Yu-hang Cui, Yong Yang, Dian-long Wang, Yan-wei Wang
{"title":"反应等离子喷涂合成的 Al-O 晶间非晶相增韧纳米级 ZrB2-ZrC 复合涂层的形成机理","authors":"Yu-hang Cui, Yong Yang, Dian-long Wang, Yan-wei Wang","doi":"10.1016/j.jmst.2024.06.059","DOIUrl":null,"url":null,"abstract":"<p>A new nanostructured ZrB<sub>2</sub>-ZrC composite coating with ZrB<sub>2</sub>-ZrC nanoscale eutectic and ZrB<sub>2</sub>+Amorphous microstructure was synthesized in situ by plasma spraying Zr-B<sub>4</sub>C-Al composite powder. The thermal analysis, quenching experiments and microstructure characterization were investigated and the formation mechanism of the bimodal in-situ microstructure was revealed. Al contributed to the liquid phase separation of molten droplets, which is the key to forming ZrB<sub>2</sub>+Amorphous microstructure. The formation of coating followed reaction-melting-liquid separation-deposition and solidification mechanism. The nanostructured ZrB<sub>2</sub>-ZrC composite coating with Al-O intergranular amorphous phase has excellent mechanical properties. The uniform nano-grains improved the hardness and the toughness of the ZrB<sub>2</sub>-ZrC eutectic. The ZrB<sub>2</sub>+Al-O amorphous microstructure obtained high toughness and the toughening mechanism was the crack deflection and crack branching caused by intergranular Al-O amorphous phase.</p>","PeriodicalId":16154,"journal":{"name":"Journal of Materials Science & Technology","volume":null,"pages":null},"PeriodicalIF":11.2000,"publicationDate":"2024-09-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Formation mechanism of Al-O intergranular amorphous phase toughened nanoscale ZrB2-ZrC composite coating synthesized by reactive plasma spraying\",\"authors\":\"Yu-hang Cui, Yong Yang, Dian-long Wang, Yan-wei Wang\",\"doi\":\"10.1016/j.jmst.2024.06.059\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>A new nanostructured ZrB<sub>2</sub>-ZrC composite coating with ZrB<sub>2</sub>-ZrC nanoscale eutectic and ZrB<sub>2</sub>+Amorphous microstructure was synthesized in situ by plasma spraying Zr-B<sub>4</sub>C-Al composite powder. The thermal analysis, quenching experiments and microstructure characterization were investigated and the formation mechanism of the bimodal in-situ microstructure was revealed. Al contributed to the liquid phase separation of molten droplets, which is the key to forming ZrB<sub>2</sub>+Amorphous microstructure. The formation of coating followed reaction-melting-liquid separation-deposition and solidification mechanism. The nanostructured ZrB<sub>2</sub>-ZrC composite coating with Al-O intergranular amorphous phase has excellent mechanical properties. The uniform nano-grains improved the hardness and the toughness of the ZrB<sub>2</sub>-ZrC eutectic. The ZrB<sub>2</sub>+Al-O amorphous microstructure obtained high toughness and the toughening mechanism was the crack deflection and crack branching caused by intergranular Al-O amorphous phase.</p>\",\"PeriodicalId\":16154,\"journal\":{\"name\":\"Journal of Materials Science & Technology\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":11.2000,\"publicationDate\":\"2024-09-20\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Materials Science & Technology\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://doi.org/10.1016/j.jmst.2024.06.059\",\"RegionNum\":1,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"MATERIALS SCIENCE, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Materials Science & Technology","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.1016/j.jmst.2024.06.059","RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
Formation mechanism of Al-O intergranular amorphous phase toughened nanoscale ZrB2-ZrC composite coating synthesized by reactive plasma spraying
A new nanostructured ZrB2-ZrC composite coating with ZrB2-ZrC nanoscale eutectic and ZrB2+Amorphous microstructure was synthesized in situ by plasma spraying Zr-B4C-Al composite powder. The thermal analysis, quenching experiments and microstructure characterization were investigated and the formation mechanism of the bimodal in-situ microstructure was revealed. Al contributed to the liquid phase separation of molten droplets, which is the key to forming ZrB2+Amorphous microstructure. The formation of coating followed reaction-melting-liquid separation-deposition and solidification mechanism. The nanostructured ZrB2-ZrC composite coating with Al-O intergranular amorphous phase has excellent mechanical properties. The uniform nano-grains improved the hardness and the toughness of the ZrB2-ZrC eutectic. The ZrB2+Al-O amorphous microstructure obtained high toughness and the toughening mechanism was the crack deflection and crack branching caused by intergranular Al-O amorphous phase.
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Journal of Materials Science & Technology strives to promote global collaboration in the field of materials science and technology. It primarily publishes original research papers, invited review articles, letters, research notes, and summaries of scientific achievements. The journal covers a wide range of materials science and technology topics, including metallic materials, inorganic nonmetallic materials, and composite materials.
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