用于电磁合作和高效电磁波吸收的稀土氧化物 CeO2 纳米粒子嵌入磁性碳纳米纤维

IF 11.2 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Journal of Materials Science & Technology Pub Date : 2024-09-20 DOI:10.1016/j.jmst.2024.08.044
Baoding Li, Yanli Deng, Chang Liu, Jing Qiao, Shanyue Hou, Na Wu, Fan Wu, Zhihui Zeng, Jiurong Liu
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引用次数: 0

摘要

多组分复合材料被认为有利于电磁波(EMW)的吸收,因为各组分的多重损耗协同效应可增强电磁波的衰减能力并优化阻抗匹配。在这项研究中,碳材料被半导电和磁性物质改性,以提高其吸收性能。CeO2 和 Co 的碳基纤维复合材料是通过电纺丝和碳化制备的。在填充率为 35 wt.% 时,CeCoC 纳米复合纤维在 2.2 mm 时的最小 RL 值为 -61.4 dB,有效吸收带宽 (EAB) 高达 7.6 GHz。优异的吸收性能源于改进的介电损耗和优化的阻抗匹配。稀土氧化物 CeO2 的引入不仅有助于保持纤维结构,还能促进传导损耗。特别是 CeO2 引入的氧空位缺陷大大提高了介电损耗能力。Co 粒子的引入优化了阻抗匹配,从而减小了匹配厚度并增强了磁损耗。这项研究证明了稀土氧化物在改善电磁波吸收性能方面的潜力,并为开发高性能电磁波吸收应用的先进材料提供了新的机遇。
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Rare earth oxides CeO2 nanoparticle embedded magnetic carbon nanofibers for electro-magnetic cooperation and efficient electromagnetic wave absorption

Multicomponent composites are considered conducive to electromagnetic wave (EMW) absorption, as multiple loss synergistic effect from each component, enhance the attenuation ability of EMW and optimize impedance matching. In this study, carbon material was modified by both semi-conductive and magnetic matters to improve their absorbing performance. The carbon-based fibrous composites of CeO2 and Co were prepared by electrospinning and subsequent carbonization. At a filling rate of 35 wt.%, the CeCoC nanocomposite fibers exhibit a minimum RL value of -61.4 dB at 2.2 mm, and an effective absorption bandwidth (EAB) of up to 7.6 GHz. The excellent absorbing performance is derived from the improved dielectric loss and optimized impedance matching. The introduction of rare earth oxide CeO2 not only helps to maintain the fibrous structure, but also promotes conduction loss. Especially, oxygen vacancy defects introduced by CeO2 greatly improved the dielectric loss capacity. The introduction of Co particles optimizes the impedance matching to reduce the matching thickness and strengthen magnetic loss. This study demonstrates the potential of rare earth oxides in improving EMW absorption performance, and opens up new opportunities for the development of advanced materials for high-performance EMW absorption applications.

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来源期刊
Journal of Materials Science & Technology
Journal of Materials Science & Technology 工程技术-材料科学:综合
CiteScore
20.00
自引率
11.00%
发文量
995
审稿时长
13 days
期刊介绍: Journal of Materials Science & Technology strives to promote global collaboration in the field of materials science and technology. It primarily publishes original research papers, invited review articles, letters, research notes, and summaries of scientific achievements. The journal covers a wide range of materials science and technology topics, including metallic materials, inorganic nonmetallic materials, and composite materials.
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