Xiaosheng Song, Xinghui Liang, Juliana Eko, H. Hohyun Sun, Jae-Min Kim, Hun Kim, Yang-Kook Sun
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引用次数: 0
摘要
锂硫(Li-S)电池系统因其超高的理论能量密度和广阔的应用前景而备受关注。然而,随着对 S 负载和电解质含量的要求越来越高,实用的锂-S 电池仍然面临着一些严峻的挑战,例如阴极界面反应动力学缓慢、阳极界面反应不稳定以及阴极和阳极之间的不良串扰效应。传统的电解质体系往往难以在实际条件下应对这些挑战,因此为实用锂-S 电池建立新的电解质体系势在必行。本综述首先讨论了建立新型电解质的必要性,并提出了具体的参数要求,如电解质与硫的质量比(Em/S)。随后,总结了研究人员提出的一些电解质改良策略,以应对与实际锂-S 电池相关的不同挑战。最后,对不同策略的组合进行了评述,旨在揭示能同时应对多种挑战的更有效的设计方法,同时为建立实用锂-S 电池的新型平衡电解质提供指导。这篇文章促进了实用锂-S 电池新电解质的开发,并可作为其他二次电池电解质开发的参考。
Toward Practical Li–S Batteries: On the Road to a New Electrolyte
The lithium–sulfur (Li–S) battery system has attracted considerable attention due to its ultrahigh theoretical energy density and promising applications. However, with the increasing demands on S loading and electrolyte content, practical Li–S batteries still face several serious challenges, such as slow reaction kinetics at the cathode interface, unstable anode interface reactions, and undesirable crosstalk effects between the cathode and anode. Traditional electrolyte systems often struggle to address these challenges under practical conditions, thereby rendering it imperative to establish a new electrolyte system for practical Li–S batteries. This review first discusses the necessity of establishing a new electrolyte and propose specific parameter requirements, such as the electrolyte-to-sulfur mass ratio (Em/S). Subsequently, some electrolyte modification strategies proposed by researchers are summarized to address the different challenges associated with practical Li–S batteries. Finally, the combination of different strategies is reviewed, aiming to reveal more effective design approaches that simultaneously address multiple challenges, while providing guidance for establishing a new balanced electrolyte for practical Li–S batteries. This article promotes the development of new electrolytes for practical Li–S batteries and can act as a reference for the development of electrolytes for other secondary batteries.
期刊介绍:
Established in 2011, Advanced Energy Materials is an international, interdisciplinary, English-language journal that focuses on materials used in energy harvesting, conversion, and storage. It is regarded as a top-quality journal alongside Advanced Materials, Advanced Functional Materials, and Small.
With a 2022 Impact Factor of 27.8, Advanced Energy Materials is considered a prime source for the best energy-related research. The journal covers a wide range of topics in energy-related research, including organic and inorganic photovoltaics, batteries and supercapacitors, fuel cells, hydrogen generation and storage, thermoelectrics, water splitting and photocatalysis, solar fuels and thermosolar power, magnetocalorics, and piezoelectronics.
The readership of Advanced Energy Materials includes materials scientists, chemists, physicists, and engineers in both academia and industry. The journal is indexed in various databases and collections, such as Advanced Technologies & Aerospace Database, FIZ Karlsruhe, INSPEC (IET), Science Citation Index Expanded, Technology Collection, and Web of Science, among others.