.35 V at 10 mA·cm<sup>−2</sup>.</p>","PeriodicalId":713,"journal":{"name":"Nano Research","volume":null,"pages":null},"PeriodicalIF":9.5000,"publicationDate":"2024-08-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Bimetallic site substitution of NiCoP nanoneedles as bifunctional electrocatalyst for boosted water splitting\",\"authors\":\"Ya Gao, Yuhui Qiao, Xuanrong Li, Chengyu Huang, Jing Zhang, Yirong Wang, Xingli Zou, Zhonghong Xia, Xinxin Yang, Xionggang Lu, Yufeng Zhao\",\"doi\":\"10.1007/s12274-024-6952-3\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>The bimetallic nickel-cobalt phosphide (NiCoP) has been confirmed as an efficient electrocatalyst in water splitting. But little attention is paid to the selectivity and affinity of metal sites on hydrogen evolution reaction (HER) and oxygen evolution reaction (OER). Herein, we report a trace-Zn-doping (2.18 wt.%) NiCoP (Zn-NiCoP) whereby the nanoparticles self-aggregated to form elongated nanoneedles. We discover that both Co and Ni sites can be replaced by Zn. The Co substitution improves HER, while the Ni substitution dramatically reduces the energy barrier of the rate-determining step (*O → *OOH). The negative shift of d-band centers after Zn doping ameliorates the intermediate desorption. Therefore, Zn-NiCoP demonstrates superior electrocatalytic activity with overpotentials of 48 and 240 mV for HER and OER at 10 and 50 mA·cm<sup>−2</sup>, respectively. The cell voltage with Zn-NiCoP as both anode and cathode in water splitting was as low as 1.35 V at 10 mA·cm<sup>−2</sup>.</p>\",\"PeriodicalId\":713,\"journal\":{\"name\":\"Nano Research\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":9.5000,\"publicationDate\":\"2024-08-31\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Nano Research\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://doi.org/10.1007/s12274-024-6952-3\",\"RegionNum\":2,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Nano Research","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.1007/s12274-024-6952-3","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
Bimetallic site substitution of NiCoP nanoneedles as bifunctional electrocatalyst for boosted water splitting
The bimetallic nickel-cobalt phosphide (NiCoP) has been confirmed as an efficient electrocatalyst in water splitting. But little attention is paid to the selectivity and affinity of metal sites on hydrogen evolution reaction (HER) and oxygen evolution reaction (OER). Herein, we report a trace-Zn-doping (2.18 wt.%) NiCoP (Zn-NiCoP) whereby the nanoparticles self-aggregated to form elongated nanoneedles. We discover that both Co and Ni sites can be replaced by Zn. The Co substitution improves HER, while the Ni substitution dramatically reduces the energy barrier of the rate-determining step (*O → *OOH). The negative shift of d-band centers after Zn doping ameliorates the intermediate desorption. Therefore, Zn-NiCoP demonstrates superior electrocatalytic activity with overpotentials of 48 and 240 mV for HER and OER at 10 and 50 mA·cm−2, respectively. The cell voltage with Zn-NiCoP as both anode and cathode in water splitting was as low as 1.35 V at 10 mA·cm−2.
期刊介绍：
Nano Research is a peer-reviewed, international and interdisciplinary research journal that focuses on all aspects of nanoscience and nanotechnology. It solicits submissions in various topical areas, from basic aspects of nanoscale materials to practical applications. The journal publishes articles on synthesis, characterization, and manipulation of nanomaterials; nanoscale physics, electrical transport, and quantum physics; scanning probe microscopy and spectroscopy; nanofluidics; nanosensors; nanoelectronics and molecular electronics; nano-optics, nano-optoelectronics, and nano-photonics; nanomagnetics; nanobiotechnology and nanomedicine; and nanoscale modeling and simulations. Nano Research offers readers a combination of authoritative and comprehensive Reviews, original cutting-edge research in Communication and Full Paper formats. The journal also prioritizes rapid review to ensure prompt publication.
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