Yukai Peng, Jiahui Li, Jingfang Xue, Hao Jin, Yu Zeng, Wei Zhao, Xuebin Su, Rong Hua
{"title":"均相苯乙烯吡啶树脂(LSL-030-bd)的合成及其在铀和钼分离中的应用","authors":"Yukai Peng, Jiahui Li, Jingfang Xue, Hao Jin, Yu Zeng, Wei Zhao, Xuebin Su, Rong Hua","doi":"10.1007/s10967-024-09698-x","DOIUrl":null,"url":null,"abstract":"<div><p>This paper synthesized a stytypyridine (LSL-030-bd) resin with small particle size and uniform distribution to recover molybdenum resources leached during neutral in-situ leaching of uranium. The batch experiment results show that the LSL-030-bd ion exchange resin produced had the highest U(VI) adsorption capacity at pH 7.0, reaching 187.20 mg·g<sup>−1</sup>. At pH 3.0, LSL-030-bd resin adsorbed 180.17 mg·g<sup>−1</sup> of Mo(VI). At pH 7.0, the resin exhibited the highest separation coefficient for uranium and molybdenum, with a KD value of 9.08. The resin's adsorption of U(VI) is a spontaneous endothermic process involving monolayer adsorption that combines physical and chemical adsorption. The adsorption of Mo(VI) by the resin is an exothermic process that is not spontaneous. It involves monomolecular layer adsorption with hydrogen bonding as the primary chemical force. By desorbing molybdenum with NH<sub>4</sub>SCN, followed by utilizing a mixed solution of NH<sub>4</sub>HCO<sub>3</sub> and (NH<sub>4</sub>)<sub>2</sub>CO<sub>3</sub> to desorb uranium, a step-by-step desorption process may be achieved to separate and purify uranium and molybdenum.</p></div>","PeriodicalId":661,"journal":{"name":"Journal of Radioanalytical and Nuclear Chemistry","volume":null,"pages":null},"PeriodicalIF":1.5000,"publicationDate":"2024-08-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Synthesis of homogeneous styrenic pyridine resin (LSL-030-bd) and its application to the separation of uranium and molybdenum\",\"authors\":\"Yukai Peng, Jiahui Li, Jingfang Xue, Hao Jin, Yu Zeng, Wei Zhao, Xuebin Su, Rong Hua\",\"doi\":\"10.1007/s10967-024-09698-x\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>This paper synthesized a stytypyridine (LSL-030-bd) resin with small particle size and uniform distribution to recover molybdenum resources leached during neutral in-situ leaching of uranium. The batch experiment results show that the LSL-030-bd ion exchange resin produced had the highest U(VI) adsorption capacity at pH 7.0, reaching 187.20 mg·g<sup>−1</sup>. At pH 3.0, LSL-030-bd resin adsorbed 180.17 mg·g<sup>−1</sup> of Mo(VI). At pH 7.0, the resin exhibited the highest separation coefficient for uranium and molybdenum, with a KD value of 9.08. The resin's adsorption of U(VI) is a spontaneous endothermic process involving monolayer adsorption that combines physical and chemical adsorption. The adsorption of Mo(VI) by the resin is an exothermic process that is not spontaneous. It involves monomolecular layer adsorption with hydrogen bonding as the primary chemical force. By desorbing molybdenum with NH<sub>4</sub>SCN, followed by utilizing a mixed solution of NH<sub>4</sub>HCO<sub>3</sub> and (NH<sub>4</sub>)<sub>2</sub>CO<sub>3</sub> to desorb uranium, a step-by-step desorption process may be achieved to separate and purify uranium and molybdenum.</p></div>\",\"PeriodicalId\":661,\"journal\":{\"name\":\"Journal of Radioanalytical and Nuclear Chemistry\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":1.5000,\"publicationDate\":\"2024-08-29\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Radioanalytical and Nuclear Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s10967-024-09698-x\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, ANALYTICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Radioanalytical and Nuclear Chemistry","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1007/s10967-024-09698-x","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, ANALYTICAL","Score":null,"Total":0}
Synthesis of homogeneous styrenic pyridine resin (LSL-030-bd) and its application to the separation of uranium and molybdenum
This paper synthesized a stytypyridine (LSL-030-bd) resin with small particle size and uniform distribution to recover molybdenum resources leached during neutral in-situ leaching of uranium. The batch experiment results show that the LSL-030-bd ion exchange resin produced had the highest U(VI) adsorption capacity at pH 7.0, reaching 187.20 mg·g−1. At pH 3.0, LSL-030-bd resin adsorbed 180.17 mg·g−1 of Mo(VI). At pH 7.0, the resin exhibited the highest separation coefficient for uranium and molybdenum, with a KD value of 9.08. The resin's adsorption of U(VI) is a spontaneous endothermic process involving monolayer adsorption that combines physical and chemical adsorption. The adsorption of Mo(VI) by the resin is an exothermic process that is not spontaneous. It involves monomolecular layer adsorption with hydrogen bonding as the primary chemical force. By desorbing molybdenum with NH4SCN, followed by utilizing a mixed solution of NH4HCO3 and (NH4)2CO3 to desorb uranium, a step-by-step desorption process may be achieved to separate and purify uranium and molybdenum.
期刊介绍:
An international periodical publishing original papers, letters, review papers and short communications on nuclear chemistry. The subjects covered include: Nuclear chemistry, Radiochemistry, Radiation chemistry, Radiobiological chemistry, Environmental radiochemistry, Production and control of radioisotopes and labelled compounds, Nuclear power plant chemistry, Nuclear fuel chemistry, Radioanalytical chemistry, Radiation detection and measurement, Nuclear instrumentation and automation, etc.