通过供体-受体环丙烷半马来酸酯合成 (±)-trans-Whiskey 和 Cognac 内酯

IF 1.7 4区化学 Q3 CHEMISTRY, ORGANIC Synlett Pub Date : 2024-08-22 DOI:10.1055/s-0043-1775397

Tim J. Menna, Michael A. Kerr

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引用次数: 0

摘要

酒精陈酿是一个永恒的过程，自发明以来几乎没有什么变化。储存在木材中的分子可以被酒精提取出来，从而产生独特的风味。这些分子包括威士忌内酯和干邑内酯。在此，我们报告了利用环丙烷半丙酮酸盐的重排方法合成反式威士忌内酯和干邑内酯的简短过程。

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Synthesis of the (±)-trans-Whiskey and Cognac Lactones via a Donor–Acceptor Cyclopropane Hemimalonate

Aging alcohol is a timeless process that has seen little variation since the time of its invention. Molecules stored within the wood can be extracted by the alcohol to produce unique flavors. Among these molecules exist the whiskey and cognac lactones. Herein we report a short synthesis of the trans-whiskey and cognac lactones using a rearrangement of cyclopropane hemimalonates.

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来源期刊

Synlett 化学-有机化学

CiteScore

3.40

自引率

5.00%

发文量

369

审稿时长

1 months

期刊介绍： SYNLETT is an international journal reporting research results and current trends in chemical synthesis in short personalized reviews and preliminary communications. It covers all fields of scientific endeavor that involve organic synthesis, including catalysis, organometallic, medicinal, biological, and photochemistry, but also related disciplines and offers the possibility to publish scientific primary data.