改性明胶增强二氧化硅气凝胶的制备及其热机械性能

IF 3.2 3区 材料科学 Q1 MATERIALS SCIENCE, CERAMICS Journal of Non-crystalline Solids Pub Date : 2024-09-17 DOI:10.1016/j.jnoncrysol.2024.123222
Wang Zhan , Jinhong Mo , Fan Shi , Zhiyuan Xu , Le Chen , Lixia Li , Ru Zhou , Mingyi Chen , Junchen Jiang
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引用次数: 0

摘要

由于二氧化硅气凝胶的机械性能较差,本研究采用改性明胶和二氧化硅溶胶共凝胶法制备了复合气凝胶。明胶被用作增强相,以提高复合气凝胶的性能。研究调查了不同浓度的明胶(1.7 %、1.9 %、2.1 %、2.3 %)和硅烷偶联剂(1 %、1.5 %、2 %、2.5 %、3 %)对复合气凝胶热机械性能的影响。为评估复合气凝胶的热机械性能,进行了各种测试,包括热稳定性、导热性、抗压性和阻燃性。此外,还使用 SEM、TEM、FTIR 和 XRD 分析了表面形貌和化学成分,以探讨其与热机械性能的相关性。结果表明,明胶含量为 2.1%、硅烷偶联剂含量为 3%的复合气凝胶具有出色的综合性能。
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Preparation and thermo-mechanical properties of modified gelatin reinforced SiO2 aerogels

Due to the poor mechanical properties of SiO2 aerogels, this study prepared the composite aerogels using the co-gel method with modified gelatin and SiO2 sol. Gelatin is used as a reinforcing phase to enhance the performance of the composite aerogels. The study investigated the impact of varying concentrations of gelatin (1.7 %, 1.9 %, 2.1 %, 2.3 %) and silane coupling agent (1 %, 1.5 %, 2 %, 2.5 %, 3 %) on the thermal-mechanical properties of the composite aerogels. Various tests were conducted to assess the thermal-mechanical properties of the composite aerogels, including thermal stability, thermal conductivity, compression resistance, and fire-retardant. Additionally, the surface morphology and chemical composition were analyzed using SEM, TEM, FTIR, and XRD to explore the correlation with the thermal-mechanical properties. The results indicated that the composite aerogels exhibited outstanding overall performance with 2.1 % gelatin and 3 % silane coupling agent.

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来源期刊
Journal of Non-crystalline Solids
Journal of Non-crystalline Solids 工程技术-材料科学:硅酸盐
CiteScore
6.50
自引率
11.40%
发文量
576
审稿时长
35 days
期刊介绍: The Journal of Non-Crystalline Solids publishes review articles, research papers, and Letters to the Editor on amorphous and glassy materials, including inorganic, organic, polymeric, hybrid and metallic systems. Papers on partially glassy materials, such as glass-ceramics and glass-matrix composites, and papers involving the liquid state are also included in so far as the properties of the liquid are relevant for the formation of the solid. In all cases the papers must demonstrate both novelty and importance to the field, by way of significant advances in understanding or application of non-crystalline solids; in the case of Letters, a compelling case must also be made for expedited handling.
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