相互关联化学反应的变异理论

Maxim V. Dudorov
{"title":"相互关联化学反应的变异理论","authors":"Maxim V. Dudorov","doi":"10.1140/epjs/s11734-024-01313-0","DOIUrl":null,"url":null,"abstract":"<p>The study of biological systems by methods of physical kinetics and non-equilibrium thermodynamics often faces the difficulty of studying nonlinear processes due to the significant deviation from equilibrium. In this paper, the new variation approach is proposed that allows us to generalize the patterns of chemical processes taking into account the influence of non-equilibrium effects.The study of interrelated chemical reactions is considered as one of the applications of this theory. The new method has been developed for the general description of the kinetics of several reactions, taking into account their mutual influence on each other. Practical examples and model calculations for several reactions with varying the degrees of influence on each other are considered. The calculations performed for the several reactions allowed us to evaluate their mutual influence on the change in the reaction rate, as well as on the change in the reaction reagents concentration over time. The results obtained can be used to describe complex chemical reactions in various systems.</p>","PeriodicalId":501403,"journal":{"name":"The European Physical Journal Special Topics","volume":"4 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2024-09-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Variation theory of interconnected chemical reactions\",\"authors\":\"Maxim V. Dudorov\",\"doi\":\"10.1140/epjs/s11734-024-01313-0\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>The study of biological systems by methods of physical kinetics and non-equilibrium thermodynamics often faces the difficulty of studying nonlinear processes due to the significant deviation from equilibrium. In this paper, the new variation approach is proposed that allows us to generalize the patterns of chemical processes taking into account the influence of non-equilibrium effects.The study of interrelated chemical reactions is considered as one of the applications of this theory. The new method has been developed for the general description of the kinetics of several reactions, taking into account their mutual influence on each other. Practical examples and model calculations for several reactions with varying the degrees of influence on each other are considered. The calculations performed for the several reactions allowed us to evaluate their mutual influence on the change in the reaction rate, as well as on the change in the reaction reagents concentration over time. The results obtained can be used to describe complex chemical reactions in various systems.</p>\",\"PeriodicalId\":501403,\"journal\":{\"name\":\"The European Physical Journal Special Topics\",\"volume\":\"4 1\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2024-09-05\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"The European Physical Journal Special Topics\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1140/epjs/s11734-024-01313-0\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"The European Physical Journal Special Topics","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1140/epjs/s11734-024-01313-0","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0

摘要

用物理动力学和非平衡热力学的方法研究生物系统时,经常会遇到研究非线性过程的困难,因为这些过程严重偏离平衡状态。本文提出了一种新的变异方法,使我们能够在考虑非平衡态效应影响的情况下概括化学过程的模式。考虑到几个反应之间的相互影响,我们开发了一种新方法,用于对几个反应的动 力学进行一般描述。我们考虑了几个相互影响程度不同的反应的实际例子和模型计算。通过对几个反应的计算,我们可以评估它们对反应速率变化以及反应试剂浓度随时间变化的相互影响。所得结果可用于描述各种系统中的复杂化学反应。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

摘要图片

查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
Variation theory of interconnected chemical reactions

The study of biological systems by methods of physical kinetics and non-equilibrium thermodynamics often faces the difficulty of studying nonlinear processes due to the significant deviation from equilibrium. In this paper, the new variation approach is proposed that allows us to generalize the patterns of chemical processes taking into account the influence of non-equilibrium effects.The study of interrelated chemical reactions is considered as one of the applications of this theory. The new method has been developed for the general description of the kinetics of several reactions, taking into account their mutual influence on each other. Practical examples and model calculations for several reactions with varying the degrees of influence on each other are considered. The calculations performed for the several reactions allowed us to evaluate their mutual influence on the change in the reaction rate, as well as on the change in the reaction reagents concentration over time. The results obtained can be used to describe complex chemical reactions in various systems.

求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
自引率
0.00%
发文量
0
期刊最新文献
Classification of sprott chaotic systems via projection of the attractors using deep learning methods Master–slave synchronization of electrocardiogram chaotic networks dealing with stochastic perturbance Approximate controllability results of $$\psi$$ -Hilfer fractional neutral hemivariational inequalities with infinite delay via almost sectorial operators Characterization of magnetic nanoparticles for magnetic particle spectroscopy-based sensitive cell quantification Jet substructure probe to freeze-in dark matter in alternative cosmological background
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1