{"title":"高负载 NaCrO2 @C 纳米纤维作为高稳定性钠离子电池的无粘结剂阴极","authors":"","doi":"10.1016/j.vacuum.2024.113647","DOIUrl":null,"url":null,"abstract":"<div><p>A NaCrO<sub>2</sub> @C flexible free-standing cathode is designed and fabricated via a facile electrospinning strategy, in which electrochemically active NaCrO<sub>2</sub> nanoparticles homogeneously dispersed in the flexible carbon nanofibers. Serving as the binder-free cathode for sodium-ion batteries, the as-constructed NaCrO<sub>2</sub>@C flexible free-standing cathode delivers a long cycling life (81 % capacity retention after 1000 cycles) with a high loading (7.6 mg cm<sup>−2</sup>). The enhancements for sodium-ion insertion/desertion is assigned to the dramatically decrease the polarization between electrodes and avoid the volume expansion during high-rate cycling. The NaCrO<sub>2</sub>@C flexible free-standing cathode opens up exciting possibilities for the development of advanced flexible sodium-ion batteries with both excellent mechanical flexibility and electrochemical properties.</p></div>","PeriodicalId":23559,"journal":{"name":"Vacuum","volume":null,"pages":null},"PeriodicalIF":3.8000,"publicationDate":"2024-09-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"High-loading NaCrO2 @C nanofibers as binder-free cathode for high-stable sodium-ion batteries\",\"authors\":\"\",\"doi\":\"10.1016/j.vacuum.2024.113647\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>A NaCrO<sub>2</sub> @C flexible free-standing cathode is designed and fabricated via a facile electrospinning strategy, in which electrochemically active NaCrO<sub>2</sub> nanoparticles homogeneously dispersed in the flexible carbon nanofibers. Serving as the binder-free cathode for sodium-ion batteries, the as-constructed NaCrO<sub>2</sub>@C flexible free-standing cathode delivers a long cycling life (81 % capacity retention after 1000 cycles) with a high loading (7.6 mg cm<sup>−2</sup>). The enhancements for sodium-ion insertion/desertion is assigned to the dramatically decrease the polarization between electrodes and avoid the volume expansion during high-rate cycling. The NaCrO<sub>2</sub>@C flexible free-standing cathode opens up exciting possibilities for the development of advanced flexible sodium-ion batteries with both excellent mechanical flexibility and electrochemical properties.</p></div>\",\"PeriodicalId\":23559,\"journal\":{\"name\":\"Vacuum\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":3.8000,\"publicationDate\":\"2024-09-13\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Vacuum\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0042207X24006936\",\"RegionNum\":2,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"MATERIALS SCIENCE, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Vacuum","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0042207X24006936","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
High-loading NaCrO2 @C nanofibers as binder-free cathode for high-stable sodium-ion batteries
A NaCrO2 @C flexible free-standing cathode is designed and fabricated via a facile electrospinning strategy, in which electrochemically active NaCrO2 nanoparticles homogeneously dispersed in the flexible carbon nanofibers. Serving as the binder-free cathode for sodium-ion batteries, the as-constructed NaCrO2@C flexible free-standing cathode delivers a long cycling life (81 % capacity retention after 1000 cycles) with a high loading (7.6 mg cm−2). The enhancements for sodium-ion insertion/desertion is assigned to the dramatically decrease the polarization between electrodes and avoid the volume expansion during high-rate cycling. The NaCrO2@C flexible free-standing cathode opens up exciting possibilities for the development of advanced flexible sodium-ion batteries with both excellent mechanical flexibility and electrochemical properties.
期刊介绍：
Vacuum is an international rapid publications journal with a focus on short communication. All papers are peer-reviewed, with the review process for short communication geared towards very fast turnaround times. The journal also published full research papers, thematic issues and selected papers from leading conferences.
A report in Vacuum should represent a major advance in an area that involves a controlled environment at pressures of one atmosphere or below.
The scope of the journal includes:
1. Vacuum; original developments in vacuum pumping and instrumentation, vacuum measurement, vacuum gas dynamics, gas-surface interactions, surface treatment for UHV applications and low outgassing, vacuum melting, sintering, and vacuum metrology. Technology and solutions for large-scale facilities (e.g., particle accelerators and fusion devices). New instrumentation ( e.g., detectors and electron microscopes).
2. Plasma science; advances in PVD, CVD, plasma-assisted CVD, ion sources, deposition processes and analysis.
3. Surface science; surface engineering, surface chemistry, surface analysis, crystal growth, ion-surface interactions and etching, nanometer-scale processing, surface modification.
4. Materials science; novel functional or structural materials. Metals, ceramics, and polymers. Experiments, simulations, and modelling for understanding structure-property relationships. Thin films and coatings. Nanostructures and ion implantation.
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