CFRTP 单层粘接及其通过激光表面处理提高的机械性能:有限元模拟和实验验证

IF 5.4 3区 材料科学 Q2 CHEMISTRY, PHYSICAL ACS Applied Energy Materials Pub Date : 2024-09-14 DOI:10.1016/j.optlastec.2024.111765
Zhaobing Liu , Shucheng Li , Yaoyao Yu
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引用次数: 0

摘要

碳纤维增强热塑性聚合物(CFRTP)具有出色的机械性能,因此被广泛应用于许多工业领域。为应对在原位修复大型非关键 CFRTP 结构部件的工程挑战,本文提出了一种红外光纤激光表面清洁技术,用于处理粘接界面并增强聚丙烯(PP)基 CFRTP 单层粘接接头的拉伸强度。具体而言,首先通过单因素和正交实验确定了不同工艺参数对粘接接头性能的影响。然后,进行在线温度监测,以阐明 CFRTP 样品界面的激光处理机制。激光处理样品的表面形态进一步表明,当样品表面温度超过树脂分解温度并延长保温时间时,树脂可以更彻底地从表面去除。此外,还建立了一个考虑各向异性传热的新型三维编织有限元(FE)模型,用于预测 CFRTP 的表面温度和清洁质量。该有限元模型结合了碳纤维的各向异性传热特性,从而准确模拟了碳纤维与树脂基体之间的传热行为。通过研究表面烧蚀形态和峰值表面温度,阐明了激光烧蚀机理。实验结果与 FE 模拟结果的比较表明,表面形态的变化趋势具有明显的一致性,表面峰值温度的差异从 3.29 % 到 24.63 % 不等。实验证明,当激光功率为 35 W、扫描速度为 2500 mm/s、扫描次数为四次时,单层粘接接头的剪切强度达到最大值。粘接接头机械性能的提高可归因于激光处理样品润湿性的改善和表面自由能的提高。
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CFRTP single-lap adhesive bonding and its mechanical performance enhanced by laser surface treatment: Finite element simulation and experimental validation

The outstanding mechanical properties of carbon fiber reinforced thermoplastic polymer (CFRTP) have led to its widespread application in many industrial sectors. In response to the engineering challenge of repairing large non-critical CFRTP structural components in situ, an infrared fiber laser surface cleaning technology is proposed to treat the bonding interface and enhance the tensile strength of polypropylene (PP)-based CFRTP single-lap bonded joints. Specifically, through single-factor and orthogonal experiments, the impact of different process parameters on the properties of the bonded joints was identified first. Then, online temperature monitoring was performed to elucidate the laser treatment mechanism of the CFRTP sample interface. Surface morphology of the laser-treated samples further indicates that when the temperature of the sample surface surpasses the resin decomposition temperature with extended holding time, the resin could be removed from the surface more thoroughly. Additionally, a novel three-dimensional woven finite element (FE) model, accounting for anisotropic heat transfer, was established to predict the surface temperature and cleaning quality of CFRTP. The FE model incorporates the anisotropic heat transfer characteristics of carbon fibers, thus accurately simulating the heat transfer behaviors between carbon fibers and the resin matrix. The laser ablation mechanism is elucidated by examining the surface ablation morphologies and peak surface temperatures. A comparison between experimental results and FE simulations demonstrated a notable coherence in the trend of surface morphology variations, with discrepancies in peak surface temperatures ranging from 3.29 % to 24.63 %. The experimental tests proved that the shear strength of single-lap bonded joints reaches its maximum value when the laser power is 35 W, the scanning speed is 2500 mm/s, and the number of scans is four. The enhancement of the mechanical properties of bonded joints can be attributed to the improved wettability and higher surface free energy of the laser-treated samples.

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来源期刊
ACS Applied Energy Materials
ACS Applied Energy Materials Materials Science-Materials Chemistry
CiteScore
10.30
自引率
6.20%
发文量
1368
期刊介绍: ACS Applied Energy Materials is an interdisciplinary journal publishing original research covering all aspects of materials, engineering, chemistry, physics and biology relevant to energy conversion and storage. The journal is devoted to reports of new and original experimental and theoretical research of an applied nature that integrate knowledge in the areas of materials, engineering, physics, bioscience, and chemistry into important energy applications.
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