锌基水性充电电池中磷酸盐阴极的先进表征技术

IF 19.5 1区 材料科学 Q1 CHEMISTRY, PHYSICAL Carbon Energy Pub Date : 2024-08-23 DOI:10.1002/cey2.611
Li-Feng Zhou, Jia-Yang Li, Jian Peng, Li-Ying Liu, Hang Zhang, Yi-Song Wang, Yameng Fan, Jia-Zhao Wang, Tao Du
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引用次数: 0

摘要

锌基水性电池正逐渐成为商业上成功的锂离子电池的替代品,特别是在发电站的大规模能源储存方面。磷酸盐阴极因其可调节的操作潜力、电化学稳定性、高理论容量和对环境的适应性而备受研究关注。然而,磷酸盐阴极的应用受到各种挑战的阻碍,研究进展也因机制不明而受阻。在这篇综述中,首先根据磷酸盐材料的结构及其相应的电化学性能,总结了作为锌基电池阴极的各类磷酸盐材料。然后,讨论了利用先进表征技术揭示磷酸盐阴极中 Zn2+ 储存机制的最新进展。最后,就锌基电池中使用的表征技术和磷酸盐的应用潜力提出了一些重要观点。本综述旨在引导研究人员采用先进的表征技术来应对关键挑战,从而加快磷酸盐阴极在锌基电池中的实际应用,实现大规模储能。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

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Advanced characterization techniques for phosphate cathodes in aqueous rechargeable zinc-based batteries

Aqueous zinc-based batteries are emerging as highly promising alternatives to commercially successful lithium-ion batteries, particularly for large-scale energy storage in power stations. Phosphate cathodes have garnered significant research interest owing to their adjustable operation potential, electrochemical stability, high theoretical capacity, and environmental robustness. However, their application is impeded by various challenges, and research progress is hindered by unclear mechanisms. In this review, the various categories of phosphate materials as zinc-based battery cathodes are first summarized according to their structure and their corresponding electrochemical performance. Then, the current advances to reveal the Zn2+ storage mechanisms in phosphate cathodes by using advanced characterization techniques are discussed. Finally, some critical perspectives on the characterization techniques used in zinc-based batteries and the application potential of phosphates are provided. This review aims to guide researchers toward advanced characterization technologies that can address key challenges, thereby accelerating the practical application of phosphate cathodes in zinc-based batteries for large-scale energy storage.

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来源期刊
Carbon Energy
Carbon Energy Multiple-
CiteScore
25.70
自引率
10.70%
发文量
116
审稿时长
4 weeks
期刊介绍: Carbon Energy is an international journal that focuses on cutting-edge energy technology involving carbon utilization and carbon emission control. It provides a platform for researchers to communicate their findings and critical opinions and aims to bring together the communities of advanced material and energy. The journal covers a broad range of energy technologies, including energy storage, photocatalysis, electrocatalysis, photoelectrocatalysis, and thermocatalysis. It covers all forms of energy, from conventional electric and thermal energy to those that catalyze chemical and biological transformations. Additionally, Carbon Energy promotes new technologies for controlling carbon emissions and the green production of carbon materials. The journal welcomes innovative interdisciplinary research with wide impact. It is indexed in various databases, including Advanced Technologies & Aerospace Collection/Database, Biological Science Collection/Database, CAS, DOAJ, Environmental Science Collection/Database, Web of Science and Technology Collection.
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Issue Information Cover Image, Volume 6, Number 10, October 2024 Back Cover Image, Volume 6, Number 10, October 2024 Interface and doping engineering of V2C-MXene-based electrocatalysts for enhanced electrocatalysis of overall water splitting Issue Information
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