D2 高速铁路车轮钢中大尺寸 CaO-Al2O3-SiO2 杂质的特征、形成机理及去除方法

IF 1.9 3区 材料科学 Q2 METALLURGY & METALLURGICAL ENGINEERING steel research international Pub Date : 2024-08-30 DOI:10.1002/srin.202400497
Daohua Bao, Guoguang Cheng, Jinwen Zhang, Zhixiang Wang, Wei Li, Yao Li, Tao Zhang
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引用次数: 0

摘要

研究了 D2 高速铁路车轮钢中大尺寸 CaO-Al2O3-SiO2 夹杂的特征、形成机理和去除方法。连铸坯中存在大尺寸的 CaO-Al2O3-SiO2 夹杂,SiO2 和 CaO 含量分别为 5 至 15 和 30 至 65 wt%。尺寸主要超过 10 μm。这些夹杂物源自精炼过程中的钙处理阶段,在这一阶段,钢液中形成了 CaO-Al2O3-SiO2 液态夹杂物。这些夹杂物与钢液的接触角低于 40°,因此具有极佳的润湿性。因此,这些夹杂物很难从钢液中去除,并会遗留在钢坯中。通过降低 SiO2 含量并将 CaO 含量控制在 8-30 wt% 之间,可形成小尺寸夹杂物。这就需要合理控制钢液中的铝和钙含量。当钢液中的 Al 和 Ca 含量分别保持在 0.012 wt% 和 8 ppm 时,钢坯中的夹杂物主要是 CaO-6Al2O3 (CA6) 和 CaO-2Al2O3 (CA2),尺寸均小于 5 μm。这些夹杂物代表了钢中合适的夹杂物。
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Characteristics, Formation Mechanism, and Removal of Large‐Sized CaO–Al2O3–SiO2 Inclusions in D2 High‐Speed Railway Wheel Steel
The characteristics, formation mechanism, and removal of large‐sized CaO–Al2O3–SiO2 inclusions in D2 high‐speed railway wheel steel are investigated. Large‐sized CaO–Al2O3–SiO2 inclusions are present in the continuous casting billet, with SiO2 and CaO content ranging from 5 to 15 and 30 to 65 wt%, respectively. The size mainly exceeds 10 μm. These inclusions originate from the calcium‐treatment stage of the refining process, during which liquid CaO–Al2O3–SiO2 inclusions are formed in the liquid steel. The contact angle between these inclusions and the liquid steel is below 40°, which results in excellent wettability. Consequently, the inclusions are difficult to remove from the liquid steel and are thus inherited into the billet. By reducing the SiO2 content and controlling CaO content between 8 and 30 wt%, small‐sized inclusions are formed. This requires reasonable control of the Al and Ca content in the liquid steel. When the Al and Ca content in liquid steel is maintained at 0.012 wt% and 8 ppm, respectively, the inclusions in the billet are mainly CaO·6Al2O3 (CA6) and CaO·2Al2O3 (CA2), both under 5 μm in size. These inclusions represent the suitable inclusions in steel.
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来源期刊
steel research international
steel research international 工程技术-冶金工程
CiteScore
3.30
自引率
18.20%
发文量
319
审稿时长
1.9 months
期刊介绍: steel research international is a journal providing a forum for the publication of high-quality manuscripts in areas ranging from process metallurgy and metal forming to materials engineering as well as process control and testing. The emphasis is on steel and on materials involved in steelmaking and the processing of steel, such as refractories and slags. steel research international welcomes manuscripts describing basic scientific research as well as industrial research. The journal received a further increased, record-high Impact Factor of 1.522 (2018 Journal Impact Factor, Journal Citation Reports (Clarivate Analytics, 2019)). The journal was formerly well known as "Archiv für das Eisenhüttenwesen" and "steel research"; with effect from January 1, 2006, the former "Scandinavian Journal of Metallurgy" merged with Steel Research International. Hot Topics: -Steels for Automotive Applications -High-strength Steels -Sustainable steelmaking -Interstitially Alloyed Steels -Electromagnetic Processing of Metals -High Speed Forming
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