掺杂 PVP 的 Si3N4-TiN 无机纳米结构的合成及其增强的形态和光学特性,有望应用于光电子领域

IF 3.9 3区 化学 Q2 POLYMER SCIENCE Journal of Inorganic and Organometallic Polymers and Materials Pub Date : 2024-08-14 DOI:10.1007/s10904-024-03324-9
Ahmed Hashim, Hamed Ibrahim, Farhan Lafta Rashid, Aseel Hadi
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摘要

制备出的 PVP-Si3N4-TiN 新型纳米结构薄膜有望应用于不同的纳米电子学和储能领域。在波长(340 纳米至 840 纳米)范围内记录了 PVP-Si3N4-TiN 纳米结构的吸光度和透射率光谱。结果表明,浓度从 12.5 g/L 增加到 37.5 g/L 时,在 λ = 380 nm 处的吸收率增加了约 63.8%,但透射率却降低了。这种特性使 PVP-Si3N4-TiN 纳米结构适用于各种可再生领域。当浓度从 12.5 g/L 增加到 37.5 g/L 时,PVP-Si3N4-TiN 纳米结构的能隙从 3.1 eV 减小到 2.4 eV。其他光学因子则随着浓度的增加而增加。储能应用结果表明,随着浓度从 12.5 g/L 增加到 37.5 g/L,熔化时间缩短了约 65.25%,这使它们适合用于储能和纳米电子学领域。
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Synthesis and Augmented Morphological and Optical Properties of Si3N4-TiN Inorganic Nanostructures Doped PVP for Promising Optoelectronics Applications

Films of PVP-Si3N4-TiN new nanostructures have been fabricated to use in different promising nanoelectronics and energy storage fields. The absorbance and transmittance spectra for PVP-Si3N4-TiN nanostructures’ were recorded at wavelength ranged (340 nm to 840 nm). The results showed the increase of concentration from 12.5 g/L to 37.5 g/L causes to increase in the absorption about 63.8% at λ = 380 nm but the transmission reduced. This behaviour lead to make the PVP-Si3N4-TiN nanostructures are suitable for various renewable fields. The energy gap of PVP-Si3N4-TiN nanostructures reduced from 3.1 eV to 2.4 eV when the concentration increased from 12.5 g/L to 37.5 g/L. The other optical factors were increased with rising concentration. The results of energy storage application indicated that the melting time decreased about 65.25% with an increase in concentration from 12.5 g/L to 37.5 g/L which make them appropriate for energy storage and nanoelectronics fields.

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来源期刊
CiteScore
8.30
自引率
7.50%
发文量
335
审稿时长
1.8 months
期刊介绍: Journal of Inorganic and Organometallic Polymers and Materials [JIOP or JIOPM] is a comprehensive resource for reports on the latest theoretical and experimental research. This bimonthly journal encompasses a broad range of synthetic and natural substances which contain main group, transition, and inner transition elements. The publication includes fully peer-reviewed original papers and shorter communications, as well as topical review papers that address the synthesis, characterization, evaluation, and phenomena of inorganic and organometallic polymers, materials, and supramolecular systems.
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