3D printing of high-stiffness and high-strength glass fiber reinforced PEEK composites by selective laser sintering

Glass fiber reinforced poly-ether-ether-ketone (PEEK) composites are emerging as structural materials of multifunctional devices in space applications, due to their outstanding mechanical properties, electrical insulating properties, and resistance to irradiation. Here, a new approach for preparing glass fiber/PEEK powders tailored for selective laser sintering (SLS) process is proposed. The surface of glass fiber is modified with the sulfonated PEEK following the designed procedure. The flowability of glass fiber/PEEK powders is also improved by adding the nano-scale SiO₂ flow agent. The glass fiber reinforced PEEK composites are successfully 3D printed using the glass fiber/PEEK powders. Further, the enhancement of interfacial bonding between PEEK and glass fiber is analyzed through quasi-static tension tests and scanning electron microscopy (SEM) for the SLSed glass fiber reinforced PEEK composites. The average ultimate tensile strength reaches approximately 100 MPa using these optimal process parameters, while the average elastic modulus is around 7 GPa. Finally, the upper limit of fiber weight fraction is evaluated with the X-ray computed tomography (XCT) and the high-fidelity discrete element method (DEM) simulation.