Li-Feng Zhou, Jia-Yang Li, Jian Peng, Li-Ying Liu, Hang Zhang, Yi-Song Wang, Yameng Fan, Jia-Zhao Wang, Tao Du
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Advanced characterization techniques for phosphate cathodes in aqueous rechargeable zinc-based batteries
Aqueous zinc-based batteries are emerging as highly promising alternatives to commercially successful lithium-ion batteries, particularly for large-scale energy storage in power stations. Phosphate cathodes have garnered significant research interest owing to their adjustable operation potential, electrochemical stability, high theoretical capacity, and environmental robustness. However, their application is impeded by various challenges, and research progress is hindered by unclear mechanisms. In this review, the various categories of phosphate materials as zinc-based battery cathodes are first summarized according to their structure and their corresponding electrochemical performance. Then, the current advances to reveal the Zn2+ storage mechanisms in phosphate cathodes by using advanced characterization techniques are discussed. Finally, some critical perspectives on the characterization techniques used in zinc-based batteries and the application potential of phosphates are provided. This review aims to guide researchers toward advanced characterization technologies that can address key challenges, thereby accelerating the practical application of phosphate cathodes in zinc-based batteries for large-scale energy storage.
期刊介绍:
Carbon Energy is an international journal that focuses on cutting-edge energy technology involving carbon utilization and carbon emission control. It provides a platform for researchers to communicate their findings and critical opinions and aims to bring together the communities of advanced material and energy. The journal covers a broad range of energy technologies, including energy storage, photocatalysis, electrocatalysis, photoelectrocatalysis, and thermocatalysis. It covers all forms of energy, from conventional electric and thermal energy to those that catalyze chemical and biological transformations. Additionally, Carbon Energy promotes new technologies for controlling carbon emissions and the green production of carbon materials. The journal welcomes innovative interdisciplinary research with wide impact. It is indexed in various databases, including Advanced Technologies & Aerospace Collection/Database, Biological Science Collection/Database, CAS, DOAJ, Environmental Science Collection/Database, Web of Science and Technology Collection.