二维软玻璃:振荡剪切下的屈服

Sayantan Ghosh, Rahul Nayak, Satyavani Vemparala, Pinaki Chaudhuri
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引用次数: 0

摘要

研究了由双分散可变形聚合物环组成的二维致密玻璃模型对外加振荡剪切的屈服响应,环刚度是控制参数。在静态玻璃状态下,柔性较高的环表现出更广泛的形状波动谱,随着环刚度的增加,形状波动谱变得越来越受限制。在剪切力作用下,高度堆积的圆环会屈服,即热组件失去刚度,随着圆环刚度的降低,阈值屈服应变显著增加。这项研究深入揭示了剪切作用下形状变化与翻译重排之间的相互作用,从而有助于理解致密堆积、可变形聚合物系统中的屈服转变。
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Two-dimensional squishy glass: yielding under oscillatory shear
The yielding response to an imposed oscillatory shear is investigated for a model two-dimensional dense glass composed of bidisperse, deformable polymer rings, with the ring stiffness being the control parameter. In the quiescent glassy state, the more flexible rings exhibit a broader spectrum of shape fluctuations, which becomes increasingly constrained with increasing ring stiffness. Under shear, the highly packed rings yield, i.e. the thermal assembly looses rigidity, with the threshold yield strain increasing significantly with decreasing ring stiffness. Further, the rings display significant deviations in their shape compared to their unsheared counterparts. This study provides insights into the interplay between shape changes and translational rearrangements under shear, thus contributing to the understanding of yielding transition in densely packed, deformable polymer systems.
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