相互关联化学反应的变异理论

Maxim V. Dudorov
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引用次数: 0

摘要

用物理动力学和非平衡热力学的方法研究生物系统时,经常会遇到研究非线性过程的困难,因为这些过程严重偏离平衡状态。本文提出了一种新的变异方法,使我们能够在考虑非平衡态效应影响的情况下概括化学过程的模式。考虑到几个反应之间的相互影响,我们开发了一种新方法,用于对几个反应的动 力学进行一般描述。我们考虑了几个相互影响程度不同的反应的实际例子和模型计算。通过对几个反应的计算,我们可以评估它们对反应速率变化以及反应试剂浓度随时间变化的相互影响。所得结果可用于描述各种系统中的复杂化学反应。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

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Variation theory of interconnected chemical reactions

The study of biological systems by methods of physical kinetics and non-equilibrium thermodynamics often faces the difficulty of studying nonlinear processes due to the significant deviation from equilibrium. In this paper, the new variation approach is proposed that allows us to generalize the patterns of chemical processes taking into account the influence of non-equilibrium effects.The study of interrelated chemical reactions is considered as one of the applications of this theory. The new method has been developed for the general description of the kinetics of several reactions, taking into account their mutual influence on each other. Practical examples and model calculations for several reactions with varying the degrees of influence on each other are considered. The calculations performed for the several reactions allowed us to evaluate their mutual influence on the change in the reaction rate, as well as on the change in the reaction reagents concentration over time. The results obtained can be used to describe complex chemical reactions in various systems.

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