α-DMACoPc/TiO2/MIL-101(Fe)增强催化系统催化降解罗丹明 B

IF 2.1 4区 材料科学 Q3 CHEMISTRY, MULTIDISCIPLINARY Journal of Nanoparticle Research Pub Date : 2024-09-11 DOI:10.1007/s11051-024-06123-y
Yanbing Yin, Xueli Zhang, Bei Jiang, Zhou Wang, Yongming Feng, Xueying Li
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引用次数: 0

摘要

开发用于可见光反应的高效催化剂在光催化领域至关重要。本研究利用 MIL-101 (Fe)的优异吸附特性、酞菁的光敏能力和 TiO2 的光催化潜力,重点合成了新型三元复合材料(α-DMACoPc/TiO2/MIL-101 (Fe))。对纳米复合材料的结构和光学特性进行了深入分析。利用 X 射线粉末衍射 (XRD) 显示了复合材料的结晶性质。此外,傅立叶变换红外(FT-IR)研究证实了三元纳米复合材料的形成。光学吸收研究表明,从紫外到可见光范围内的光带隙都可以调节。结果表明,在氙灯的模拟阳光下暴露 150 分钟后,近 94% 的有机材料被分解。这种高效率可归因于复合材料之间的协同作用,从而增强了光的吸收。循环测试证明了这种复合材料的稳定性。这为推动由金属有机框架与半导体协同组成的光催化剂的设计和合成提供了宝贵的信息。探索了基于 MOFs 的介孔材料光降解有机污染物的可能性。此外,还研究了 MOFs 介孔材料对有机污染物的光催化降解。证实了复合材料在工业废弃物染料降解领域的潜力。良好的回收光催化再利用性表明这种光催化剂具有广阔的应用前景。
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Catalytic degradation of rhodamine B by α-DMACoPc/TiO2/MIL-101 (Fe) enhanced catalytic system

Developing efficient catalysts for visible light reactions is vital in the field of photocatalysis. This study focuses on the synthesis of novel ternary composites (α-DMACoPc/TiO2/MIL-101 (Fe)) by leveraging the excellent adsorption properties of MIL-101 (Fe), the photosensitizing capabilities of phthalocyanine, and the photocatalytic potential of TiO2. The nanocomposites’ structural and optical attributes were thoroughly analyzed. X-ray powder diffraction (XRD) was utilized to showcase the crystalline nature of the composites. Furthermore, Fourier transform infrared (FT-IR) studies confirmed the formation of ternary nanocomposites. Optical absorption investigations demonstrated the tuning of the optical band gap from the UV to the visible range. The results indicated that nearly 94% of the organic material was decomposed after 150 min of exposure to simulated sunlight from a xenon lamp. This high efficiency can be attributed to the synergistic interaction among the composites, enhancing light absorption. The composite’s robust stability was evidenced through cyclic tests. Valuable information was provided to advance the design and synthesis of photocatalysts consisting of metal–organic frameworks synergized with semiconductors. Exploring the possibility of mesoporous materials was based on MOFs for photodegradation of organic pollutants. The photocatalytic degradation of organic pollutants by MOFs mesoporous materials was also investigated. The potential of composite materials in the field of dye degradation of industrial waste is confirmed. The good recycling photocatalytic reusability indicates the promising application of this photocatalyst.

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来源期刊
Journal of Nanoparticle Research
Journal of Nanoparticle Research 工程技术-材料科学:综合
CiteScore
4.40
自引率
4.00%
发文量
198
审稿时长
3.9 months
期刊介绍: The objective of the Journal of Nanoparticle Research is to disseminate knowledge of the physical, chemical and biological phenomena and processes in structures that have at least one lengthscale ranging from molecular to approximately 100 nm (or submicron in some situations), and exhibit improved and novel properties that are a direct result of their small size. Nanoparticle research is a key component of nanoscience, nanoengineering and nanotechnology. The focus of the Journal is on the specific concepts, properties, phenomena, and processes related to particles, tubes, layers, macromolecules, clusters and other finite structures of the nanoscale size range. Synthesis, assembly, transport, reactivity, and stability of such structures are considered. Development of in-situ and ex-situ instrumentation for characterization of nanoparticles and their interfaces should be based on new principles for probing properties and phenomena not well understood at the nanometer scale. Modeling and simulation may include atom-based quantum mechanics; molecular dynamics; single-particle, multi-body and continuum based models; fractals; other methods suitable for modeling particle synthesis, assembling and interaction processes. Realization and application of systems, structures and devices with novel functions obtained via precursor nanoparticles is emphasized. Approaches may include gas-, liquid-, solid-, and vacuum-based processes, size reduction, chemical- and bio-self assembly. Contributions include utilization of nanoparticle systems for enhancing a phenomenon or process and particle assembling into hierarchical structures, as well as formulation and the administration of drugs. Synergistic approaches originating from different disciplines and technologies, and interaction between the research providers and users in this field, are encouraged.
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