Yanzhuang Jiang, Qian Yang, Lin Zhang, Liyan Yu, Na Song, Lina Sui, Qingli Wei, Lifeng Dong
{"title":"利用 MIL-101(Cr)/Fe3O4 中间膜开发高通量反渗透膜","authors":"Yanzhuang Jiang, Qian Yang, Lin Zhang, Liyan Yu, Na Song, Lina Sui, Qingli Wei, Lifeng Dong","doi":"10.1007/s11706-024-0692-x","DOIUrl":null,"url":null,"abstract":"<div><p>MIL-101(Cr) has a special pore cage structure that provides broad channels for the transport of water molecules in the reverse osmosis (RO) water separation and purification. Combining MIL-101(Cr) with Fe<sub>3</sub>O<sub>4</sub> nanoparticles forms a water transport intermediate layer between the polyamide separation membrane and the polysulfone support base under an external magnetic field. MIL-101(Cr) is stable in both water and air while resistant to high temperature. With the introduction of 0.003 wt.% MIL-101(Cr)/Fe<sub>3</sub>O<sub>4</sub>, the water flux increased by 93.31% to 6.65 L·m<sup>−2</sup>·h<sup>−1</sup>·bar<sup>−1</sup> without sacrificing the NaCl rejection of 95.88%. The MIL-101(Cr)/Fe<sub>3</sub>O<sub>4</sub> multilayer membrane also demonstrated certain anti-pollution properties and excellent stability in a 72-h test. Therefore, the construction of a MIL-101(Cr)/Fe<sub>3</sub>O<sub>4</sub> interlayer can effectively improve the permeability of RO composite membranes.</p></div>","PeriodicalId":572,"journal":{"name":"Frontiers of Materials Science","volume":null,"pages":null},"PeriodicalIF":2.5000,"publicationDate":"2024-09-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Development of high-flux reverse osmosis membranes with MIL-101(Cr)/Fe3O4 interlayer\",\"authors\":\"Yanzhuang Jiang, Qian Yang, Lin Zhang, Liyan Yu, Na Song, Lina Sui, Qingli Wei, Lifeng Dong\",\"doi\":\"10.1007/s11706-024-0692-x\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>MIL-101(Cr) has a special pore cage structure that provides broad channels for the transport of water molecules in the reverse osmosis (RO) water separation and purification. Combining MIL-101(Cr) with Fe<sub>3</sub>O<sub>4</sub> nanoparticles forms a water transport intermediate layer between the polyamide separation membrane and the polysulfone support base under an external magnetic field. MIL-101(Cr) is stable in both water and air while resistant to high temperature. With the introduction of 0.003 wt.% MIL-101(Cr)/Fe<sub>3</sub>O<sub>4</sub>, the water flux increased by 93.31% to 6.65 L·m<sup>−2</sup>·h<sup>−1</sup>·bar<sup>−1</sup> without sacrificing the NaCl rejection of 95.88%. The MIL-101(Cr)/Fe<sub>3</sub>O<sub>4</sub> multilayer membrane also demonstrated certain anti-pollution properties and excellent stability in a 72-h test. Therefore, the construction of a MIL-101(Cr)/Fe<sub>3</sub>O<sub>4</sub> interlayer can effectively improve the permeability of RO composite membranes.</p></div>\",\"PeriodicalId\":572,\"journal\":{\"name\":\"Frontiers of Materials Science\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":2.5000,\"publicationDate\":\"2024-09-13\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Frontiers of Materials Science\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s11706-024-0692-x\",\"RegionNum\":4,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"MATERIALS SCIENCE, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Frontiers of Materials Science","FirstCategoryId":"88","ListUrlMain":"https://link.springer.com/article/10.1007/s11706-024-0692-x","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
Development of high-flux reverse osmosis membranes with MIL-101(Cr)/Fe3O4 interlayer
MIL-101(Cr) has a special pore cage structure that provides broad channels for the transport of water molecules in the reverse osmosis (RO) water separation and purification. Combining MIL-101(Cr) with Fe3O4 nanoparticles forms a water transport intermediate layer between the polyamide separation membrane and the polysulfone support base under an external magnetic field. MIL-101(Cr) is stable in both water and air while resistant to high temperature. With the introduction of 0.003 wt.% MIL-101(Cr)/Fe3O4, the water flux increased by 93.31% to 6.65 L·m−2·h−1·bar−1 without sacrificing the NaCl rejection of 95.88%. The MIL-101(Cr)/Fe3O4 multilayer membrane also demonstrated certain anti-pollution properties and excellent stability in a 72-h test. Therefore, the construction of a MIL-101(Cr)/Fe3O4 interlayer can effectively improve the permeability of RO composite membranes.
期刊介绍:
Frontiers of Materials Science is a peer-reviewed international journal that publishes high quality reviews/mini-reviews, full-length research papers, and short Communications recording the latest pioneering studies on all aspects of materials science. It aims at providing a forum to promote communication and exchange between scientists in the worldwide materials science community.
The subjects are seen from international and interdisciplinary perspectives covering areas including (but not limited to):
Biomaterials including biomimetics and biomineralization;
Nano materials;
Polymers and composites;
New metallic materials;
Advanced ceramics;
Materials modeling and computation;
Frontier materials synthesis and characterization;
Novel methods for materials manufacturing;
Materials performance;
Materials applications in energy, information and biotechnology.