跨临界奥氏体化后淬火对石油天然气工业用 K55 级钢微观结构和拉伸性能的影响

IF 16.4 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY Accounts of Chemical Research Pub Date : 2024-08-28 DOI:10.1002/srin.202400478
Verônica Stela da Silva Lima, Arthur Cançado Schuttenberg, Geraldo Lúcio de Faria
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引用次数: 0

摘要

API K55 级钢广泛用于石油和天然气勘探用无缝钢管,尤其是井筒用套管。传统上,这种钢材的加工方法是先热轧,然后进行淬火和回火,以获得所需的尺寸和微观结构特征,同时兼顾高强度和延展性。本文介绍了一种替代方法,通过对高强度低合金钢进行临界奥氏体化后淬火热处理,获得双相显微组织(铁素体/马氏体),从而达到 API K55 级钢所需的拉伸性能。热力学模拟和稀释实验表明,提高奥氏体化温度可促进奥氏体的形成,显著降低其碳含量,从而促进马氏体转变,提高 Ms 和 Mf 温度。完整的相变图显示了奥氏体化温度如何影响淬火热处理过程中的马氏体转变动力学。结果表明,在 750 ℃ 下奥氏体化,然后在 650 ℃ 下淬火和短回火,可产生 30% 铁素体和 70% 马氏体的双相微观结构,在机械强度和延展性之间实现了良好的平衡,符合 API K55 等级要求,超越了行业内的传统方法。
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Effect of Quenching Post‐Intercritical Austenitizing on the Microstructure and Tensile Properties of an K55 Grade Steel for Oil and Gas Industry
The API K55 grade steel is widely utilized in seamless pipes for oil and gas exploration, especially as casing pipes for wellbores. Traditionally, this steel is processed using hot rolling followed by quenching and tempering to achieve the desired dimensional and microstructural characteristics, balancing high strength with ductility. This article introduces an alternative method to attaining the required tensile properties for API K55 grade steel by employing a biphasic microstructure (ferrite/martensite) achieved through quenching post‐intercritical austenitizing heat treatment to high‐strength‐low‐alloy steel. Thermodynamic simulations and dilatometric experiments revealed that increasing the austenitizing temperature enhances austenite formation, decreasing significantly its carbon content, which facilitates martensitic transformation and increases the Ms and Mf temperatures. A complete phase transformation mapping was presented, highlighting how the austenitizing temperature influences martensitic transformation kinetics during the quenching heat treatment. It was concluded that austenitizing at 750 °C, followed by quenching and short tempering at 650 °C, produced a biphasic microstructure with 30% ferrite and 70% martensite, providing a favorable balance between mechanical strength and ductility that meets the API K55 grade requirements, surpassing traditional methods in the industry.
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来源期刊
Accounts of Chemical Research
Accounts of Chemical Research 化学-化学综合
CiteScore
31.40
自引率
1.10%
发文量
312
审稿时长
2 months
期刊介绍: Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
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